金微纳阵列表面等离激元中红外波段光谱特性

表面等离激元是金属表面自由电子在入射光激发下产生的电子集体振荡行为及其相应的电磁场分布。目前，金微纳颗粒表面等离激元除了在可见光波段内被大量研究和应用外，在中红外波段内也显示出独特的光谱特性，具备设计生产优良传感器的潜力，因而同样备受瞩目。研究表明，在中红外波段内设计表面等离激元传感器的关键问题在于如何有效地调节共振谱的共振波长、峰值吸收率以及半峰宽等主要特征参数。相比于单个微纳颗粒而言，阵列结构由于拥有良好的周期性，从而能够在上述参数的宽光谱调节方面具有独特的优势。基于此，提出一种基于金微纳颗粒组成的阵列结构，利用时域有限差分方法，在4～18 μm波段范围内，通过分别改变该阵列的结构参数，包括颗粒半径、高度、间距及颗粒形状等，系统地研究了该微纳阵列结构在中红外波段对入射光的反射光谱、透射光谱和吸收光谱等特性的影响。研究发现，在8～10 μm光谱内，入射光能够与其所激发的金微纳阵列表面等离激元产生共振效应，表现出明显的共振峰特性。可以通过分别改变上述结构参数来有效调节吸收率谱线共振峰的共振波长、峰值吸收率和半峰宽等主要特征参数。研究结果对中红外光谱内基于金微纳阵列结构传感器的科学研究和实际设计具有独特的理论应用价值。     

高光谱分辨率激光雷达鉴频器的设计与分析

提出了利用Fabry-Perot干涉仪的反射场实现高光谱分辨率激光雷达精细探测大气光学参量的新方法和思路.设计了高光谱分辨率的分光系统,并分析了干涉仪反射场的光谱透过特征曲线.结合高光谱激光雷达探测信号特征,讨论分析了谱分离比和瑞利信号透过率随反射率和腔长的变化曲线,同时结合误差传递公式,建立了仿真分析模型,讨论了回波光束发散角和入射角变化对激光雷达探测结果的影响.结果表明,所提出的Fabry-Perot干涉仪反射场可以实现高光谱分辨率激光雷达探测系统的精细分光,同时探测结果误差随回波光束发散角变化不敏感,控制发散角在10 mrad以内,入射角在1.5 mrad以内时,可以实现气溶胶光学参数廓线的高精度探测.     

Perovskite-type oxide films combined with gratings for reduction of material consumption and improvement of thermochromism property

Combination of thermochromism of perovskite-type materials and gratings can result in some interesting variations of the spectral properties of structured surfaces. This paper aims at investigating thermal absorptive/radiative characteristics of structured thermochromic material La_0.825Sr_0.175MnO₃ (LSMO) with metallic and/or dielectric gratings. Numerical computation is conducted to obtain the distribution of the spectral absorptance of such structured surfaces with different structural parameters. The directional and temperature dependence of absorptance are also analyzed. The results reveal that compared with bulk LSMO material, the structured surface of LSMO achieves an improved thermochromic performance and much thinner layer of a structured LSMO film by combining the film with one-dimensional Al and SiO₂ gratings. Therefore, the other advantage of such structured surface is that the reduction of material consumption and weight is achieved due to the smaller LSMO layer thickness, which may be vital for thermal management of space vehicles.     

非对称银纳米双环表面等离激元光谱特性

贵金属纳米材料在入射光激发下能够产生表面等离激元,即金属表面自由电子产生集体振荡。当其振荡频率与入射光频率相同时,发生表面等离激元共振,形成一种特殊的电磁场模式和光谱特性。利用该电磁场模式和光谱特性, 能够调节金属纳米材料的光谱学行为,例如通过改变金属纳米结构的大小、形状以及周围介质介电常数等参数, 在微纳尺度上实现光谱学信号的有效调控。目前,除了具有一定对称性的贵金属纳米材料被大量研究和应用外,非对称纳米结构的表面等离激元光谱特性也受到广泛关注。研究表明,在可见-近红外波段光谱范围内设计表面等离激元光电传感器件的关键问题在于,如何有效地调节其消光谱的共振波长、半峰宽以及峰值强度等主要特征参数。提出一种基于银纳米双环组成的非对称结构,利用时域有限差分方法,在可见-近红外波段内,通过分别改变银纳米双环的尺寸、间距及入射光偏振方向等参数,计算了该纳米结构在不同条件下的消光谱。结果表明,在0.4～3 μm的消光谱内,入射光能够激发产生两个独立的表面等离激元共振峰。通过研究峰值波长处的电场分布图发现,上述共振峰分别对应两种不同的电磁场模式。结果还表明,消光谱内两个独立的共振峰可以通过改变该双环结构的不同参数,被分别地进行调节。其中,可以通过改变该双环结构的半径来有效调节短波长峰的共振波长和半峰宽,同时保持长波长峰的共振波长和半峰宽基本不变。此外,通过改变两环间距或入射光偏振方向,可以分别以不同趋势来调节两个共振峰的峰值强度。在提出的非对称银纳米双环的消光谱中,获得了能够被分别调节的两个表面等离激元共振峰,研究结果能够为可见-近红外波段内基于银纳米材料光电传感器件的开发设计提供理论基础。     

低温辐射计不同结构黑体腔吸收率仿真与实验测量

目前,国际最高光辐射功率基准为低温辐射计,其可探测光谱范围覆盖真空紫外到太赫兹波段（115 nm~THz）,利用真空低温超导条件下的电替代测量原理,将光辐射功率参数溯源到可以精确测量的电参数进行高精度测量,实现超宽光谱范围的光辐射绝对功率测量,其测量不确定度达到10-5量级,尤其在国防军事和光辐射计量领域,光电有效载荷、定量遥感、超高光谱成像以及光辐射量值溯源等应用领域具有不可替代的作用。低温辐射计黑体腔作为光辐射吸收的核心器件,具有光谱吸收平坦、0.999以上的超高吸收比,其吸收率参数是影响低温辐射计高准确测量的主要因素之一。目前,针对低温辐射计黑体腔不同结构及涂层参数开展了很多的理论及仿真工作,但针对不同结构参数黑体腔吸收率的实验测量及比对工作还未见报道。因此,为实现低温辐射计宽光谱、高精度测量要求,光电子一级站开展了适用于低温辐射计的黑体腔研制及吸收率测量的研究工作。课题组研制了四种不同结构参数,以高电导无氧铜（OFHC）为材质,壁厚0.1 mm,内壁电镀镍磷黑（NiP）涂层的超高吸收率黑体腔;采用蒙特卡罗光线追迹算法分别对四种结构黑体腔吸收率进行了光学仿真,得到不同结构参数之间的吸收率差异;采用替代法测量吸收率,搭建了以高稳定光源、积分球系统组合的黑体腔吸收率测量装置,通过将标准白板与黑体腔之间切换,准确测量黑体腔吸收率,并分析了黑体腔吸收率的影响因素。实验结果表明：（1）通过比对仿真数据与实验测量结果,验证测量方法的有效性和测量数据的可靠性;（2）研制的黑体腔实现了(0.999 962±0.000 005)@632.8 nm的超高光谱吸收率,满足了低温辐射计的高精度测量要求;（3）斜底圆柱腔的吸收性能优于圆锥柱腔;（4）通过设计螺纹结构增加腔内表面积、设计圆锥口径类比光阑结构形式并没有明显增加黑体体吸收率。     

Total light absorption in a wide range of incidence by nanostructured metals without plasmons

Metals structured by nanocavities have recently been demonstrated to efficiently absorb light in a wide range of angles of incidence. It has been assumed that nanovoid plasmons are at the origin of the strong absorption. It is shown that it is possible to totally absorb incident light without plasmons. To avoid their excitation, a diffraction grating consisting of cylindrical cavities in a metallic substrate is illuminated in transverse electric polarization. It is found that cylindrical cavities can sustain cavity resonances with a high enhancement of the light intensity, provoking a total absorption of light in a wide range of incidence.     

基于亚波长二维光栅的入射角不敏感颜色滤光片研究

提出了一种基于二维亚波长光栅的具有非偏振光入射下入射角不敏感特性的反射式颜色滤光片. 采用严格耦合波分析方法详细分析了光栅周期、光栅层厚度以及固定光栅占空比下光栅的结构尺寸对反射率峰值、反射带位置及带宽的影响. 结合入射角不敏感特性, 经过优化设计得到了光栅的最终结构参数, 获得了中心波长424 nm, 峰值反射率56%, 带宽45 nm的反射滤光片.模拟结果表明, 在非偏振光入射下, 此滤光片的反射光谱表现出显著的入射角不敏感特性. 当入射角高达60°时反射带的中心波长偏移6 nm 反射率下降6%带宽增加8 nm 其参数没有较大变化通过调整光栅的结构参数可在400–520 nm范围内调节滤光片的中心波长以获得不同颜色的入射角不敏感滤光片. 关键词： 反射式滤光片 二维亚波长光栅 入射角不敏感 严格耦合波分析     

Surface enhanced Raman scattering of molecules related to highly ordered gold cavities

We presented a controlled particles‐in‐cavity (PIC) pattern for surface‐enhanced Raman scattering (SERS) detection. The periodic gold cavity array was fabricated by electrodeposition using highly ordered polystyrene spheres as a template. The as‐prepared gold cavities can be used as a SERS active substrate with significant spectral enhancement and reproducibility, which was evaluated by SERS signals using 4‐mercaptobenzoic acid (4‐MBA) as probe molecules. The surface of these gold cavities was further functionalized with cetyltrimethylammonium bromide molecules, which may immobilize the 4‐MBA‐modified silver nanoparticles in the gold cavity to form a PIC structure via the electrostatic interaction. We have demonstrated that there exists a pH window for the immobilization of the nanoparticles inside cavities. Therefore, the silver nanoparticles can be selectively immobilized into the functionalized gold cavities under the optimized pH value of the media. Further enhancement of the Raman scattering of the labeled molecules can be achieved due to the interconnection between the silver nanoparticles and gold cavity. Copyright © 2013 John Wiley & Sons, Ltd.     

Different optical properties in different periodic slot cavity geometrical morphologies

In this paper,optical properties of two-dimensional periodic annular slot cavity arrays in hexagonal close-packing on a silica substrate are theoretically characterized by finite difference time domain(FDTD) simulation method.By simulating reflectance spectra,electric field distribution,and charge distribution,we confirm that multiple cylindrical surface plasmon resonances can be excited in annular inclined slot cavities by linearly polarized light,in which the four reflectance dips are attributed to Fabry–Perot cavity resonances in the coaxial cavity.A coaxial waveguide mode TE11 will exist in these annular cavities,and the wavelengths of these reflectance dips are effectively tailored by changing the geometrical pattern of slot cavity and the dielectric materials filled in the cavities.These resonant wavelengths are localized in annular cavities with large electric field enhancement and dissipate gradually due to metal loss.The formation of an absorption peak can be explained from the aspect of phase matching conditions.We observed that the proposed structure can be tuned over the broad spectral range of 600–4000 nm by changing the outer and inner radii of the annular gaps,gap surface topography.Meanwhile,different lengths of the cavity may cause the shift of resonance dips.Also,we study the field enhancement at different vertical locations of the slit.In addition,dielectric materials filling in the annular gaps will result in a shift of the resonance wavelengths,which make the annular cavities good candidates for refractive index sensors.The refractive index sensitivity of annular cavities can also be tuned by the geometry size and the media around the cavity.Annular cavities with novel applications can be implied as surface enhanced Raman spectra substrates,refractive index sensors,nano-lasers,and optical trappers.     

Mechanism investigation of a narrow-band super absorber using an asymmetric Fabry–Perot cavity

We propose a metal–insulator-metal super absorber based on an asymmetric Fabry–Perot cavity, by which a perfect narrow-band absorption can be achieved. In this structure, two silver layers form a cavity spaced by a lossless silicon oxide layer. The absorption of the absorber can reach about 98% and its absorption peak can be tuned by altering the thickness of the middle SiO₂ layer. We further present a deep comprehension on the physics mechanism of such high absorption. This super absorber can be easily fabricated by mature thin film technology, which make it an appropriate candidate for photodetectors, sensing, and spectroscopy.     

TM模场入射到金属光栅的表面增强喇曼散射计算分析

以纳米量级金属履带矩形光栅为模型,研究了表面增强喇曼散射的特性.针对TM模的入射光,采用严格的耦合波原理对金属表面的衍射场进行了分析,并用数值计算方法讨论了光栅深度、光栅占空比等参量对金属表面增强的影响以及增强因子随光栅深度的变化关系.结果显示：当入射光波长为700 nm、入射角度为10°、光栅周期p=600 nm、 光栅深度d=37.5 nm、占空比为1/3时,获得最大增强,增强因子G达104倍.     

Tunability of temperature-dependent absorption in a graphene-based hybrid nanostructure cavity

Enhanced absorption is obtained in a hybrid nanostructure composed of graphene and one-dimensional photonic crystal as a cavity in the visible wavelength range thanks to the localized electric field around the defect layers. The temperature-induced wavelength shift is revealed in the absorption spectra in which the peak wavelength is red-shifted by increasing the temperature. This temperature dependence comes from the thermal expansion and thermo-optical effects in the constituent layers of the structure. Moreover, the absorption peaks can be adjusted by varying the incident angle. The results show that absorption is sensitive to TE/TM polarization and its peak values for the TE mode are higher than the TM case. Also, the peak wavelength is blue-shifted by increasing the incident angle for both polarizations. Finally, the possibility of tuning the absorption using the electro-optical response of graphene sheets is discussed in detail. We believe our study may be beneficial for designing tunable graphene-based temperature-sensitive absorbers.     

Investigation on the transmission of subwavelength metallic cavity arrays

Numerical investigation of the optical transmission through the one-dimensional subwavelength metallic cavity arrays (SMCA) is presented. Based on the finite-difference time-domain technique, we discuss the influence of the structural parameters on the transmission spectrum. The transmission peaks are attributed to the Fabry-Perot resonance; and the transmission dips are attributed to the surface plasmon resonance. For the SMCA with two cavities in one unit, the redshift of the transmission peak with increasing the distance between the two cavities originates from the depression of the coupling strength. These results obtained here will be helpful to design the plasmonic frequency-selecting device.     

Ultra-broadband absorber based on cascaded nanodisk arrays

An ultra-broadband perfect absorber consisting of cascaded nanodisk arrays is demonstrated by placing insulator-metal-insulator-metal nanodisks on insulator-metal film stacks. The absorber shows over 90% absorption in a wavelength range between 600 nm and 4000 nm under transverse magnetic (TM) polarization, with an average absorptivity of 91.5% and a relative absorption bandwidth of 147.8%. The analysis of the electric field and magnetic field show that the synergy of localized surface plasmons, propagating surface plasmons, and plasmonic resonant cavity modes leads to the ultra-broadband perfect absorption, which accords well with the results of impedance-matched analysis. The influences of structural parameters and different metal materials on absorption performance are discussed. Furthermore, the absorber is polarization-independent, and the absorption remains more than 90% at a wide incident angle up to 40° under TE polarization and TM polarization. The designed ultra-broadband absorber has promising prospects in photoelectric detection and imaging.     

Numerical simulation of the optical reflection and transmission coefficients of a periodic surface of metallic nanowire grating

The optical reflection and transmission coefficients of a metallic nanograting have been studied with the use of numerical simulation in a wide range of the size of structural units of the grating. The grating is composed of silver nanowires arranged periodically on a quartz substrate. The cases of s- and p-polarized incident waves have been considered. In particular, it has been found that the spectral dependence of the reflection and transmission coefficients of the nanograting becomes oscillatory and exhibits several deep minima when all structural parameters of the grating (the nanowire’s width and height, and the grating period) approach tens of nanometers. The physical reason of the appearance of these oscillations has been analyzed. It has been shown how the depth and position of the discovered minima depend on the light angle of the incident wave and the rotation angle of the grating around its normal surface.     

等离子体密度凹坑对光波的吸收作用

用数值计算方法研究有密度凹坑的等离子体对P偏振入射光的吸收,结果表明,如果密度凹坑及其周围密度分布取得适当参数,吸收峰值可以达到近100%,即远超过线性密度等离子体共振吸收的峰值50%;吸收曲线随入射角变化呈现双峰值结构.密度凹坑就象个共振谐振腔,从腔内的透射光与第一个反射面的反射光干涉相消,使总反射光变弱,由此导致了大的吸收率.     

磁力负刚度薄膜结构低频吸声特性

针对背腔深度较小的薄膜吸声结构难以实现低频吸声的问题,提出了磁力负刚度的解决方法。采用传递矩阵法,建立了负刚度薄膜吸声结构理论模型,分析得出该结构的声阻抗等同与大背腔常规薄膜吸声结构的声阻抗;阻抗管实验验证得出,在一定磁场条件下,不同背腔的负刚度薄膜吸声结构与无负刚度结构相比其共振频率显著下降,吸声系数曲线与理论结构吻合。负刚度机制能够降低薄膜吸声结构的共振频率,用较小背腔实现低频吸声,从而实现薄型低频吸声结构设计。      

Design of a β=0.45, f=350 MHz Spoke Cavity

Recently intensive studies have been done on superconducting cavities (e.g. spoke cavity, reentrant cavity, and ch cavity), which are used as accelerating structures in the low and medium energy part of high power high intensity proton or ion accelerators. many experiments have shown that spoke cavity is a good candidate for low energy part. it is also promising to be used for the medium β area. so a β=0.45 spoke cavity is being studied at Peking university. in this paper, the structural and electromagnetic design of a β=0.45, f=350mhz spoke cavity is reported in detail. the calculated rf parameters (e.g. Q, r/Q, peak surface fields and dissipated power) indict a potential of good acceleration.     

二维银球腔阵列的制备及其在SERS检测中的应用

以密堆积的700 nm单分散聚苯乙烯微球为模板,采用多电流阶跃方法制备了不同深度的二维有序微/纳尺度银球腔阵列。通过扫描电子显微镜,反射紫外对球腔形貌及表面等离子体共振进行了表征,以对氨基苯硫酚及罗丹明6G为探针分子进行了表面增强拉曼光谱(SERS)的研究。结果表明,通过控制电化学沉积的条件可以实现对球腔形貌的控制。以该种球腔阵列作为SERS基底,其增强因子可达107,并具有良好的信号重现性,信号间相对标准偏差小于8%。该基底用于对罗丹明6G的定量检测,检测限可达0.1 ng·mL-1。     

不同类型银纳米粒子的吸收和拉曼增强特性的关系研究

一直以来,将纳米结构材料用于其表面增强拉曼散射(SERS)时会先测试其吸收光谱,因为一般研究认为,纳米结构材料产生SERS的原因是纳米结构材料对于入射光的吸收产生了局域表面等离子体共振(LSPR),因此我们常把SERS的增强因子随波长变化的曲线等同于吸收光谱曲线。近年来,有学者认为两者之间的联系可能是非常间接的,并且在许多情况下会产生误导。为了能够阐明两个之间的具体关系,考虑到银纳米粒子(AgNPs)以其局域表面等离子体共振而显著提高拉曼散射的能力而闻名, 是制备SERS基底的理想纳米材料,我们从实验和理论两个角度研究了三种不同状态的AgNPs中表面增强拉曼散射的增强因子(EF)、吸收光谱以及空间的电场分布。实验上,利用化学还原法制备了银溶胶(Ag-sol),并对Ag-sol做了透射电子显微镜(TEM)、紫外可见分光光度计(UV-Vis)以及拉曼的表征实验,统计和计算了银溶胶的EF和吸收光谱。理论上,利用仿真软件COMSOL Multiphysics建立了不同聚合类型AgNPs的仿真模型,模拟计算了与实验相对应的EF随波长变化的曲线以及吸收光谱。结果表明：表面等离子体共振的空间分布对吸收和最大EF值起着重要的作用;具有固定位置的共振吸收峰(第一个峰位)主要受“单颗粒类型”效应的影响,而最大EF处的吸收峰(第二个峰位)由“耦合间隙类型”效应引起的蓝移谐振峰主导,且最大EF值及第二个吸收峰的峰位会随着粒子的间隙、偏振角度等因素而变化。研究表明,AgNps样品的吸收光谱和最大EF曲线之间是部分相关的。