Spectral superbroadening of self-focused picosecond laser pulses in D2O

Intense picosecond light pulses of a mode-locked Nd: glass laser at _L =1054 nm (fundamental wavelength) and _SH =527 nm (second harmonic wavelength) are passed through a sample of D₂O under self-focusing conditions. Spectrally structured superbroadened, spatially bell-shaped emission in the forward direction is obtained. Primary generation processes are pump-pulse-degenerate stimulated parametric four-photon interaction (₁ + _{1 3} + ₄) and stimulated Raman scattering (_{1 R} + ), which occur concurrently (₁= _L or _SH angular pump frequency, #x03C9; _R first Stokes frequency, #x03C9; signal frequency, #x03C9;₃ signal frequency, #x03C9;₄ idler frequency). The parametric four-photon interaction occurs under collinear non-phase-matched conditions and under longitudinally phase-matched, transversally non-phase-matched (erenkov-like) conditions. Subsequent interaction processes are pump-pulse-nondegenerate four-photon interaction of the type ₁ + _{R 3} + ₄, coherent antiStokes Raman scattering (CARS, ₁ + ₁ – _{4 3}), inverse Raman scattering ( _A + ₁ + ), and cascading light up-conversion of the type ₁ + _(i) – _{R (i+1)}.     

Calculation of the dispersion of the third-order optical nonlinearity in C60 films

Using wave functions determined from ground-state local-density calculations, we have calculated the wave-dispersed free response of the optical nonlinear polarizability ⁽³⁾(–3;,,), for the C₆₀ molecule and ⁽³⁾(–3;,,) i.e. Third-Harmonic Generation (THG) for films using a sum-over-states approach. The influence of screening was determined by applying an external static electric field in separate selfconsistent calculations to evaluate induced dipole moments which was used to determine the static linear and nonlinear polarizabilities. The polarizabilities calculated in the static limit were used to determine an effective screening parameter which was, in turn, used together with an RPA approach to calculate screened wave-dispersed, third-order nonlinear optical properties such as ⁽³⁾(–3;,,) and ⁽³⁾(–3;,,). Comparing evaluated polarizabilities with experimental values we found that the non-resonant free polarizability compares well in absolute magnitude with experimental results. Inclusion of screening results in a polarizability about two orders of magnitude below the experimental values.Paper presented at the 129th WE-Heraeus-Seminar on Surface Studies by Nonlinear Laser Spectroscopies, Kassel, Germany, May 30 to June 1, 1994     

CW coherent VUV radiation generated by resonant sum-frequency mixing in metal vapors

Resonant third-order sum-frequency mixing of continuous-wave visible and ultraviolet laser light is investigated in the metal vapors of Sr, Ca, Mg, and Zn. The laser radiation (with the frequencies ₁, ₂, and ₃) is generated by single-mode dye- and argonion lasers. The third-order nonlinear susceptibility is enhanced by tuning the laser frequencies 2₁ or ₁+₂ to a two-photon resonance. The wavelength of the generated coherent VUV radiation (with the frequency _VUV=3₁, _VUV=2₁+₂ or _VUV=₁+₂+₃) is tunable in spectral regions between 133 and 217 nm. For most conversion processes an additional enhancement of the nonlinearity is provided by an autoionizing level or by a highly excited state close to E=_VUV. With laser powers of 0.2–3 W the power of the generated sum frequencies is in the range of 5×10⁵–6×10¹⁰ photons s^–1 (0.5 pW–60 nW).     

Two-photon absorption and resonant non-phase-matched second-harmonic generation in CdSe

Exciting a hexagonal CdSe crystal with picosecond Nd: glass laser pulses, two-photon absorption and resonant non-phase-matched second-harmonic generation occur simultaneously. Using different crystal orientations, all components of the secondharmonic susceptibility tensor (non-vanishing components ared ₃₁,d ₃₃ andd ₁₅) and some components of the two-photon absorption susceptibility tensor _ijkl ⁽³⁾ (–_L; _L, _L, –_L) are determined.     

Linear and non-linear ac response of the stochastic classical model for sliding charge density waves

A comprehensive study of the ac response properties of the classical stochastic model for sliding charge density waves (CDW) in quasi one-dimensional metals is made by numerically solving the associated Fokker-Planck equation. Above the conductivity threshold a noise mechanism is indispensable to give finite line widths to the resonances of the applied ac signal of frequency with the narrow band noise frequency _OSC inherent in the model. In the present investigation a current noise of strengthT _N proportional to the CDW current is used in the Fokker-Planck equation in order to model the broad band current noise frequently observed above threshold. The present model thus incorporates three characteristic frequency scales: _OSC,T _N ,and a crossover frequency _OSC. Results are evaluated for the ac conductivity (;E ₀,E ) as function of frequency , dc bias electric fieldE ₀ and ac signal field strengthE . ForE 0 the linear ac response is obtained by a separate treatment of the Fokker-Planck equation. The resonances near =_OSC are studied in detail. Strong ac signals reduce the response at the fundamental resonance and lead to a harmonic interference structure nearn=_OSC. The overall agreement of the present results with recent measurements of the linear ac response is not good. In reality our results seem to be superimposed on a background not reproduced by the classical model with one cross over frequency. However, the peak in Im (;E ₀,E =0) vs.E ₀, when the narrow band noise frequency is near , is well reproduced. The spectral width of this peak which corresponds to the inductive dip in the susceptibility is studied as function of current noise strengthT _N .The results stress the need for a complete Fokker-Planck treatment sinceT _N is not simply related to the line width.     

Dynamics of vector spin glasses: The Gabay-Toulouse line

The dynamics of ann-component vector spin glass with infinite range interactions are investigated near and above the Gabay-Toulouse (GT) line. The local transverse susceptibility _T for 0 varies along the whole GT lineT _c1 (H) as ^v , with a field and temperature independent critical exponentv=1/2. The longitudinal susceptibility _L () remains analytic for all (T, H)T _c1 (H), except for a cross-over fromv=1 tov=1/2 forH0 at the freezing temperatureT=T _f . The dynamic susceptibilities _T () and _L () are already coupled above the GT line via self-energy terms. BelowT _c1 (H), this coupling is strongly enhanced by other mechanisms.     

Static and Vibrational Properties of Transition Metals

A model pseudopotential depending on an effective core radius but otherwise parameter free is proposed to study the equation of state by incorporating the s-d hybridization effects. Very recently proposed screening function due to Sarkar et al has been used to obtain the screened form factor. The equations of state for Cu, Ta, Mo, W and Pt have been studied up to the pressure of 1000 GPa. The vibrational properties such as phonon dispersion curves (in q and r space), phonon density of states, mode Grüneisen parameters, maximum frequency _max, mean frequency , ^21/2 = (/ ^-1)^1/2 and fundamental frequency ² and static properties such as dynamical elastic constants of rhodium and iridium are also calculated. The theoretical results are compared with experimental findings wherever possible. A good agreement between theoretical investigations and experimental findings has confirmed our formulation.     

Harmonic mixing by weakly pinned charge density waves

Third order harmonic mixing voltageE ₀ in case of frequency matching, =₂–₁=0, and third order pseudo harmonic mixing currentj() in the detuned case, 0, are evaluated for the one-dimensional Fukuyama-Lee-Rice model for weakly pinned charge density waves in the region of sub-threshold bias electric fields. After a perturbation expansion of the phase response to the ac driving fields the impurity averaging is performed diagrammatically. Specific statistical properties of the charge density wave phase in the weak pinning limit and a non-trivial result for the pinning of the static phase are utilized to expressE ₀ andj() in terms of the dielectric function (). A recent evaluation of () within the self-consistent Born approximation is used to present the results explicitly in a number of diagrams. In comparison to the overdamped anharmonic oscillator the following differences are found: Randomness leads to interference contributions which increase the amplitudes and decrease the phase shifts. The more realistic form for () at lower frequencies lead to a downward shift in the maximum ofj() when ₁ is decreased below the cross-over frequency _c . The present theory retains inertia in the dynamical equations and remains valid for frequencies near and above the pinning frequency. It fails, however, for small frequencies _{1 c} due to the neglect of metastable states and screening.     

Enhancement of activated decay of metastable states by resonant pumping

We consider the effect of a high-frequency pumping cost on the escape rate of a classical underdamped Brownian particle out of a deep potential well. The energy dependence of the oscillation frequency(E) is assumed to be weak on the scale of thermal energy,_E(0)T(0)T/V₀ (0)[_E(0) is the derivative of(E) atE= 0,V ₀ is the barrier height,V ₀ T]. The quadratic-in- contribution to the decay rate is calculated in two different regimes: (1) for the case of resonance of the pumping frequency with the nth harmonic of the internal motion at an energye, when = n(e); (2) for a rollout region of the basic resonance near the bottom of the potential well, when ¦-(0)¦ and is the damping coefficient. In the latter case the absorption spectrum and the enhancement of the decay rate are calculated as functions of two reduced parameters, the anharmonicity of the potential,v _E (0)T/, and the resonance mismatch, [ —(0)]/. It is shown that the effect of the pumping increases with diminishing ¦v¦ and at small v is proportional tov ^–1. In this regime, the dependence on is stepwise: the pumping contribution is large for v > 0 and small for v < 0. In the frame of our theory, the decay rate is invariant against the simultaneous alternation of the signs of andv. The spectrum of the energy absorption has the standard Lorentzian shape in the absence of anharmonicity,v=0, and with increasing of ¦v¦ shifts and widens retaining its bell-shape form.     

Generation of more than 40 laser emission lines from the ultraviolet to the visible regions by two-color stimulated raman effect

An intense and monochromatic laser beam consisting of more than 40 vibrational and rotational lines is generated by the stimulated Raman effect, when two-color laser beams separated by 590 cm^–1 are tightly focused into pressurized hydrogen. This phenomenon is reasonably explained by four-wave mixing; one beam is used for two-step excitation (₁+₁) to an imaginary level and another beam (₂) acts as a seed beam, generating a fourth beam (2₁–₂). Through cascade processes, so many laser emissions appear with a frequency difference of (₁–₂) in entire ultraviolet and visible regions.     

Ferromagnetic resonance in media with an inhomogeneous saturation magnetization

The method of transition probabilities is used to calculate the line width of ferromagnetic resonance in a medium with an inhomogeneous saturation magnetization. It is shown that in addition to linear (with respect to the Fourier components of the function describing inhomogeneities) terms, the perturbation Hamiltonian must include also quadratic terms. The frequency dependence of the contribution of the porosity to H is fundamentally different from the frequency dependence of the magnetic anisotropy contribution. This anisotropy contribution H_a() decreases on increase in the frequency and has a maximum at = (2/3)_M, whereas the porosity contribution H_p increases on increase in the frequency and vanishes at = (2/3)_M.deceasedTranslated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp.48–52, December, 1980.     

Normal mode configuration in an inorganic medium containing defects

The vibrational structure in an inorganic medium containing defects is analyzed as a function of the frequency of the applied field. Since the dispersion relations for the medium are nonlinear, the configuration of the normal modes depends differently upon and . It is shown that exponential damping of the optic branches is observed for <₀, and that the structure of these modes changes significantly over the range 0<<₀, so that only in the neighborhood of ₀ does it correspond to long wavelength vibrations with configurations of stress deviator waves.Institute for the Physics of Strength and Materials Science, Russian Academy of Sciences, Siberian Division. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 87–90, October, 1994.     

Some exact models for nonspherical collapse. III

The gravitational nonradiative collapse of dust configurations in the presence of electromagnetic field is analyzed in terms of exact dynamical solutions for a wide range of spacetime symmetries: cylindrical, pseudoplanar, toroidal, and also spherical, planar, and pseudospherical [when the anisotropy factor of the (x ²,x ³) surfaces,(R, T), is replaced by a massless scalar field]. The condition that the collapse is nonradiative leaves three possibilities for the coordinate dependence of(R,T) (i)=(a),a (R, T) being the scale factor of the (x ²,x ³) surfaces, (ii)=(T), and (iii)=(R). Almost all (in the meaning indicated in the text) solutions for charged dust with=(a) and for dust in the external electromagnetic field with=(T) and=(R) have been obtained and discussed. A wideranging discussion concerning the topics of papers I–III is given. Special attention is paid to the question of horizon existence and formation and also the perspective of extension of the techniques developed onto the more realistic case of axial symmetry.     

Low frequency limits of third-order harmonic coefficients for atomic hydrogen in any level of discrete energy spectrum

In this paper the analytical expression is derived for the third-order optical harmonic coefficients x _abcd ^v (,,) of the atomic hydrogen at very low frequencies 0 in many level of the discrete energy spectrum.The author expresses his thank to Prof. Nguyen Van Hieu for suggesting the problem and fruitful discussions.     

The Hamiltonian of the guiding centre in the electromagnetic field

The Hamiltonian of the guiding centre in an adiabatically variable electromagnetic field (for the relative variations of the field 1/H. dH/dt _c , 1/E. dE/dt _c ) is derived in the present paper.The solution of the corresponding canonical equations is given for an axially symmetric stationary electromagnetic field.     

Excited-state absorption and third-order optical nonlinearities in symmetric π-electron organic molecules

Excited-State Absorption (ESA), Two-Photon Absorption (TPA) and the third-order polarizability (;,, – ) have been investigated for a model dichloride derivative of a symmetrically substituted benzylidene analine (SBAC), using a multielectron configuration-interaction procedure. The calculations indicate that SBAC exhibits ESA across the visible region of the spectrum, but that it is not as extensive as for molecules such as the phthalocyanines. The magnitude of the third-order polarizability is dominated by resonance enhancement from a very strongA _g B _u one-photon absorption. The calculated off-resonance value for (;,, – ) suggests that SBAC is a potential candidate for ultrafast switching applications.     

Classical “freezing” of plane rotations: A proof of the Boltzmann-Jeans conjecture

Using simple known methods and results of classical perturbation theory, especially those due to Nekhoroshev and Neishtadt, we study the energy exchanges between the rotational and the translational degrees of freedom in a particular model representing the planar motion of a rigid body in a bounded analytic potential. We prove that, if the angular velocity is initially large, then the energy exchanges are small,O( ^–1), for times growing exponentially with, |t|exp. We also deduce that in a scattering process from a (smooth) potential barrier, the overall change in the rotational energy of the incoming body is exponentially small in, exp(–. The results are interpreted in the light of an old conjecture by Boltzmann and Jeans on the existence of very large time scales for equilibrium in statistical systems containing high-frequency degrees of freedom (purely classical freezing of the high-frequency degrees of freedom); the rotating object is, in this interpretation, a (classical) molecule, which moves in an external field, or collides with the wall of a container. Two different limits of large are considered, namely the limit of large rotational energy, and (as is interesting for the molecular interpretation) the limit of point mass, at finite rotational energy.     

Directed paths on percolation clusters

We consider a variant of the problem of directed polymers on a disordered lattice, in which the disorder is geometrical in nature. In particular, we allow a finite probability for each bond to be absent from the lattice. We show, through the use of numerical and scaling arguments on both Euclidean and hierarchical lattices, that the model has two distinct scaling behaviors, depending upon whether the concentration of bonds on the lattice is at or above the directed percolation threshold. We are particularly interested in the exponents and, defined by ft and xt , describing the free-energy and transverse fluctuations, respectively. Above the percolation threshold, the scaling behavior is governed by the standard random energy exponents (=1/3 and =2/3 in 1+1 dimensions). At the percolation threshold, we predict (and verify numerically in 1+1 dimensions) the exponents=1/2 and =v/v, where v and v are the directed percolation exponents. In addition, we predict the absence of a free phase in any dimension at the percolation threshold.     

Electromagnetic Modes in Schwarzschild Geometry in an Annular Region

The fundamental electromagnetic modes in a spherical annular cavity with perfectly conducting walls at r = a and r = b are calculated, in the presence of a weak Schwarzschild gravitational field. Explicit expressions are given for the case of a thin shell, (b - a)/a 1. The modified angular frequency for mode ,m can be written as = = ₀ \{ 1 - (GM/a)[2 - ( + 1)/(₀ a)²] where ₀ is the nongravitational frequency. This formula (being independent of m) holds for the magnetic as well as for the electric modes.     

Structure factor of substitutional sequences

We study the structure factor for a large class of sequences of two elementsa andb such that longer sequences are generated from shorter ones by a simple substitution rulea ₁(a, b) andb ₂(a, b), where the's are some sequences ofa's andb's. Such sequences include periodic and quasiperiodic systems (e.g., the Fibonacci sequence), as well as systems such as the Thue-Morse sequence, which are neither. We show that there are values of the frequency at which the structure factors of these sequences have peaks that scale withL, the size of the system likeL ⁽⁾. For a given sequence a simple one- or two-dimensional dynamical iterative map of the variable can easily be abstracted from the substitution algorithm. The basin of attraction of a given fixed point or limit cycle of this map is a set of values of at which there are peaks of the structure factor all of which share the same value of. Furthermore, only those values of which are in the basin of attraction of the origin can have()=2. All other peaks will grow less rapidly withL. We show how to construct many sequences which, like the Thue-Morse sequence, have noL ² peaks. Other qualitative features of the structure factors are presented. Our approach unifies the treatment of a large class of apparently very diverse systems. Implications for the band structure of these systems as well as for the analysis of sequences with more than two elements are discussed.