两种电场结构下离子运动轨迹模拟与实验对比研究

结合最新的离子与分子碰撞模型,编写在Simon 7.0平台下的离子运动模拟程序,实现了在漂移管电场中离子运动轨迹的模拟,开展在两种漂移管电极结构即均匀电场和周期性聚焦电场下离子的运动轨迹模拟与质子转移反应质谱(PTR-MS)实验检测对比研究,得到了常见有机物的可探测灵敏度,发现周期性聚焦电场PTR-MS的性能总体上要比均匀电场PTR-MS好,可探测灵敏度增加了5~9倍,显示了通过对离子运动轨迹的理论模拟在仪器性能优化与改进上的优势,同时该方法具有用于提高其他质谱检测仪器灵敏度的巨大潜力.     

两种电场结构下离子运动轨迹模拟与实验对比研究

结合最新的离子与分子碰撞模型,编写在Simon 7.0平台下的离子运动模拟程序,实现了在漂移管电场中离子运动轨迹的模拟,开展在两种漂移管电极结构即均匀电场和周期性聚焦电场下离子的运动轨迹模拟与质子转移反应质谱(PTR-MS)实验检测对比研究,得到了常见有机物的可探测灵敏度,发现周期性聚焦电场PTR-MS的性能总体上要比均匀电场PTR-MS好,可探测灵敏度增加了5～9倍,显示了通过对离子运动轨迹的理论模拟在仪器性能优化与改进上的优势,同时该方法具有用于提高其他质谱检测仪器灵敏度的巨大潜力.     

硫离子修饰的金纳米棒用于汞离子检测

表面修饰硫离子的金纳米棒可与汞发生相互作用,导致体系的共振光散射（RLS）和紫外-可见吸收光谱发生变化。利用这种特殊的选择性结合反应建立了一种采用RLS技术定量检测水溶液中汞离子的新方法。在优化的实验条件下,汞离子分析测定的线性范围为0.1—10.0μm ol.L^-1,检出限为0.096μm o.lL^-1。     

离子检测仪器中新型直流—射频聚焦电场电极结构性能研究

基于直流—射频电极结构对离子的径向和轴向聚焦理论,以离子检测仪器中质子转移反应质谱检测技术为例,对该新型电极结构展开理论和实验研究,相比于静电场电极结构,直流—射频聚焦电场电极结构的性能更好,丙酮产物离子强度提高了近10倍,初步的实验结果表明该结构对于提高离子相对透过率具有较大潜力,同时,该新型直流—射频聚焦电场电极结构对于提高其他类型的离子检测仪器性能将具有一定的应用潜力和参考价值.     

线型离子阱中钙离子库仑晶体结构和运动轨迹模拟

离子阱中囚禁的离子在满足库仑耦合条件下,会形成库仑晶体,其结构分布和运动轨迹由离子阱的参数和离子种类决定.本文采用分子动力学模拟软件LAMMPS和(py)LIon程序包,仿真了⁴⁰Ca⁺在线型离子阱中库仑晶体的形成过程,以及不同位置离子的微运动和宏运动轨迹.另外,本文还对混入少量同位素离子(⁴⁴Ca⁺)和氢化钙离子(CaH⁺)后的⁴⁰Ca⁺晶体结构进行了仿真,并对混入前后形成的库仑晶体结构变化进行对比和分析,期望能对离子阱实验中形成的暗离子进行识别和处理.     

离子推力器加速栅极离子运动规律的数值研究

 以离子推力器栅极组件为研究对象,建立了3维数值模型,应用网格质点法研究了束流离子和电荷交换离子在栅极组件间的运动规律。根据给定的几何和物理参数,模拟得到了栅极组件附近的电势分布、束流离子和电荷交换离子的运动轨迹、速度相空间分布以及加速极电流等。模拟结果表明：加速栅极下游产生的电荷交换离子在电场的作用下会加速撞击加速栅极下游面,是造成加速栅极腐蚀的主要因素;栅极间产生的电荷交换离子会撞击到加速栅极孔壁面,使加速栅极孔逐渐增大。     

射频阱中碳原子族离子同N2的化学反应

利用激光溅方法产生并在射频离子阱中的囚禁了碳原子的簇离子，进而利用离子阱质量选择存储和离子存储时间长等特点，研究了碳原子族离子同Ｎ２的化学反应，分析了Ｎ２分子在离子阱中活化的条件和过程，根据得到的大反应产物并结合化学反应热效应的计算。分析了碳原子簇离子同Ｎ２反应的主要通道，测得了相应通道的反应物与反应产物的分支比，推算了碳原子簇离子同Ｎ２反应的速率常数，分析了碳原子簇离子同Ｎ２的反应活性力簇尺寸奇     

基于有限元方法的离子俘获装置模拟计算

利用有限元程序ANSYS,开展潘宁离子俘获装置的电场模拟计算。基于电场数据,结合Runge_Kutta_Fehlberg方法进行潘宁装置在多种模式下的离子俘获过程模拟工作,得到了准确的离子俘获结果。并对实际条件下具有偏离理想情况电极分布的俘获装置进行了优化计算及电场分析,同样实现了离子俘获过程的准确模拟。有限元方法用于离子俘获装置的电场计算以及后续离子俘获过程模拟流程的建立,为类似的电势阱离子俘获装置建造运行提供有效的技术支持。     

离子能量筛选器仿真设计

离子源作为一种离子束发射装置,常用于光学薄膜的制备中,但离子束中包含各种能量的离子,在光学薄膜制备过程中严重影响着薄膜成型后的微观结构和性能.针对目前国内外离子源普遍存在输出能谱过宽的缺点,以电磁场理论为基础,并对各能级的离子运动轨迹进行了仿真分析,设计了一种离子能量筛选器,仿真结果表明,经过筛选器筛选后能有效剔除过高...     

反应离子刻蚀ZnTe的THz辐射和探测研究

运用电光采样技术揭示了反应离子刻蚀（RIE）ZnTe晶体表面THz辐射的光学整流产生机制， 观察到0.25 ps的THz场分布.通过比较刻蚀前后以及不同刻蚀条件下ZnTe样品在不同激发功 率下的THz辐射强度，发现由于反应离子刻蚀破坏了ZnTe样品表面的有序性，晶体的电光系 数随射频功率的增加而减小.借助于计算不同刻蚀条件下ZnTe晶体的频率响应函数，分析了 随射频功率增加ZnTe晶体响应频谱展宽的现象. 关键词： THz辐射 反应离子刻蚀 ZnTe     

Scattering of ion beam by the current-driven ion wave turbulence

The effective scattering of an ion beam by the ion wave turbulence is investigated experimentally. The results are compared with the values predicted theoretically.     

Anti-scaling properties of zinc ion and copper ion in the recycling water

This paper investigated the respective applications of zinc and copper ions as inhibitors in the recycling water. The results show when their concentrations are not less than 0.5 mg L⁻¹, the treated water is clear as usual. However, their scaling on the tube wall still lasts. In the solution of zinc ion, the weight of precipitation on the tube wall always increases stably; but in the solution of copper ion, that increases less stably; besides, when the concentration of copper ion is beyond 2 mg L⁻¹, the increase of precipitation weight on the tube wall has become small. All of which showed different scaling mechanisms. For the solution of zinc ion, the scaling on the tube wall increases stably because of the homogeneous germs. However, in the solution of copper ion, the different types of copper ion germs will be adsorbed selectively by the tube wall because of heterogeneous germs, or the part of having been adsorbed germs onto the tube wall will be washed out.     

A contribution to the investigation of ion impact desorption by ion scattering

Sputtering or ion impact desorption of adsorbed layers can be directly investigated by low-energy ion scattering. Because of its specific sensitivity to surface atoms, this method provides the possibility of monitoring the decrease of the signal from the adsorbate or the increase of the signal from the substrate. Both signals were studied with He⁺ backscattering from the system O on Ni (110). The measured desorption cross-sections and the principal implications for both ways of observation are discussed. The use of the substrate signal for the desorption study can be of major advantage, particularly in the case of light adsorbates.     

Axial and radial ion movement in the plasma of an ion laser

This paper presents a theory of ion movement in the plasma of a cw ion laser considering all ions in a cross-section of the discharge tube collectively. Results are given for an experimental study of the profile of the spontaneous emission of the ArII-4880 Å line under optimal lasing conditions up to the region of output power saturation. A comparison of calculated and experimental results with respect to line shape, line width or temperature, and line shift shows satisfactory agreement.     

囚禁离子的非线性Jaynes-Cummings模型及其布居数反转演化

从描述囚禁离子与驻波激光场相互作用的Jaynes-Cummings(J-C)模型出发，导出了囚禁离子谐振动单量子共振激发相互作用的非线性J-C模型. 通过求解这一模型的系统状态随时间变化，数值研究了离子布居数反转的演化规律. 结果表明，离子布居数反转演化的崩塌-复原周期与Lamb-Dick参数η和离子在驻波激光场中的位置有关，随着η参数的增大，离子布居数反转的崩塌-复原周期变短，当离子质心的位置从驻波激光场的波节移向波腹时，离子布居数崩塌-复原的周期变长. 关键词： 驻波激光场 囚禁离子 非线性J-C模型 Lamb-Dick参数     

Evolution of the ion distribution function during HF heating at twice the ion cyclotron frequency

We derive the equation governing the ion distribution function when a toroidal plasma is heated by a radiofrequency wave at $\text{ω = 2Ω}{}_{\mathrm{<mtext>ci</mtext>}}$. A numerical integration of this equation shows that a suprathermal anisotrpic tali develops in the distribution function, as experimentally observed on the ST Tokamak.     

Penning阱离子谱中奇异峰分析

本文报道Penning离子阱中离子谱出现的奇异峰,提出鉴别它的方法,分析其产生的原因和消除它的可能性,还利用该机制设计出具有高分辨率的探测存储离子的新方法.     

All-optical ion generation for ion trap loading

We have investigated the all-optical generation of ions by photo-ionisation of atoms generated by pulsed laser ablation. A direct comparison between a resistively heated oven source and pulsed laser ablation is reported. Pulsed laser ablation with 10 ns Nd:YAG laser pulses is shown to produce large calcium flux, corresponding to atomic beams produced with oven temperatures greater than 650 K. For an equivalent atomic flux, pulsed laser ablation is shown to produce a thermal load more than one order of magnitude smaller than the oven source. The atomic beam distributions obey Maxwell–Boltzmann statistics with most probable speeds corresponding to temperatures greater than 2200 K. Below a threshold pulse fluence between 280 mJ/cm² and 330 mJ/cm², the atomic beam is composed exclusively of ground-state atoms. For higher fluences ions and excited atoms are generated.     

Calculation of the ion transverse velocity distribution function under ion cyclotron resonance heating

The ion transverse velocity distribution functions and the fraction η of ions heated above a certain energy W ₁ are calculated as applied to the ion cyclotron resonance heating method of isotope separation. It is assumed that the longitudinal ion velocity distribution in a plasma source is nonequilibrium. Under high heating temperatures, the averaged ion transverse velocity distribution becomes essentially nonequilibrium and exhibits two maxima. The ion heating efficiency η is calculated for W ₁=40 eV and various values of the parameter p=λ/L, where λ is the wavelength of the electric field of an antenna and L is the heating zone extension. The relative contributions of the time-of-flight and Doppler broadenings are evaluated.