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1.
研究了加入敏化离子Cr3+和Er3+的Tm:YAG晶体的吸收谱和荧光谱,计算了Cr3+、Er3+、Tm3+离子的2E、4I13/2、3F4能态的平均寿命及能量;转移效率、转移速率.得出Cr3+→Tm3+转移效率为80%,转移速率为2.1×103s-1.由(Er,Tm):YAG的荧光谱可见存在Er3+→Tm3+的有效的能量转移.讨论了Cr3+→Tm3+和Er3+→Tm3+能量转移的不同.  相似文献   

2.
用发射光谱法研究了N+2和N+与Ar碰撞产生的激发和电荷转移激发,获取了丰富的光谱信息。计算了各发射光谱线的发射截面,并研究了它们与入射离子能量的依赖关系。同种元素的分子离子和原子离子N+2和N+与Ar碰撞引起的谱线发射截面的对比中发现了一些有趣的结果。  相似文献   

3.
对Hg1-xDdxTe(HCT)晶体表面上由电化学阳极化生长的氧化膜进行了俄歇电子能谱分析,并经Ar^+离子蚀刻,研究了薄膜及其与底晶的界面层的深度元素分布和化学计量,估计了可能生成的化合物,阐述了阳极化过程中电流密度,糟电压及电解质溶液浓度对阳极化膜的AES的影响。  相似文献   

4.
本文采用MonteCarlo方法模拟低能Ar+离子注入ZrO2单晶所引起的原子级联碰撞过程.模拟结果表明,Ar+离子沿[111]轴沟道方向入射的溅射率低于沿[101]轴沟道方向入射的溅射率,更低于沿非沟道方向入射的溅射率.Ar+离子沿沟道方向入射的溅射率与非沟道方向入射的溅射率的差别随着Ar+离子入射能量的增大而迅速增大.因此在薄膜生长的过程中,若用一定能量的离子束以一定的入射角度进行轰击,薄膜中那些低指数晶向对准离子入射方向的晶粒,其溅射率和损伤程度较小.这些晶粒能保存下来并继续生长,而其它的晶粒由于其溅射率和损伤程度较大生长受到抑制.在薄膜生长的过程中,溅射率最少的晶粒由于生长速度较快,最终抑制了其它取向晶粒的生长.该模拟计算定性地说明了由于晶粒溅射产额的各向异性导致了Y稳定的ZrO2薄膜具有单一的取向和平面织构.  相似文献   

5.
测定了Ce3+,Er3+∶YAG中Ce3+离子的吸收截面.用从能级跃迁速率方程和激光传输方程推出的表达式计算了16μm波长激光的阈值能量(功率)和斜率效率.表明在Ce3+,Er3+∶YAG中,Ce3+对Er3+离子的激光性能影响与激活离子Er3+的浓度、晶棒大小有关.短晶棒或浓度低的晶体加入Ce3+可降低Er3+的激光阈值,增加斜率效率.而长晶棒、或Er3+浓度高的晶体加入Ce3+反而增加激光阈值,减小斜率效率.  相似文献   

6.
A3M2GeO12石榴石体系中Cr^3+离子的宽带发射光谱   总被引:1,自引:0,他引:1  
首次报道在A3M2Ge3O12:Cr(A=Cd^2+,M=Al^3+,Ga^3+,Sc^3+)锗酸盐石榴石体系中,Cr^3+离子室温下的红-近红外宽发射带光谱性质。随位于八面体格位上的Al^3+→Ga^3+→Sc^3+和十二面体格位上的Cd^2+→Ca^2+组成顺序变化,室温下,Cr^3+离子的^4T2→^4A2能级跃迁的R-NIR宽发射带,发射峰及光谱的长波和短波边逐渐向低能长波边移动。  相似文献   

7.
氟磷酸锶晶体Cr4+:YAG被动调Q激光特性研究   总被引:1,自引:0,他引:1  
采用氙灯泵浦,实现了掺钕氟磷酸锶晶体以Cr^4+:YAG作为被动调Q元件的1.059μm激光运转,测量了Cr^4+:YAG 同小爱过率及不同泵浦能量上激光单脉冲的输出能量、脉冲宽度、重复率,给出了Nd:S-FAP晶体Cr^4+:YAG调Q工作原理的方程组,数值求解该方程组得的理论结果与实验值相符。  相似文献   

8.
所谓掺杂的标度性指的是:分子晶体,如NH4NO3晶体在其相变过程中,其所掺杂的离子如Na+,K+,Ag+,Pb2+或F-,Cl-,Br-等,会对相变有影响。影响的强度表现在掺杂离子间的间距d对其质量的根号M的标度,即d/M这个参数上。这意味着对不同的...  相似文献   

9.
首次报告在A3M2Ge3O12∶Cr(A=Cd2+,Ca2+;M=Al3+,Ga3+,Sc3+)锗酸盐石榴石体系中,Cr3+离子室温下的红—近红外(R—NIR)宽发射带光谱性质。随位于八面体格位上的Al3+→Ga3+→Sc3+和十二面体格位上的Cd2+→Ca2+组成顺序变化,室温下,Cr3+离子的4T2→4A2能级跃迁的R-NIR宽发射带,发射峰及光谱的长波和短波边逐渐向低能长波边移动。这是由于晶场强度减弱,阳离子的离子半径增大的结果。在镉(钙)铝和镉(钙)镓锗酸盐体系中,少量Sc3+取代八面体上的Al3+和Ga3+时,可使Cr3+的R-NIR荧光发射强度增强。  相似文献   

10.
YAG晶体中Ce^3+对Er^3+的敏化作用   总被引:2,自引:1,他引:1  
黄莉蕾  洪治 《光学学报》1998,18(4):03-506
通过求解(Ce,Er):YAG和Er:YAG的能级跃迁速率方程,讨论了Ce^3+对Er^3+离子的敏化作用。表明掺Ce^3+可增强Er^3+离子1.66μm波长的激光强度,但仅改变了1.66μm波长激光粒子数反转,即N2(^4I12/2)〉N1(^4I15/2)与Er^3+离子浓度的关系。  相似文献   

11.
The kinetic energy of ions in dielectric barrier discharge plasmas are analysed theoretically using the model of binary collisions between ions and gas molecules. Langevin equation for ions in other gases, Blanc law for ions in mixed gases, and the two-temperature model for ions at higher reduced field are used to determine the ion mobility. The kinetic energies of ions in CH4 + Ar(He) dielectric barrier discharge plasma at a fixed total gas pressure and various Ar (He) concentrations are calculated. It is found that with increasing Ar (He) concentration in CH4 + Ar (He) from 20% to 83%, the CH4+ kinetic energy increases from 69.6 (43.9) to 92.1 (128.5)eV, while the Ar+ (He+) kinetic energy decreases from 97 (145.2) to 78.8 (75.5)eV. The increase of CH4+ kinetic energy is responsible for the increase of hardness of diamond-like carbon films deposited by CH4 + Ar (He) dielectric barrier discharge without bias voltage over substrates.  相似文献   

12.
By use of optical spectrum technology, the spectra of X-ray induced by highly charged 40Arq+ ions interacting with Au surface have been studied. The results show that the argon Kα X-ray were emitted from the hollow atoms formed below the surface. There is a process of multi-electron exciting in neutralization of the Ar16+ion, with electronic configuration 1s2 in its ground state below the solid surface. The yield of the projectile Kα X-ray is related to its initial electronic configuration, and the yield of the target X-ray is related to the projectile kinetic energy.  相似文献   

13.
Bubble detectors which are commonly used as neutron detectors have been demonstrated through this study to be good detectors for registration of high energy heavy ion tracks. Large size bubble detectors made in China Institute of Atomic Energy were irradiated to heavy ions Ar and C up to 650 MeV/u and 400 MeV/u, respectively. Very clear features of stringy tracks of high energy heavy ions and their fragmentations are manifested and distinguishable. A single track created by a specific high energy heavy ion is composed of a line of bubbles, which is visible by naked eyes and retained for months wihhout reduction in size. The creation of heavy ion tracks in bubble detectors is governed by a threshold whose essence is approximately a critical value of energy loss rate (dE/dX)c similar to that of etch track detectors. Ranges of heavy ions in bubble detectors are apparent and predictable by existing formulas. Identification of high energy heavy ions and the applications to heavy ion physics, cosmic rays, exotic particles and cancer therapy monitoring are obviously promising. The experimental and theoretical aspects of high energy heavy ion tracks in bubble detectors as well as the expectable applications are presented and discussed.  相似文献   

14.
高电荷态离子Arq+入射在金属表面形成靶原子X射线谱   总被引:3,自引:3,他引:0  
本文报道低能高电荷Ar12+、Ar13+ 、Ar14+离子与金属Mo表面作用过程中Mo原子受激发射X射线和X射线强度随入射能量变化的实验结果.结果表明,低速高电荷离子与金属表面原子相互作用可有效地激发靶原子或靶离子内壳层电子而发射X射线.  相似文献   

15.
Polyvinyl alcohol films were irradiated to 90 MeV O 6+ and 150 MeV Si 14+ ions at fluence ranging from 1010 to 1012 ions/cm2. The observed changes in optical energy gap of this polymer have been investigated and results are tried to be explained in terms of energy transferred by the incident ions. It has been noticed that the value of optical energy gap decreases with increasing energy loss during the ion–polymer interaction process.  相似文献   

16.
The effects of ion-beam bombardment on the physical and chemical properties of poly(allyl diglycol carbonate) (CR-39) polymer have been investigated. CR-39 samples were bombarded with 320 keV Ar and 130 keV He ions at fluences ranging from 1 × 1013 to 2 × 1016 ions/cm2. The nature and extent of radiation damage induced were studied by UV–VIS spectrometry, Fourier-transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) analysis, as well as Vickers' hardness measurements. In addition, the effect of ion fluence on the wetting properties of ion-beam bombarded CR-39 polymer was determined by measuring the contact angle for distilled water. UV–VIS spectra of bombarded samples reveal that the optical band gap decreases with increasing ion fluence for both Ar and He ions. In the FTIR spectra, changes in the intensity of the bands on irradiation relative to pristine samples occurred with the appearance of new bands. XRD analyses showed that the degree of ordering of the CR-39 polymer is dependent on the ion fluence. Changes of surface layer composition and an increase in the number of carbonaceous clusters produced important change in the energy gap and the surface wettability. The surface hardness increased from 10.54 MPa for pristine samples to 28.98 and 23.35 MPa for samples bombarded with Ar and He ions at the highest fluence, respectively.  相似文献   

17.
李耀宗  张小安  梁昌慧  赵永涛  周贤明 《物理学报》2014,63(16):163202-163202
探测了动能为3.0–6.0 MeV的Eu20+离子入射Au靶激发Eu的L-X射线谱,获得了射线产额与离子入射动能的实验关系. 采用有心保守力作用下的两体碰撞模型,并考虑了离子的能损,计算了Eu离子与Au 原子碰撞过程中单离子L壳层空穴的产额. 根据离子L 壳层空穴退激的荧光产额,给出了碰撞过程Eu单离子L-X 射线产额与离子入射动能的理论关系. 结果表明,射线产额的理论值与实验数据符合得较好. 关键词: 离子动能 荧光产额 单离子X射线产额  相似文献   

18.
本文中我们利用紫外、红外光谱等分析手段获取低能离子束生物诱变的信息。发现用30 ke V低能氮离子和氩离子在 0 - 2× 1 0 16 ions/cm2注入剂量范围内注入胸腺嘧啶 ,其残存率随剂量的变化趋势均出现了不同于γ射线等辐照时的线性或肩型曲线 ,而呈现一种新的变化趋势——“马鞍型”曲线 ,表明参与结构的质量沉积不足以解释“马鞍型”曲线。红外光谱的分析结果表明在离子束注入过程中胸腺嘧啶分子确实存在结构上的修复。研究结果表明紫外、红外光谱可以给出离子束注入前后生物分子结构突变或重组、分子结构突变与注入剂量的关系以及分子的修复等信息。  相似文献   

19.
韩亮  宁涛  刘德连  何亮 《物理学报》2012,61(17):176801-176801
利用磁过滤真空阴极电弧技术制备了sp3键大于80%的四面体非晶碳(ta-C)薄膜, 通过冷阴极离子源产生keV能量的氩离子轰击ta-C薄膜,研究了氩离子轰击能量对ta-C薄膜结构, 内应力以及耐磨性的影响.通过X射线光电子能谱和原子力显微镜研究了氩离子轰击对薄膜结构 与表面形貌的改性,研究表明,氩离子轰击诱导了ta-C薄膜中sp3键向sp2键的转化, 并且随着氩离子轰击能量的增大,薄膜中sp2键的含量逐渐增多, 薄膜内应力随着氩离子轰击能量的增大逐渐减小.氩离子轰击对薄膜的表面形貌有较大影响, 在薄膜表面形成刻蚀坑,并且改变了薄膜的表面粗糙度,随着氩离子轰击能量的增大, 薄膜的表面粗糙度也会逐渐增大.通过摩擦磨损仪的测试结果,氩离子轰击对薄膜的初始摩擦系数影响较大, 但是对薄膜的稳定摩擦系数影响较小,经过氩离子轰击前后的ta-C薄膜的摩擦系数为0.1左右, 并且具有优异的耐磨性.  相似文献   

20.
Secondary ions emitted from Si targets were measured with a quadrupole mass spectrometer under large Ar cluster and monomer ion bombardment. Incident ion beams with energies from 7.5 to 25 keV were used and the mean size of the Ar cluster ion was about 1000 atoms/cluster. Sin+ ions with n values up to n = 8 were detected under Ar cluster ion bombardment, whereas Si cluster ions were scarcely detected under Ar monomer ion bombardment. These cluster ion yields showed the power law dependence on the cluster size.  相似文献   

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