一类广义强阻尼Sine-Gordon方程的整体解

同时考虑黏性效应及外阻尼作用研究了一类广义强阻尼Sine-Gordon方程-利用Galerkin方法,首先证明了该方程在初值u(x,0)∈H¹₀(Ω),u_t(x,0)∈L²(Ω)的条件下初边值问题存在整体弱解u(x,t),并证明了整体弱解关于初始条件具有 关键词： Sine-Gordon型方程 强阻尼 Galerkin方法 整体解     

一类带扰动的Sine-Gordon方程的谱方法

研究一类具扰动的Sine-Gordon方程u_tt-u_xx+αsinu-βu_xxt=g(u),t>0,-∞< x< ∞的周期初值问题,提出了谱方法,并用先验估计方法作了误差估计,证明了近似方法的收敛性,并得到了该问题广义解的存在、唯一性。     

一类非线性发展方程的特征中心差分法

给出一类非线性发展方程的特征中心差分法,分别得到非规则网格上的位移u、速度u_t及其对空间变量x的一阶导数项的差分解和误差估计.所讨论方法的计算量与基于线性插值的特征差分法相当,其近似解与基于二次插值的特征差分法的近似解具有相同阶的误差估计,u,u_t对空间变量x的一阶导数近似均具有超收敛误差估计.数值试验说明了该方法的可行性和有效性.     

一维波动方程反问题求解的正则化方法

讨论了一维波动方程u_{tt-∂x(μ(x)ux)=0在一般的初、边值条件和附加条件下系数μ(x)的求解方法.把反问题归结为一不适定的非线性积分方程组,利用正则化方法克服了反问题的不适定性.}     

Burgers-Korteweg-de Vries复合方程的格子Boltzmann方法模拟

针对Burgers-Korteweg-de Vries(cBKdV)复合方程提出一种格子Boltzmann模型.通过恰当地处理色散项u_xxx并运用Chapman-Enskog展开从格子Boltzmann方程推导出宏观方程,从而得到联系微观量与宏观量的局部平衡分布函数.对不同微分方程进行数值实验,数值解与解析解非常吻合,相比于其它数值结果,该格子Boltzmann模型的数值结果更精确,说明该数值模型的高效性.     

核磁共振法测定氟硅油的分子量和氟硅橡胶中乙烯基含量

用一系模型化合物归属了氟硅油和氟硅橡胶(聚甲基,r.r.r.三氟丙基硅氧烷,的¹H NMR谱,提出了一测定氟硅油分子量的方法。此法是基于端基的测量。对于甲基封端的氟硅油, x=6S_CH3(b)/S_CH3(a),M=156x+162对于羟基封端的氟硅油, x=((SCH₃(b))/SCH₃(a)+1)×2,M=156x+18 S_CH3(a)和S_CH3(b)分别为端甲基和其余的甲基的峰面积,x和M分别为聚合度和分子量。 使用高灵敏度的¹H NMR谱测定了氟硅橡胶中乙烯基含量和一系列共聚物的组成。 乙烯基 mole%=(S_-CH-CH2)/S_-CH2×(2)/3 S_-CH-CH2和S_-CH2分别是乙烯基和-CH₂基的峰面积。     

一类演化方程的高稳定性的差分格式

考虑一类演化方程u_t=au∂_2k+1(其中a是常数,u∂_2k+1=∂^2k+1u/∂x^2k+1,k=1,2……)的有限差分解法。构造了两类具有高稳定性的显式差分格式。并用引入耗散项的方法建立了两类半显式差分格式,它们是无条件稳定的且可显式地进行计算。     

非线性耗散对亚稳态系统量子衰变速率的影响

发展了一种快速傅里叶变换路径积分方法，研究非线性耗散系统的量子衰变速率，得到了Bounce轨道的作用量S_B，即衰变速率的指数因子.在系统与环境存在非线性耦合f(x)=tanh［λ(x-x_b)］的情形下，发现其对衰变速率具有抑制作用.指数因子随温度T的关系不再满足S_B=a［1-b(T/T_c)²］法则；与通常的线性耗散情形相比，跨越温度T_c回升，即系统更早地进入穿透区域. 关键词： 量子衰变 非线性耦合 路径积分 快速傅里叶变换     

La2-xNdxCuO4+δ(0.1≤x≤1.2)体系中滞弹性弛豫与相变内耗研究

通过对La_2-xNd_xCuO_4+δ(0.1≤x≤1.2)体系中滞弹性弛豫与相变内耗性能的研究发现,当0.1≤x≤1.0时,在250K左右存在一个与间隙氧有关的弛豫内耗峰,并且当0.1≤x≤0.4时,弛豫内耗峰峰高随着x值的增大而升高,此时体系为正交结构;当0.5≤x≤1.0时,体系在宏观上呈现四方结构,此时内耗峰峰高随着x< 关键词： 2-xNd_<i>xCuO_4+δ')" href="#">La_2-xNd_<i>xCuO_4+δ 间隙氧 弛豫内耗峰 相变内耗峰     

杂多阴离子的NMR和ESR研究——P-V-W Keggin阴离子的31P、51V、17O-NMR谱

本文合成了六种含有P-V-W和V-V-W Keggin结构的杂多阴离子,并研究了它们的³¹P、⁵¹V、¹⁷O-NMR谱,对于PV_xW_12-xO₄₀^(x+3)-(x=1~4)阴离子,当x=1时,³¹P和⁵¹V-NMR谱只有一条线,并且此线化学位移和pH无关。当x ≥ 2时,谱线数目随着x迅速增加,其原因是几何异构体的数目和类型迅速增加。它们的化学位移δ_p,和δ_v。依赖于溶液的酸性和x,即δ_p,随pH值和x增加而减少,而δ_v,却随pH和x的增加而增加。最后简短讨论了桥氧上质子化的影响。     

New variable separation solutions for the generalized nonlinear diffusion equations

The functionally generalized variable separation of the generalized nonlinear diffusion equations ut = A(u, ux)uxx +B(u, ux) is studied by using the conditional Lie–Ba¨cklund symmetry method. The variant forms of the considered equations,which admit the corresponding conditional Lie–Ba¨cklund symmetries, are characterized. To construct functionally generalized separable solutions, several concrete examples defined on the exponential and trigonometric invariant subspaces are provided.     

On generalized Bäcklund transformations for equations describing pseudo-spherical surfaces

It is shown that each one-parameter subgroup of SL(2,R) gives rise to a local correspondence theorem between suitably generic solutions of arbitrary scalar equations describing pseudo-spherical surfaces. Thus, if appropriate genericity conditions are satisfied, there exist local transformations between any two solutions of scalar equations arising as integrability conditions of sl(2,R)-valued linear problems.

A complete characterization of evolution equations u_t=K(x,t,u,u_x,…,u_x^k) which are of strictly pseudo-spherical type is also provided.     

1-forms over the moduli space of irreducible connections defined by the spectrum of Dirac operators

Let (P) be the moduli space of irreducible connections of a G-principal bundle P over a closed Riemannian spin manifold M. Let D_A be the Dirac operator of M coupled to a connection A of P and f a smooth function on M. We consider a smooth variation A(u) of A with tangent vector ω and denote T_ω:= (D_A(u)−f) (u=0. The coefficients of the asymptotic expansion of trace (T_ω · e^-t(D_A−f)2) near t=0 define 1-forms a^(k)_f, K=0, 1, 2, … on (P). In this paper we calculate aa⁽⁰⁾_f, a⁽¹⁾_f, a⁽²⁾_f and study some of their properties. For instance using the 1-form a⁽²⁾_f for suitable functions f we obtain a foliation of codimension 5 of the space of G-instantons of S⁴.     

On nonanalytic solitary waves formed by a nonlinear dispersion

We study the prototypical, genuinely nonlinear, K(m, n) equation, u_t ± a(u^m)_x + (uⁿ)_xxx = 0, a = const, which exhibits a number of remarkable dispersive effects. In particular, the distinguished subclass wherein m = n + 2 is transformed into a new, purely dispersive equation free of convection. In addition to compactons, the K(m, n) can support both kinks and solitons with an infinite slope(s), periodic waves and dark solitons with cusp(s) all being manifestations of nonlinear dispersion in action. For n < 0 the enhanced dispersion at the tail may generate algebraically decaying patterns.     

拟随机选择法

本文针对通常的随机选择法在求Riemann问题基本解上遇到的困难,提出采用拟特征线形式下的各独立标量方程形式,求其简单的Riemann问题组以代替原Riemann问题的解。这样,使方法基本保持了随机选择法的特点,又使方法的实现、应用和推广更加容易,而且可以设计并行算法。最后用激波管和溃坝问题为例作了实算。结果与已知的结果相比也是满意的。     

Projective and affine connections on S and integrable systems

It is known that the Korteweg–de Vries (KdV) equation is a geodesic flow of an L² metric on the Bott–Virasoro group. This can also be interpreted as a flow on the space of projective connections on S¹. The space of differential operators Δ⁽ⁿ⁾=∂ⁿ+u₂∂ⁿ⁻²++u_n form the space of extended or generalized projective connections. If a projective connection is factorizable Δ⁽ⁿ⁾=(∂−((n+1)/2−1)p₁)(∂+(n−1)/2p_n) with respect to quasi primary fields p_i’s, then these fields satisfy ∑_i=1ⁿ((n+1)/2−i)p_i=0. In this paper we discuss the factorization of projective connection in terms of affine connections. It is shown that the Burgers equation and derivative non-linear Schrödinger (DNLS) equation or the Kaup–Newell equation is the Euler–Arnold flow on the space of affine connections.     

A study on the nonstoichiometry of tin oxides by coulometric titration

In this investigation, nonstoichiometries and defect structures of tin oxides were studied between 694 and 990 K by coulometric titration using solid state electrolyte (YSZ) cells. The relationship between nonstoichiometry of the oxide (x) and equilibrium oxygen partial pressure (P_o2) was expressed by the proportionality: xP_O2^−1/6. An intermediate oxide phase, Sn₃O₄ between Sn and SnO₂ was observed in the temperature range of 696–732 K. The standard Gibbs energy of formation of Sn₃O₄ via the reaction; was found to be ΔG^o_Sn3O4 = −1163960+417.36 T (J/mol). The standard Gibbs energy change for the defect formation reaction in SnO_2−x was calculated to be ΔG^o_SnO2−x = 3.05×10⁵−38.97 T (J/mol)).     

Oxygen diffusion and surface exchange in La1−xSrxFe0.8Cr0.2O3−δ (x=0.2, 0.4 and 0.6)

Oxygen tracer diffusion (D*) and surface exchange rate constant (k*) have been measured, using isotopic exchange and depth profiling by secondary ion mass spectrometry (SIMS), in La_1−xSr_xFe_0.8Cr_0.2O_3−δ (x=0.2, 0.4 and 0.6). Measurements were made as a function of temperature (700–1000 °C) and oxygen partial pressure (0.21–10⁻²¹ atm) in dry oxygen, water vapour and water vapour/hydrogen/nitrogen mixtures. At high oxygen activity, D* was found to increase with increasing temperature and Sr content. The activation energies for D* in air are 2.13 eV (x=0.2), 1.53 eV (x=0.4) and 1.21 eV (x=0.6). As the oxygen activity decreases, D* increases as expected qualitatively from the increase in oxygen vacancy concentration. Under strongly reducing conditions, the measured values of D* at 1000 °C range from 10⁻⁸ cm² s⁻¹ for x=0.2 to 10⁻⁷ cm² s⁻¹ for x=0.4 and 0.6. The activation energies determined at constant H₂O/H₂ ratio are 1.21 eV (x=0.2), 1.59 eV (x=0.4) and 0.82 eV (x=0.6).

The surface exchange rate constant of oxygen for the H₂O molecule is similar in magnitude to that for the O₂ molecule and both increase with increasing Sr concentration.     

Commutator representations of differential calculi on the quantum group SUq(2)

Let (Γ, d) be the 3D-calculus or the 4D_±-calculus on the quantum group SU_q (2). We describe all pairs (π, F) of a ^*-representation π of (SU_q(2)) and of a symmetric operator F on the representation space satisfying a technical condition concerning its domain such that there exist a homomorphism of first order differential calculi which maps dx into the commutator [iF, π(x)] for x ε (SU_q (2)). As an application commutator representations of the two-dimensional left-covariant calculus on Podles quantum 2-sphere S_qc² with c = 0 are given.