共查询到19条相似文献,搜索用时 109 毫秒
1.
2.
3.
煤粉热分解的反应动力学研究 总被引:3,自引:0,他引:3
煤的热分解过程是煤的燃烧、气化、液化等转换过程的初级阶段,对后继过程有极其重要的影响。研究煤的热分解机理,确定反应机理方程和动力学参数,对于建立热分解模型,判断不同煤种的反应能力,正确描述热分解和燃烧的化学反应过程,进而完成整个复杂的燃烧及气化过程的数学模化,有着重要的作用。 相似文献
4.
5.
6.
1引言煤燃烧过程中特别是流化床中为了减少SOZ的排放,一般采用向炉内加入石灰石等添加物的方法。这些添加物质的存在,使挥发分含氮物质的氧化机理异于纯单相氧化。因此研究钙基脱硫剂(CaCO。)及其生成物(CaSO。、煤灰)对NH。和HCN的多相氧化有助于了解实际锅炉煤燃烧过程中脱硫对氮氧化物生成的影响。Lin[‘]研究了石灰石和CaSO。对NH。氧化的影响。发现石灰石对NH。氧化生成NO具有相当大的催化作用,可使NH3MNO的转化率达65%,而C3SO4存在和空管时NH3氧化结果一致,表明CaSO。对NHa无氧化作用。IisJ‘」在研究Ca… 相似文献
7.
8.
9.
10.
11.
The development and change of surface ruggedness in chars was studied at conditions typical in a pulverized coal furnace. The fractal dimension, a measure of surface ruggedness, of chars was measured using physisorption techniques. By adjusting the temperature encountered (1173 to 1773 K) and residence time (0.1 to 1.5 s) of the synthetic coal (sized to 46–106 μm diameter), chars at different stages of combustion were prepared in a laminar flow (drop-tube) furnace. The particles were quickly cooled and quenched in an inert atmosphere. The samples were examined using a scanning electron microprobe, and their fractal dimensions were determined using gas physisorption. The adsorption data were used to test if the char surface was fractal on a molecular scale, to determine the fractal dimension, and to quantify changes in the fractal dimension during combustion. The fractal dimension of the unburned synthetic coal was approximately 2. The fractal dimension increased as high as 2.85 as the carbon matrix burned away and exposed mineral moieties. However, as combustion continued the carbon burned completely away leaving a mineral fly ash particle with a fractal dimension as low as 2.47. 相似文献
12.
13.
It had been conjectured that diffusion limited aggregates and Laplacian growth patterns (with small surface tension) are in the same universality class. Using iterated conformal maps we construct a one-parameter family of fractal growth patterns with a continuously varying fractal dimension. This family can be used to bound the dimension of Laplacian growth patterns from below. The bound value is higher than the dimension of diffusion limited aggregates, showing that the two problems belong to two different universality classes. 相似文献
14.
The fractal and multi-fractal patterns of metal atoms are observed in the surface layer and cross section of a metal ion implanted polymer using TEM and SEM for the first time. The surface structure in the metal ion implanted polyethylene terephthalane (PET) is the random fractal. Certain average quantities of the random geometric patterns contain self-similarity. Some growth origins appeared in the fractal pattern which has a dimension of 1.67. The network structure of the fractal patterns is formed in cross section, having a fractal dimension of 1.87. So it can be seen that the fractal pattern is three-dimensional space fractal. We also find the collision cascade fractal in the cross section of implanted nylon, which is similar to the collision cascade pattern in transverse view calculated by the TRIM computer program. Finally, the mechanism for the formation and growth of the fractal patterns during ion implantation is discussed. 相似文献
15.
16.
湍流预混火焰的时间和空间分形特性研究 总被引:1,自引:0,他引:1
1引言湍流燃烧过程是一个强烈的非线性动力学过程,用于描述湍流燃烧的诸多特性参数表现出随机脉动的特点,对于传统参量的分析处理也只能停留在时均平均加脉动项的概率统计上,不论从时间、还是空间角度都显粗糙。Damkohler[1]早在1942年提出了火焰结构与湍流燃烧速度的内在联系,引导人们将注意力转向火焰形状结构的研究上。图像计算机技术的兴起为实时获得湍流火焰结构参数创造了条件。Boyer[2]在研究高强度湍流燃烧时发现,由于脉动造成的复杂火焰表面已不能用传统的Euclidean几何加以描述。分形理论不仅可以用细微尺度规划几何结构,… 相似文献
17.
We consider a conformal theory of fractal growth patterns in two dimensions, including diffusion limited aggregation (DLA) as a particular case. In this theory the fractal dimension of the asymptotic cluster manifests itself as a dynamical exponent observable already at very early growth stages. Using a renormalization relation we show from early stage dynamics that the dimension D of DLA can be estimated, 1.69相似文献
18.
19.
Polymer electrolyte membranes containing various weight percent of salt have been prepared in the authors’ laboratory for
the study of their potential applications in solid state electrochemical devices; however, the polymer electrolyte membranes
were found to become sort of media for fractal growth, months after they were prepared. Fractal growth patterns in polymer
membranes of poly (ethylene oxide) and chitosan membranes have been analyzed, and their fractal dimensions were determined.
A diffusion-limited aggregate model which is based on the Brownian motion theory is applied to simulate the experimentally
obtained fractal patterns. The approach was extended by performing computer simulations with computing resources available.
The fractal dimension values of the simulated and the experimentally obtained original fractal patterns were marginally close.
This indicates that the simulation work has successfully produced fractal patterns that are in fairly acceptable conformity
with the fractal patterns observed in the polymer membranes. 相似文献