加压对110 K Bi-Pb-Sr-Ca-Cu-O单相样品超导电性的影响

 在静压0~1 GPa（10 kbar）范围内，80~300 K温区，用测量电阻的方法，研究了Bi-Pb-Sr-Ca-Cu-O（起始转变温度T_c^on=110 K，终止转变温度T_c^fi=106 K）的起导电性。观察到超导临界温度T_c随压力以dT_c/dp=2K/GPa的速率增高，而在不同压力下的斜率d logR/dp却保持不变。     

高温超导体低温、高压下的物理性质的研究

 在3~20 GPa压力范围内，测量了含氧量较低的YBa₂Cu₃O_7-δ（δ=0.46）单晶压力增强效应（dT_c/dp=4.9KGPa^-1）；YBa₂Cu₃O₇（T_c0=90 K）单晶在压力下临界电流密度随压力变化；外磁场H=30 kO_e时，T_c与磁场、压力关系；压力达16.5 GPa下，Bi₂Sr₂CaCu₂O_x单晶T_c(p)关系（dT_c/dp=-0.4 KGPa^-1）。发现Y系高温超导体的温度压力导数dT_c/dp与T_c0中间呈dT_c/dp=b-mT_c0线性关系（b、m为常数）。结合压力下Y系超导体结构相变和含氧量对T_c影响，分析这类超导体T_c有很强的正压力效应的原因。把实验结果同几种超导电性微观理论模型进行了分析和比较。     

Zn0.83Mn0.17Se和ZnSe/Zn0.84Mn0.16Se超晶格材料中Mn2+的压力光谱研究

 采用压力光谱技术在低温下观测到了Mn²⁺离子的⁴T₁→⁶A₁跃迁,该谱线在Zn_0.83Mn_0.17Se和ZnSe/Zn_0.84Mn_0.16Se超晶格样品中有不同的压力行为,体材料中其压力系数为-42.4 peV/Pa,超晶格中为-29.5 peV/Pa。用晶体场理论计算得到体材料Zn_0.83Mn_0.17Se中Mn²⁺离子⁴T₁→⁶A₁谱线的压力系数为-38.3 peV/Pa,与实验结果基本一致。结合材料中发光峰积分强度随压力的变化关系进行分析,证实Mn²⁺离子的发光性质主要与其近邻的晶体场环境有关。     

(Fe0.03Ni0.97)8(Si0.79P0.21)3的等温状态方程研究

 采用固态高温烧结反应方法,成功合成出了陨硅镍铁石样品(Fe_0.03Ni_0.97)₈(Si_0.79P_0.21)₃。X射线衍射结果表明,合成样品的结构为R3'c,对应的晶胞参数为a=b=0.663 8(1) nm,c=3.789 2(2) nm,V=1.446 15(6) nm³。在室温下,对样品进行原位高压X射线衍射研究,实验最高压力达到21.3 GPa,随着压力的升高,晶胞体积逐渐减小,但并没有观察到结构相变。利用Birch-Murnaghan状态方程对体积与压力的关系进行拟合,获得常温常压下的体积V₀=1.441 4(24) nm³,体积模量K₀=220(7) GPa。晶轴与压力的关系利用Murnaghan状态方程拟合,获得a轴和c轴的模量分别为K_a=257(9)和K_c=165(4),c轴较a轴容易压缩。     

D介子与∑c+重子寿命的宇宙线数据

本文提出一个证认宇宙线中新X粒子的分析原则:筛比较法。对目前全部已知乳胶室事例进行了判定。其中结果有D介子和∑_c⁺重子的平均寿命和质量,τ（D^&;#177;）=5.8×10^-13秒,τ（D⁰）=2.0×10^-13秒,τ（∑_c⁺）（?）2.4×10^-14秒。支持△I=1的选择规则。     

关于162,164Er,164,166Yb,168Hf诸核的回弯机制

通过对相邻奇A核转动带的回弯行为的分析,无法肯定^162,164Er,^164,166Yb,¹⁶⁸Hf诸核的回弯机制。本文利用HFB推转模型,计算了这些核的排列角动量i（ω）和回弯的临界角频率ω_c,探讨了阻塞效应的影响,通过和实验值的比较,确定了它们出现回弯均是由于一对i_13/2中子转动排列的结果。     

23Na（p,α）20Ne反应中几个非孤立共振的研究

本工作测量了²³Na（p,α₀）²⁰Ne_g.s.反应在 E_p=1—2.5MeV 能量范围内和θ_L=30°,150°时的激发函数,还测量了²³Na（p,α₁）²⁰Ne_lst,反应在上述能量范围内和θ_L=30°时的激发函数.对2.171 MeV 共振,在12个角度上测量了（p,α₀）的激发函数,并由激发函数求得了多个角分布,另外在一个固定能量上（150°激发函数的共振峰上）测量了（p,α₀）反应的角分布.对2.117 MeV 共振,在二个固定能量上（150°激发函数的共振峰上和其高能端的半高点处）测量了（p,α₀）反应的角分布.对2.075 MeV 共振,在16个角度上测量了（p,α₀）反应的激发函数,并由激发函数求得了角分布.这三个共振的角分布不是90°对称的,并且共振峰的峰位与角度有关.用复合核理论对它们进行了讨论.     

相对论性电磁束缚系统（π±μ干）、（K±μ干）的库仑裂解与衰变

本文应用复合粒子量子场论的微扰展开式和相对论性的（π^&;#177;μ^?）、（K^&;#177;μ^?）的B.S.波函数,计算了在原子核屏蔽库仑场中高能（π^&;#177;μ^?）、（K^&;#177;μ^?）原子的裂解能谱和截面。在极端相对论近似下,对大多数原子核,它们的裂解截面分别约为10^-18cm²和10^-17cm²。利用同样的波函数,还计算了（π^&;#177;μ^?）→π⁰+v_μ（v_μ）,（K^&;#177;μ^?）→K⁰+v_μ（v_μ）,以及（π^&;#177;μ^?）→μ⁺+μ^-+v_μ（v_μ）,（K^&;#177;μ^?）→μ⁺+μ^-+v_μ（v_μ）的衰变几率。     

C12（d,p）C13反应中存在一个中间结构的可能性

在氘核能量为0.5-2.5MeV能区,测量了C¹²（d,d）C¹²,C¹²（d,p₀）C_8.3.¹³,C¹²（d,p₁）C_13t¹³,C¹²（d,p₂）C_2nd¹³和C¹²（d,p₃）C_3rd¹³反应在几个角度上的激发函数,及在一些能量点上的角分布。围绕E_d=1.73MeV附近,在角分布和激发函数中出现有规律变化趋势,讨论了不同反应机制之间相干,并探讨了孤立“门态”存在的可能性。     

Semileptonic decays Bc→(ηc,J/Ψ)lv in the perturbative QCD approach

In this paper we study the semileptonic decays of B_c^-→(η_c,J/Ψ)l^-v_l. We first evaluate the B_c→(η_c,J/Ψ) transition form factors F₀(q²), F₊(q²), V(q²) and A_0,1,2(q²) by employing the pQCD factorization approach, and then we calculate the branching ratios for all considered semileptonic decays. Based on the numerical results and the phenomenological analysis, we find that: (a) the pQCD predictions for the values of the B_c→η_c and B_c→J/Ψ transition form factors agree well with those obtained by using other methods; (b) the pQCD predictions for the branching ratios of the considered decays are Br(B_c^-→η_c e^-v_e(μ^-v_μ)=(4.41_-1.09^+1.22)×10^-3, Br(B_c^-→η_cτ^-v_τ) =(1.37_-0.34^+0.37)×10^-3, Br(B_c^-→J/Ψ e^-v_e(μ^-v_μ)) =(10.03_-1.18^+1.33)×10^-3, and Br(B_c^-→J/Ψτ^-v_τ) =(2.92_-0.34^+0.40)×10^-3; and (c) we also define and calculate two ratios of the branching ratios R_ηc and R_J/Ψ, which will be tested by LHCb and the forthcoming Super-B experiments.     

晶面结构非均匀性对金刚石晶形的影响

 不仅考虑表面能，同时也引入表面结构非均匀性自由焓G_stⁱ，通过热力学分析，解释了随着晶体的逐渐长大而{110}面常在金刚石的外形中消失的机理，并用逆推法计算了有关数值。     

铜的高压声速和冲击熔化

 用光分析技术，测量了在一维应变冲击条件下，无氧铜的高压下声速，压力范围为125~170 GPa。将上述结果与Broberg、Morris等和Aльгшуер等过去发表的数据结合在一起，对0~170 GPa整个压力区间的声速数据做了综合分析，给出了声速随压力的变化规律。实验结果发现，无氧铜在156~159 GPa之间开始发生冲击熔化，到170 GPa左右，完全进入液相区；对于处于0~156 GPa固体无氧铜的弹性声速c_l可用ln c_l=1.565 888-2.645 488×10^-2ln p+2.710 681×10^-2ln²p拟合公式描述（p的单位为GPa，c_l的单位为km/s），拟合值与实验值的相对误差小于1.3%。     

压力对GdoBr:Eu晶场参数的影响

 在室温下测量了GdoBr:Eu的常压和高压荧光谱，光谱范围在13 000~21 500 cm^-1之间，压力至12 GPa。由光谱数据得到了Eu³⁺晶场能级随压力的变化曲线。⁷F_0～5能级随压力的变化规律比较复杂，而⁵D_0~2各能均随压力的升高几乎线性地降低。在基态谱项⁷F的49个状态上进行了晶场拟合计算，所得常压下的5个非零晶场参数分别为：B₀²＝-1 124.0 cm^-1，B₀⁴＝-969.6 cm^-1，B₄⁴＝827.9 cm^-1，B₀⁶＝889.6 cm^-1，B₄⁶＝377.0 cm^-1。高压下的计算结果表明，B₀⁴、B₀⁶这两个晶场参数随压力的增加而增大，B₄⁶随压力的增加而减小，而B₀²、B₄⁴随压力的变化有些起伏。晶场强度在8 GPa以下随压力增加而减小，其后开始变强。     

Experimental Study of High-Spin States in Deformed Odd-Odd 180 Ir

High spin states in deformed odd-odd ¹⁸⁰Ir have been investigated using the ¹⁵⁴Sm (³¹P, 5nγ)¹⁸⁰Ir reaction through the measurements of excitation functions at 150, 155, 160, 165 and 170 MeV beam energies, K X-γ and γ-γ coincidences at 160 MeV. A new level scheme composed of 5 rotational bands has been established. According to the band structure characteristics and the deduced in band B(M1)/B(E2) ratios, the quasiparticle configurations and spin and parity have been proposed to the observed bands. The neutron AB crossing is observed at hω_c≈0.26 MeV for the π1/2^－[541]⊙ν1/2^－[521] and π1/2^－[541]⊙ν5/2^－[512] bands. This AB crossing frequency is close to that in the ν5/2^－[512] band of ¹⁷⁹Os indicating the loss of intruder nature of the π1/2 - orbit. Gradual alignment gain in both the π9/2^－[514]⊙ν7/2⁺[633] and π9/2^－ν5/2^－[512] bands is observed which is similar to the low spin anomaly in alignment in the πh_11/2,πd_5/2 and πi_13/2 bands of neighboring Ir and Re isotopes. Different alignment properties have been discussed in the framework of cranked shell model, and a larger quadrupole deformation is suggested for the bands with π9/2^－[514] orbit involved.     

一种脒基碳酸氢盐的NMR研究

采用¹H、¹³C NMR、同核相关谱(gCOSY)、异核相关谱(gHSQC)和远程偶合谱(gHMBC)等多种核磁方法研究了一种脒基碳酸氢盐化合物N, N′-双十二烷基乙脒基碳酸氢盐的结构和构型,证明了该化合物具有两种不同的构型：A[E, Z]和B[E, E],完成了该化合物两种构型中¹H、¹³C NMR谱带的归属. 并考察了不同温度、不同极性溶剂（CDCl₃和DMSO-d₆）对此化合物两种不同构型比例变化的影响. 表明了N, N′-双十二烷基乙脒基碳酸氢盐在溶剂CDCl₃中存在两种构型A和B, 随着温度的升高,构型B的比例增加. 在溶剂DMSO-d₆中只存在一种构型A.     

A Comparison of GaN Epilayers with Multiple Buffer Layers and with a Single Buffer Layer Grown on Si（111） Studied by HRXRD and RBS/Channeling

Two hexagonal GaN epilayers （samples A and B） with multiple buffer layers and single buffer layer are grown on Si （111） by metal-organic vapour phase epitaxy （MOVPE）. From the results of Rutherford backscattering （RBS）/channeling and high resolution x-ray diffraction （HRXRD）, we obtain the lattice constant （a and c） of two GaN epilayers （aA = 0.3190 nm, cA = 0.5184 nm and aB = 0.3192 nm, CB = 0.5179 nm）, the crystal quality of two GaN epilayers （ ХminA=4.87%, ХminB =7.35% along 〈1-↑213〉 axis） and the tetragonal distortion eT of the two samples along depth （sample A is nearly fully relaxed, sample B is not relaxed enough）. Comparing the results with the two samples, it is indicated that sample A with multiple buffer layers have better crystal quality than sample B with a single buffer layer, and it is a good way to grow GaN epilayer on Si （111） substrates using multiple buffer layers to improve crystal quality and to reduce lattice mismatch.     

Polarized Micro-Raman Study of the Temperature-Induced Phase Transition In 0.67 Pb（Mg1/3Nb2/3）O3-0.33PbTiO3

Polarized Raman spectra of ferroelectric relaxor 0.67Pb（Mg1/3Nb2/3）O3-0.33PbTiO3 （0.67PMN-0.33PT） single crystal are systematically investigated in a wide temperature range from -196 to 600℃ by micro-Raman scattering technique. The results clearly reveal that there are two structural phase transitions in such composite ferroelectric relaxor： the rhombohedral-tetragonal （R- T） phase transition and the tetragonal-cubic （T- C） phase transition. The former occurs at about TR-T =34℃, corresponding to the vanishing of the soft A1 mode at 106cm^-1 recorded in the parallel polarization. The latter appears at about TT-C = 144℃, which can be verified with the vanishing of mode at 780cm^-1 measured in the crossed polarization.     

Normal coordinate in harmonic crystal obtained by virtue of the classical correspondence of the invariant eigen-operator

Noticing that the equation frac d²O_ndt²={H_c,{H_c,O_n}} =λO_n with double-Poisson bracket, where O_n is normal coordinate, H_c is classical Hamiltonian, is the classical correspondence of the invariant eigen-operator equation (2004 Phys. Lett. A. 321 75), we can find normal coordinates in harmonic crystal by virtue of the invariant eigen-operator method.     

Sol-gel法制备Er3+-Yb3+共掺杂Al2O3粉末光致发光特性

采用异丙醇铝[Al(OC₃H₇)₃]为前驱体,溶胶-凝胶(Sol-gel)法制备Er³⁺-Yb³⁺共掺杂Al₂O₃粉末.实验结果表明:900 ℃烧结的粉末为固溶Er³⁺、Yb³⁺的γ-(Al,Er,Yb)₂O₃相和少量θ-(Al,Er,Yb)₂O₃相的混合物.Er³⁺-Yb³⁺共掺杂Al₂O₃粉末具有中心波长为1.533 μm的光致发光(PL)特性.1 mol % Er³⁺和1 mol% Yb³⁺共掺杂的Al₂O₃粉末的PL强度较1 mol % Er³⁺掺杂提高2倍,半峰宽从53 nm增加到63 nm.随泵浦功率的提高,PL强度呈线性增加后渐呈饱和趋势.