Optical transitions of Eu3+ ions in EuCl3 solutions

The optical absorption spectra of EuCl₃ in aqueous and acidic solutions were measured in the visible anduv regions of the spectrum. The concentration as well as the temperature of the solutions were varied to establish an accurate free-ion energy level scheme of Eu³⁺. The energy levels were assigned on the basis of a correlation between the calculated and the experimentally observed transition energies and associated band intensities.     

Spectroscopic studies of Nd and Er in KGd(WO4)2 single crystals

Single crystals of KGd(WO₄)₂ doped with Nd³⁺ and Er³⁺ ions were grown by the top seeded solution growth method. Detailed analysis of the room-temperature absorption spectra was performed using the conventional Judd-Ofelt theory and actual dependence of the refractive index on the wavelength. In addition to the intensity parameters Ω_2,Ω_4,Ω₆, the branching ratios and radiative lifetimes were estimated for all possible transitions in the studied spectral region. Those transitions which can be potentially used for laser applications have been identified for both ions.     

BaCrSi4O10与AgGaSe2:Cr2+吸收光谱的精细结构及自旋单态对零场分裂参量的影响

在强场图像中构造了四角对称环境中Cr²⁺离子包括自旋单态在内的完全能量矩阵, 通过对角化能量矩阵方法, 计算得到了BaCrSi₄O₁₀与AgGaSe₂:Cr²⁺吸收光谱的精细结构及自旋单态对零场分裂参量的影响. 从理论上给出了BaCrSi₄O₁₀与AgGaSe₂:Cr²⁺吸收光谱的精细结构及BaCrSi₄O₁₀的零场分裂参量值. 计算结果显示自旋单态对零场分裂参量D的影响完全可忽略, 但对a和F的影响比较大. 这种影响主要来自自旋-轨道耦合导致的自旋五重态与自旋三重态和自旋单态的相互作用, 而自旋轨道耦合的选择定则显示自旋单态并非直接影响五重态而是通过自旋三重态间接地影响基态的五重态. 因此, 为了得到准确的零场分裂参量值, 所有的自旋态都应该考虑.     

Spectral Manifestations of Anion-Cation Interactions of Water-Soluble Porphyrins

The influence of anion-cation interactions on the structure and electronic absorption spectra of cationic 5,10,15,20-tetrakis-(4-N-methylpyridyl)porphyrin and anionic 5,10,15,20-tetrakis-(4-sulfonatophenyl)porphyrin has been investigated by absorption spectroscopy and molecular modeling. It is shown that the shifts of bands in the electronic absorption spectra appearing when passing from aqueous solutions to solutions in organic solvents are due to the interaction of ionized peripheral substituents of the porphyrin macrocycle with counterions. The bathochromic shift of the Q _x transition is due to the influence of counterions on the energy characteristics of the molecule itself, primarily, as a result of Coulomb interactions changing the relative position of the orbitals and the distribution of electron density on them. The hypsochromic shift of the Q _y transition is a consequence of the increase in the dihedral angle between the plane of the porphyrin macrocycle and the aromatic rings with ionized groups due to the decrease in the -electron interaction between them under the action of counterions.     

分子晶体的高压Raman光谱及结构相变

 本文综合我们从NH₃F（氟化胺）、HCCl₃（氯仿）、HCBr₃（溴仿）、S₈（硫）和C₃N₆H₆（三聚氰胺）等分子晶体获得的高压Raman光谱数据，讨论了分子晶体Raman光谱的谱带强度，频率位移，晶场劈裂和Grüneisen常数等对压力的依赖关系。总结了分子晶体压致结构相变的光谱证据和高压新相结构确定的几种方法。     

腔靶软X射线能谱结构的实验研究

叙述了利用双狭缝透射光栅谱仪,在高功率激光物理联合实验室神光装置上,对腔靶不同位置的能谱进行诊断,给出了腔靶源区能谱的空间分布和爆区的能谱结构,为腔靶辐射场的研究提供了重要信息。     

Spectral kinetic properties of Yb3+:Na4Y6F22 and Yb3+:LiLuF4 crystals

Yb³⁺ (2.7 at.%):Na₄Y₆F₂₂ and Yb³⁺(1 at.%):LiLuF₄ crystals were grown by the Bridgman-Stockbarger method. We measured the temperature dependences of the thermal conductivity of the crystals and the absorption spectra. We determined the radiative lifetime of the Yb³⁺ ion in these crystals (1.94 msec and 2.13 msec) and calculated the stimulated emission cross section spectra. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 6, pp. 761–766, November–December, 2007.     

NONLINEAR LOCALIZED STRUCTURE IN DUSTY PLASMA

The nonlinear effect of ponderomotive force of high-frequency ion motion on the low-frequency motion of ions coupling with the dust density fluctuation is investigated. The nonlinear localized structure described by Zakharov equations and nonlinear Schr?dinger equation in dusty plasma are obtained. Envelope solitons for high-frequency ion motion and the dust density cavitons are also obtained and discussed.     

Influence of isovalent substitutions on absorption spectra of orthoferrities

The role of impurity ions in formation of the optical properties of rare-earth orthoferrites is investigated. Optical spectra of the substituted against unsubstituted orthoferrites are presented. The influence of different isovalent substitutions on the optical absorption of orthoferrites that are promising for magnetooptics is studied. Institute of Solid-State and Semiconductor Physics of the Academy of Sciences of Belarus, 17, P. Brovka St., Minsk, 220072, Belarus. Translated from zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 5, pp. 642–645, September–October, 1997.     

Raman and infrared spectral studies of [C(NH2)3]2MII(H2O)4(SO4)2, MII = Mn,Cd and VO

The Raman and FTIR spectra of three metal guanidinium sulfates, [C(NH₂)₃]₂M^II(H₂O)₄(SO₄)₂, (M^II = Mn, Cd and VO), are recorded. The observed spectral bands are assigned in terms of the fundamental modes of vibration of the guanidinium ions, sulfate groups and water molecules. The appearance of the sulfate tetrahedra's ν₁ and ν₂ modes in the IR spectra and the partial lifting of the ν₄ mode in the Raman spectra indicate the distortion of the SO₄²⁻ tetrahedra in the structure, so that its symmetry is lowered from T_d to C₁. The geometry of the sulfate group in guanidinium vanadyl sulfate does not deviate much from that of the average sulfate group. The distortion of the SO₄ tetrahedra is stronger in GuCds than in GuMnS. The CN₃ group in the guanidinium ion is planar (D_3h point group) in GuCdS and GuMnS, whereas it is lowered in the vanadyl compound. Furthermore, the spectral analyses show the presence of weak hydrogen bonds in the structures. Copyright © 2007 John Wiley & Sons, Ltd.     

原子势模型理论中精细结构的计算公式

应用微扰理论导出了最弱受约束电子势模型理论中精细结构的计算公式，该公式可直接用于单价原子（离子）能级的精细结构的计算。     

压气机叶栅壁面拓扑和二次流结构分析

本文从涡动力学原理出发，根据实验测量和流场显示结果，对压气机平面叶机的壁面拓扑和叶栅二次流结构进行了研究．由叶栅壁面拓扑分析和二次流结构可知，叶栅的通道涡较强，出口集中脱落涡和角区分离泡的存在，造成了叶栅两端区较高的二次流损失，并且随叶栅来流冲角的提高，旋涡出现破裂，二次流损失进一步提高．     

CdSxSe1-x纳米微晶的辐射跃迁过程

利用变温吸收光谱和光致发光光谱研究了CdS_xSe_1-x纳米微晶的辐射跃迁过程.由Varshni公式,拟合了微晶的吸收峰随温度的变化.根据变温发射光谱,研究了发光峰位置和温度的依赖关系,并分析了吸收峰和发光峰随温度变化的快慢.对发光的动力学过程.作了简单的分析.     

气液段塞流气弹区相界面结构理论研究

根据气液段塞流气弹区相界面结构特征将气弹分为气弹头、气弹体、水跃面和气弹尾四部分,并根据各自的流动和界面结构特征分别进行模化,建立了描述不同倾角的圆管内气液段塞流气弹区相界面结构的一维理论模型.该模型的计算结果表明气液混合Froude数、管道倾角和气弹长度显著影响气液段塞流气弹区相界面结构,计算与实验结果吻合良好.     

湍流边界层拟序结构的大涡模拟研究

采用动力亚格子模型,利用大涡模拟方法模拟了雷诺数为13000的充分发展槽道湍流流动。从瞬时速度和脉动 速度场、脉动速度相关、均方根脉动涡量分布、以及瞬时涡量场等多个方面,对湍流边界层流动的拟序结构进行了分析, 包括近壁区小尺度湍流结构和瞬态过程,如条纹结构、喷射和扫掠过程、以及近壁旋涡结构等。     

1.315μm附近CO2的高分辨率吸收光谱

 利用可调谐激光长程吸收光谱测量系统，记录到1.315μm附近高气压（80kPa和40kPa）CO₂的高分辨率吸收光谱，拟合分析获得谱线参数，结果与HITRAN 2k的数据基本一致。用程差法测量了绝对吸收，氧碘激光频率(7 603.138 5cm^-1)的总吸收截面为(0.23~0.29)×^-24cm²。仅计算谱线吸收的吸收截面为0.18×10^-24cm²。在1.315μm波段COCO₂存在连续吸收，吸收截面为(0.05~0.11)×10^-24cm²。还讨论了测量误差问题。     

IR spectra of tellurium germanate glasses and their structure

We have used IR spectroscopy to study the structure of tellurium germanate glasses synthesized in the system TeO₂-GeO₂-B₂O₃-PbO. The structure of the glasses consists of [BO₃], [BO₄], [GeO₄], [GeO₆], [TeO₃], and [PbO₆] groups. Changes in the coordination of boron and germanium ions occur when the PbO and GeO₂ contents in the glasses increase. The glasses are attractive for designing optical and laser devices. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 1, pp. 78–81, January–February, 2007.     

用低能电子衍射谱计算过渡金属吸附CO的表面结构

本文用低能电子衍射谱研究了CO分子吸附在过渡金属上的表面结构。     

机敏材料与结构中的准分布式光纤传感阵列

介绍适用于机敏材料与结构中状态监测和损伤估计的三种简单的强度调制型准分布式光纤传感阵列，并比较其各自的优缺点。     

聚乙烯基咔唑与Alq3混合薄膜的发光性能与能量传递过程

研究了Alq3与聚乙烯基咔唑(PVK)按不同比例的混合体系制备的薄膜的发光特性.通过对混合薄膜的吸收光谱、激发光谱和发射光谱的分析，研究了PVK与Alq3之间的 能量传递规律.当Alq3与PVK的质量比为1∶7时，能量传递效率最高.用一个由单链模 型扩展到包括杂质的哈密顿量对实验进行模拟，发现该模型能够较好地解释有关的实验结果. 关键词： 吸收光谱 激发光谱 发射光谱 能量传递