交叉分子束实验研究F+D_2(v=1,j=0)反应（英文）

本文使用交叉分子束方法研究了氟原子和振动激发态氖分子D_2(v=1,j=0)的反应.使用受激拉曼抽运的方法制备了振动激发的D_2分子.实验中未观测到来自于旋轨耦合激发态氟原子F*(~2P_(1/2))与振动激发态D_2分子的贡献.观测到来自于旋轨耦合基态氟原子F(~2P_(3/2))和振动激发态D_2的反应信号,相应的产物DF分子布居于u'=2,3,4,5振动态上.与振动基态反应F+D_2(v=1,j=0)相比,振动激发态反应F+D_2(v=1,j=0)生成的DF产物转动分布更"热".获得了振动激发反应的四个碰撞能在0.32至2.62 kcal/mol范围内的微分反应截面.在最低的碰撞能0.32 kcal/mol下,所有振动态的DF产物都以后向散射为主.随着碰撞能的增加,DF产物的角分布逐渐从后向转移到侧向.测量了DF(v'=5)产物的前向微分散射截面随碰撞能变化的曲线.前向散射的DF(v'=5)信号出现于1.0 kcal/mol.在2.62 kcal/mol碰撞能下DF(v'=5)主要为前向散射.     

F+H2→HF+H反应的全量子态分辨的散射动力学研究

利用高灵敏度的氢原子里德堡飞渡时间谱方法研究了 F H_2→HF H 反应碰撞能在5.02kJ/mol 下的交叉分子束反应态态散射动力学.所有在时间飞渡谱中被观测到的谱峰可以归属为 HF 产物的振转态结构.还观测到了明显的 HF(v’=3)前向散射,以及少许的 HF(v’=2)前向散射.     

H+H2反应截面的全量子力学研究

利用全量子力学耦合通道扭曲波近似(CCDWA)方法和三种势能面计算了H+H2(vα=0,jα=0)→H2(vβ,jβ)+H碰撞的反应截面,并与准经典弹道计算结果及公认较好的计算结果作了比较.研究表明:在相同的势能面下利用CCDWA方法得到的截面和公认较好的计算结果符合很好,而准经典弹道计算的反应截面误差较大. 关键词： 反应散射 势能面 反应截面     

Li+HF(v = 0–3, j = 0)→LiF+H 反应的立体动力学理论研究

基于2003年Alfredo Aguado 等人构造的新势能面(Aguado和Paniagua. J. Chem. Phys., Vol. 119, No. 19, 2003), 本文结合振动激发和碰撞能两个因素,采用准经典轨线的方法对反应Li+HF(v=0–3) 的k-j' 两矢量相关和k-k'-j'三矢量相关的分布函数及极化微分反应截面进行了详细的立体动力学研究. 结果表明, 描述三原子分子反应的k-j'两矢量相关联的函数P(θ_r)分布不受振动激发影响, 而碰撞能则对其影响较大. 描述 k-k'-j'三矢量相关的函数P(φ_r)分布和极化微分反应截面对振动激发较敏感, 同时我们发现碰撞能对P(φ_r)分布和极化微分反应截面也有较大影响. 关键词： 矢量相关 立体动力学 准经典轨线方法 极化微分反应截面     

碰撞能对O++DH (v=0, j=0)→OD++H的准经典轨线

运用准经典轨线的方法,基于RODRIGO势能面,研究反应体系O⁺+DH (v=0, j=0)→OD⁺+H的立体动力学性质. 对描述k-j′两矢量相关和k-k′-j′三矢量相关的分布函数P(θr)和P(φr)以及产物转动取向参数进行了详细的讨论,发现极化微分反应截面呈现有趣的现象. 计算了反应几率与反应截面. O⁺+DH (v=0, j=0)→OD⁺+H反应的立体动力学性质对体系的碰撞能非常敏感.     

Sr+HF体系的动力学研究

应用扩展的LEPS势能面 ,对处于高碰撞能零振动激发 (Ecol=5 4 .18kJ/mol ,ν =0 ,j=0 )和低碰撞能低振动激发 (Ecol=7.5 6kJ/mol ,ν =1,j=0 )两种初始条件下的Sr+HF体系的竞争反应模式、定态分布函数Pν(b)以及反应碰撞能对产物SrF转动取向的影响进行了准经典轨线计算 ,计算结果与实验结果及相关理论符合得很好 ,且能给予实验以合理的动力学解释 . The quasiclassical trajectory method based on the extended LEPS potential energy surface has been employed here to investigate the reaction mechanism and features in the reaction Sr+HF→SrF+H at two reactional conditions (collision energy E c o l=54.18 kJ/mol, ν=0, j=0 and E c o l=7.56 kJ/mol, ν=1, j=0). The dynamical features in the competitive reaction modes are discussed and the stationary distribution function P ν(b) of the product SrF has already been deduced...     

高分辨交叉分子束实验研究F+HD→HF+D在碰撞能为5.43～18.73 kJ/mol的反应

运用高分辨的H/D原子里德堡标记飞行时间谱方法,研究了F+HD→HF+D反应在5.43～18.73 kJ/mol十个碰撞能下的动力学过程. 获取了产物振转态分辨的微分截面. HF(v′=2)前向产物的强度随着碰撞能的增大而降低,表明随着碰撞能的增大共振贡献减弱. 当碰撞能高于HF(v′=3)产物的阈值能量时,观察到了该产物的前向散射峰. 分析了总能量在产物振动、转动和平动中的分配以及HF产物的振动分支比随碰撞能的变化关系.     

O(3P)+CD4反应的含时波包动力学计算

基于Modified Jordan和Gilbert的势能面,运用SVRT(semirigid vibrating rotor target)模型和TDWP(Time-Dependent Wave Packet)方法,对O(3P)+CD4反应体系进行了含时量子动力学计算,给出了该体系的总反应几率,散射截面和热速率常数等结果.通过对j=0时, v=0,1的反应几率的计算,看出D-CD3的振动激发,极大地提高了反应几率,而反应阈能明显降低,说明反应分子的振动能对分子的碰撞反应有重要贡献. 而对于v=0时j=0,1,2,3的反应几率的计算,得出转动量子数j的增大,也会使反应几率有较大的提高,但反应阈能基本不变.     

O(3P)+CD4反应的含时波包动力学计算

基于Modified Jordan和Gilbert的势能面,运用SVRT(semirigid vibrating rotor target)模型和TDWP(Time-Dependent Wave Packet)方法,对O(3P)+CD4反应体系进行了含时量子动力学计算,给出了该体系的总反应几率,散射截面和热速率常数等结果.通过对j=0时, v=0,1的反应几率的计算,看出D-CD3的振动激发,极大地提高了反应几率,而反应阈能明显降低,说明反应分子的振动能对分子的碰撞反应有重要贡献. 而对于v=0时j=0,1,2,3的反应几率的计算,得出转动量子数j的增大,也会使反应几率有较大的提高,但反应阈能基本不变.     

原子-多原子分子反应的含时波包理论研究

基于Modified Jordan和Gilbert的势能面，运用SVRT(semirigid vibrating rotor target)模型和TDWP(Time-Dependent Wave Packet)方法，对D CH4，O(^3P) CH4反应体系进行了含时波包动力学研究，计算得到了不同初始振动态的总反应几率，总散射截面和热速率常数。通过对j=0时，v=0，1的反应几率的计算，看出H—CH3的振动激发，极大地提高了反应几率，而反应阈能明显降低，说明反应分子的振动能对分子的碰撞反应有重要贡献。     

Coulomb displacement energies of the T = 1, J = 0 states of A = 42 nuclei

Coulomb displacement energies of the T = 1, J = 0⁺ and 6₁⁺ states of A = 42 nuclei are analyzed with previously known charge dependent forces and effects, and with the available HartreeFock single-particle wave functions. From the study of the Coulomb displacement energies of the 6₁⁺ states, it is found that the present knowledge on the charge dependence, including a phenomenological charge symmetry breaking force previously introduced so as to help explain the Nolen-Schiffer anomaly, gives a sufficient and consistent explanation for both single-particle and twoparticle systems. From the study of the 0⁺ states, we found that the Coulomb displacement energies of the second 0₂⁺ states can be explained with a compensation between the smaller Coulomb energies of the second lowest two-particle state and larger ones of the deformed 4p-2h state.     

I=0 toI=1 transition form factors

A method is proposed to extend the hard scattering picture of Brodsky and Lepage to transitions between hadrons with orbital angular momentuml=0 andl=1. The use of covariant spin wave functions turns out to be very helpful in formulating that method. As a first application we construct a light-cone wave function of the nucleon resonance N^*(1535) in the quark-diquark picture. Using this wave function and the extended hard scattering picture, theN-N ^* transition form factors are calculated at large momentum transfer and the results compared to experimental data. As a further application of our method we briefly discuss the- a₁ form factors in an appendix.Supported by the Deutsche Forschungsgemeinschaft.     

空间光学的发展与波前传感技术

摘要：进入21世纪，国际上一些发达国家和有关部门都已制定了空间发展战略规划，如美国航空航天局（NASA）、欧洲空间局（ESA）和俄罗斯政府相关部门等都提出空间发展战略规划，这些规划提出了今后一段时间内空间科学要解决的问题和发展的方向，而解决这些问题并推进空间技术的发展很大程度上依赖于先进的光学和无线电望远镜及仪器设备。因此，本文介绍本世纪初国际上空间科学应用的大型天文望远镜的发展情况，重点描述了大口径光学望远镜的光学系统以及实现这类天文望远镜的关键技术之一一波前传感技术。     

New compactifications of Chiral N = 2, d = 10 supergravity

We present a number of new compactifying solutions of chiral N = 2 ten-dimensional supergravity to five dimensions. Several are of the standard Freund-Rubin type; we give a complete classification of such compactifications for which the internal space M⁵ is a coset manifold. In another type of solution M⁵ is a non-Einstein U(1) bundle over a four-dimensional Kähler space, and the complex three-index field strength is nonvanishing in the internal directions. The latter construction gives a solution with SU(3) symmetry when M⁵ is taken to be a stretched five-sphere.     

Investigation of the stability of superheavy nuclei aroundZ=114 andZ=164

The potential-energy-surface has been calculated using a method developed in a previous paper. Two regions of relative stability against spontaneous fission aroundZ=114 andZ=164 are discussed in greater detail. The stability of the quasistable elements against fission is discussed and the stability against alpha- and beta-decay is estimated by using the mass formula of Myers-Swiatecki. It is found that quasistable elements should exist in the regions aroundZ=114 andZ=164.     

N = 3 and N = 1 supersymmetry in a new class of solutions for d = 11 supergravity

We present a new class of compactifying solutions for d = 11 supergravity. The internal 7-spaces are described by coset manifolds N^pqr of the form SU(3) × U(1)/U(1) × U(1). The three integers p, q, r characterize the embedding of the stability subgroup U(1) × U(1) in SU(3) × U(1).Their supersymmetry content is quite remarkable. For a particular choice of p, q, r the isometry of N^pqr is SU(3) × SU(2): in this case we find that N = 3 supersymmetry survives. For all the other values of p, q, r, supersymmetry is broken to N = 1, and the isometry group is SU(3) × U(1).We also find a class of solutions with internal photon curl F_αβγδ ≠ 0, breaking all supersymmetries.     

The decay of theT=1 isospin triplet inA=12 systems

A complete theoretical study is carried out of the beta decays of the¹²B and¹²N ground states to the¹²C ground state. We calculated the form factor coefficientsF _KLs ^N (k_e, m, n, ρ) using the Cohen-Kurath wave functions. In particular, we obtained reasonable values for the form factor coefficients ^A F ₁₀₁ ⁰ and ^v F ₁₁₁ ⁰ whose ratio contains the influence of the weak magnetism coupling constant. It is shown that in this way the measurements of the shape factors presented by Wu and coworkers can be explained. In addition, it is demonstrated that the contribution of the term proportional to (WR)² cannot be completely neglected because of the large end point energyW ₀. From our value of ^v F ₁₁₁ ⁰ we have derived the radiative widthΓ _γ (M1) of the isobaric analogγ transition from the excited state¹²C^* to the ground state of¹²C. The result is in good agreement with the experimental data. For both beta transitions we have evaluated theft values which are in good agreement with the experimental values. It is confirmed that the difference between theft values for both beta transitions can be accounted for by binding energies effects.     

A relation betweenD=10, D=26 andD=32: Analysing the spacetime content of string-type field theories

A detailed analysis of the spacetime content of string-type field theories is presented. We rigorously explain the appearance ofD=10 andD=26, and argue that they are naturally contained inD=32. Our results suggest a new way to the compactification of theD=10 fermionic string and possible new (fermionic) models forD=4, D=6 andD=18. Some connected aspects are also discussed.