Plasma plume induced during laser ablation of graphite

The plasma plume induced during ArF laser ablation of a graphite target is studied. Velocities of the plasma expansion front are determined by the optical time of flight method. Mass center velocities of the emitting atoms and ions are constant and amount to 1.7×10⁴ and 3.8×10⁴ m s⁻¹, respectively. Higher velocities of ions result probably from their acceleration in electrostatic field created by electron emission prior to ion emission. The emission spectroscopy of the plasma plume is used to determine the electron densities and temperatures at various distances from the target. The electron density is determined from the Stark broadening of the Ca II and Ca I lines. It reaches a maximum of ∼9.5×10²³ m⁻³ 30 ns from the beginning of the laser pulse at the distance of 1.2 mm from the target and next decreases to ∼1.2×10²² m⁻³ at the distance of 7.6 mm from the target. The electron temperature is determined from the ratio of intensities of ionic and atomic lines. Close to the target the electron temperature of ∼30 kK is found but it decreases quickly to 11.5 kK 4 mm from the target.     

Characterisation of laser-produced tungsten plasma using optical spectroscopy method

This paper describes results of spectroscopic investigation of laser-produced tungsten plasma. The laser intensity on the target surface reached up to 30 GW/cm² depending on the focusing conditions. Optical spectra emitted from plasma plumes which were formed under vacuum conditions in front of the tungsten target due to the interaction of Nd-YAG laser pulses (1.06 μm, 0.5 J), were characterised by means of an optical spectrometer (λ/Δλ= 900) in the wavelength range from 300 to 1100 nm. The spectra were recorded automatically with the use of a CCD detector with exposition time varied from 100 ns to 50 ms. On the basis of WI and WII lines it was possible to estimate electron temperature and electron density which corresponded to the expansion phase of the plasma. T_e and N_e were measured as 1.1 eV and 8×10¹⁶ cm^-3, respectively. The spectra collected by the ion energy analyser showed that the plasma included tungsten ions up to 6+ ion charge. Signals from the ion collector allowed to estimate the average value of ion energy of tungsten as 4.6 keV. Basing on this value the electron temperature corresponding to the initial stage of the plasma formation was estimated to be about 320 eV. Optical microscope investigation showed that laser irradiation caused structural changes on the surface of the target.     

Characterization of the laser ablation plasma used for the deposition of amorphous carbon

The plasma produced by laser ablation of a graphite target was studied by means of optical emission spectroscopy and a Langmuir planar probe. Laser ablation was performed using a Nd:YAG laser with emission at the fundamental line with pulse length of 28 ns. In this work, we report the behavior of the mean kinetic energy of plasma ions and the plasma density, as a function of the laser fluence (J/cm²), and the target to probe (substrate) distance. The characterized regimes were employed to deposit amorphous carbon at different values of kinetic energy of the ions and plasma density. The mean kinetic energy of the ions could be changed from 40 to 300 eV, and the plasma density could be varied from 1 × 10¹² to 7 × 10¹³ cm⁻³. The main emitting species were C⁺ (283.66, 290.6, 299.2 and 426.65 nm) and C⁺⁺ (406.89 and 418.66 nm) with the C⁺ (426.65 nm) being the most intense and that which persisted for the longest times. Different combinations of the plasma parameters yield amorphous carbon with different structures. Low levels (about 40 eV) of ion energy produce graphitic materials, while medium levels (about 200 eV) required the highest plasma densities in order to increase the CC sp³ bonding content and therefore the hardness of the films. The structure of the material was studied by means of Raman spectroscopy, and the hardness and elastic modulus by depth sensitive nanoindentation.     

X-Rays emission by high-intensity pulsed lasers irradiating thin foils at PALS laboratory

X-rays and forward ion emission from laser-generated plasma in the Target Normal Sheath Acceleration regime of different targets with 10-μm thickness, irradiated at Prague Asterix Laser System (PALS) laboratory at about 10¹⁶ W/cm² intensity, employing a 1,315 nm-wavelength laser with a 300-ps pulse duration, are investigated. The photon and ion emissions were mainly measured using Silicon Carbide (SiC) detectors in time-of-flight configuration and X-ray streak camera imaging. The results show that the maximum proton acceleration value and the X-ray emission yield growth are proportional to the atomic number of the irradiated targets. The X-ray emission is not isotropic, with energies increasing from 1 keV for light atomic targets to about 2.5 keV for heavy atomic targets. The laser focal position significantly influences the X-ray emission from light and heavy irradiated targets, indicating the possible induction of self-focusing effects when the laser beam is focalized in front of the light target surface and of electron density enhancement for focalization inside the target.     

Investigations of the spatio-temporal build-up of atomic oxygen inside the micro-scaled atmospheric pressure plasma jet

The ascent of atomic oxygen densities created inside the micro-scaled atmospheric pressure plasma jet has been investigated spatially resolved under parameter variations such as applied power, gas mixture and gas velocity using two-photon absorption laser induced fluorescence spectroscopy. Along the discharge channel an increase of the atomic oxygen density within the plasma is observed. The density shows an exponentially asymptotic convergence into an equilibrium close to the effluent. In the post-discharge effluent an exponential spatial decrease can be found. Typical ascent distances of a few hundreds of μm decrease with the applied power and increase with gas velocity and oxygen admixture. The maximum atomic oxygen density increases with applied power and admixed molecular oxygen up to more than 10¹⁶ cm^-3. An increase of the maximum atomic oxygen density with increasing gas velocity has been found. Optical emission spectroscopy measurements indicate a strong increase of the nitrogen emission at low gas flow rates along the channel.     

Low energy ion beams by laser interaction

We developed an ion accelerator with a double accelerating gap system supplied by two power generators of different polarity. The ions were generated by laser ion source technique. The laser plasma induced by an excimer KrF laser, freely expanded before the action of accelerating fields. After the first gap action, the ions were again accelerated by a second gap. The total acceleration can imprint a maximum ion energy up to 160 keV per charge state. We analysed the extracted charge from a Cu target as a function of the accelerating voltage at laser energy of 9, 11 and 17 mJ deposited on a spot of 0.005 cm². The peak of current density was 3.9 and 5.3 mA for the lower and medium laser energy at 60 kV. At the highest laser energy, the maximum output current was 11.7 mA with an accelerating voltage of 50 kV. The maximum ion dose was estimated to be 10¹² ions/cm². Under the condition of 60 kV accelerating voltage and 5.3 mA output current the normalized emittance of the beam measured by pepper pot method was 0.22 π mm mrad.     

Temperature and density spectroscopic measurements in different laser-generated plasmas

A pulsed Nd:Yag laser, at intensities of the order of 10¹⁰ W/cm², is employed to irradiate different thick metallic targets (Ti, Fe, Ag, and Ni) placed in vacuum. The obtained non-equilibrium plasmas are investigated with various analytical techniques. An electrostatic ion energy analyzer and different ion collectors are employed to monitor in situ the ions ejected from the plasma and to determine the core plasma temperature, the ion energy distributions and the ion angular emission. An optical spectrometer is employed to analyze the plasma corona emitted light vs. wavelength and to identify the emitted characteristic lines. The optical spectroscopy permitted to evaluate the electron temperatures and densities. Results show strong temperature and density gradients occurring in the laser-generated plasma plume.     

Enhanced field emission from pulsed laser deposited nanocrystalline ZnO thin films on Re and W

Nanocrystalline ZnO thin films have been deposited on rhenium and tungsten pointed and flat substrates by pulsed laser deposition method. An emission current of 1 nA with an onset voltage of 120 V was observed repeatedly and maximum current density ∼1.3 A/cm² and 9.3 mA/cm² has been drawn from ZnO/Re and ZnO/W pointed emitters at an applied voltage of 12.8 and 14 kV, respectively. In case of planar emitters (ZnO deposited on flat substrates), the onset field required to draw 1 nA emission current is observed to be 0.87 and 1.2 V/μm for ZnO/Re and ZnO/W planar emitters, respectively. The Fowler–Nordheim plots of both the emitters show nonlinear behaviour, typical for a semiconducting field emitter. The field enhancement factor β is estimated to be ∼2.15×10⁵ cm⁻¹ and 2.16×10⁵ cm⁻¹ for pointed and 3.2×10⁴ and 1.74×10⁴ for planar ZnO/Re and ZnO/W emitters, respectively. The high value of β factor suggests that the emission is from the nanometric features of the emitter surface. The emission current–time plots exhibit good stability of emission current over a period of more than three hours. The post field emission surface morphology studies show no significant deterioration of the emitter surface indicating that the ZnO thin film has a very strong adherence to both the substrates and exhibits a remarkable structural stability against high-field-induced mechanical stresses and ion bombardment. The results reveal that PLD offers unprecedented advantages in fabricating the ZnO field emitters for practical applications in field-emission-based electron sources.     

Characteristics of electron-free plasma confinement in an rf quadrupole field

A low-density plasma composed solely of massive atomic ions, namely Tl⁺ and I⁻, was produced by photodissociation of molecular TlI at low pressure, using the powerful 206 nm atomic iodine emission line, and confined in a Paul rf quadrupole electric field. A simple theoretical model based on an infinite homogeneous plasma of low density is used to estimate the perturbation of the ion oscillation frequencies in the external field due to the electrostatic interaction between the ions. The decay characteristics of the plasma under ionic recombinations were observed over a period of 10s, and the absolute ion density determined to be 1.1×10⁷ cm⁻³ with a maximum energy on the order of 5 eV. This work was originally undertaken at NASA/Goddard Space Flight Center, Greenbelt, MD., USA (1970–71) and continued at the CNRS Laboratoire de l'Horloge Atomique, Orsay, France. On leave at Department of Physics, University of Kuwait, Kuwait, Arabian Gulf.     

Characterization of laser-generated silicon plasma

A study of visible laser ablation of silicon, in vacuum, by using 3 ns Nd:YAG laser radiation is reported. Nanosecond pulsed ablation, at an intensity of the order of 10¹⁰ W/cm², produces high non-isotropic emission of neutrals and ionic species. Mass quadrupole spectrometry, coupled to electrostatic ion deflection, allows estimation of the energy distributions of the emitted species from plasma. Neutrals show typical Boltzmann-like distributions while ions show Coulomb-Boltzmann-shifted distributions depending on their charge state. Time-of-flight measurements were also performed by using an ion collector consisting of a collimated Faraday cup placed along the normal to the target surface. Surface profiles of the craters, created by the laser radiation absorption, permitted to study the ablation threshold and ablation yields of silicon in vacuum. The plasma fractional ionization, temperature and density were evaluated by the experimental data. A special regard is given to the ion acceleration process occurring inside the plasma due to the high electrical field generated at the non-equilibrium plasma conditions. The angular distribution of the neutral and ion species is discussed.     

Laser induced breakdown spectroscopy of germane plasma induced by IR CO2 pulsed laser

Laser-induced breakdown spectroscopy (LIBS) in germane (GeH₄), initially at room temperature and pressures ranging from 2 to 10 kPa, was studied using a high-power transverse excitation atmospheric (TEA) CO₂ laser (λ=10.653 μm, τ _FWHM=64 ns and power densities ranging from 0.28 to 5.52 GW cm⁻²). The strong emission spectrum of the generated plasma is mainly due to electronic relaxation of excited Ge, H and ionic fragments Ge⁺, Ge²⁺ and Ge³⁺. The weak emission is due to molecular bands of H₂. Excitation temperatures of 8100±300 K and 23,500±2500 K were estimated by Ge atomic and Ge⁺ singly ionized lines, respectively. Electron number densities of the order of (0.7–6.2)×10¹⁷ cm⁻³ were deduced from the Stark broadening of several atomic Ge lines. The characteristics of the spectral emission intensities from different species have been investigated as functions of the germane pressure and laser irradiance. Optical breakdown threshold intensities in germane at 10.653 μm have been determined. The mechanism of initiation of the laser-induced plasma in germane has been analyzed.     

Laser acceleration of light ions from high-intensity laser-target interactions

A systematic theoretical study of laser-irradiated targets made of material with increasing atomic number has been performed. The formation of energetic light ions resulting from the interaction of an intense ultrashort pulse laser with thin planar targets is investigated theoretically with a two-dimensional relativistic electromagnetic particle-in-cell model. A common parameter, the areal electron density of the foil, can be used to describe qualitatively targets made of different material. By varying either the laser intensity or the target thickness we observe a gradual transition of various ion acceleration mechanisms from one into another. Light ions, such as H⁺, Li³⁺, C⁶⁺, and Al¹³⁺, can be accelerated to GeV energies with existing laser systems at a laser fluence of 10–20 J/μm².     

Three-dimensional simulation of laser–plasma-based electron acceleration

A sequential three-dimensional (3D) particle-in-cell simulation code PICPSI-3D with a user friendly graphical user interface (GUI) has been developed and used to study the interaction of plasma with ultrahigh intensity laser radiation. A case study of laser–plasma-based electron acceleration has been carried out to assess the performance of this code. Simulations have been performed for a Gaussian laser beam of peak intensity 5 × 10¹⁹ W/cm² propagating through an underdense plasma of uniform density 1 × 10¹⁹ cm^− 3, and for a Gaussian laser beam of peak intensity 1.5 × 10¹⁹ W/cm² propagating through an underdense plasma of uniform density 3.5 × 10¹⁹ cm^− 3. The electron energy spectrum has been evaluated at different time-steps during the propagation of the laser beam. When the plasma density is 1 × 10¹⁹ cm^− 3, simulations show that the electron energy spectrum forms a monoenergetic peak at ~14 MeV, with an energy spread of ±7 MeV. On the other hand, when the plasma density is 3.5 × 10¹⁹ cm^− 3, simulations show that the electron energy spectrum forms a monoenergetic peak at ~23 MeV, with an energy spread of ±7.5 MeV.     

Prospects of “water-window” X-ray emission from subpicosecond laser plasmas

Soft-X-radiation in the “water-window” region (23.3–43.6 ?) mainly from carbon laser plasmas generated by subpicosecond (700 fs) 0.248-μm laser pulses is studied as a function of angle of incidence and intensity (up to 10¹⁸ W/cm²) for p-polarized laser light. Furthermore, comparison is made between plasmas generated from massive and foil targets. Numerical calculations are performed using a hydrocode coupled to X-ray line and continuum emission calculations including radiation transport. The optimized conditions to achieve maximum water-window X-ray emissivity and, in particular, carbon Lyman-α line emission are investigated. In addition, analytical scalings are presented. These theoretical results are essentially confirmed by previous experiments. It is found that at optimized conditions, picosecond or subpicosecond laser plasma X-ray sources with a power of the order of 1–10 GW in a spectral window of 1 ? could be developed. Received: 6 August 1998 / Final version: 6 August 1999 / Published online: 30 November 1999     

Transient reflectivity and transmission changes during plasma formation and ablation in fused silica induced by femtosecond laser pulses

We have studied the plasma formation and ablation dynamics in fused silica upon irradiation with a single 120 fs laser pulse at 800 nm by using fs-resolved pump-probe microscope. It allows recording images of the laser-excited surface at different time delays after the arrival of the pump pulse. This way, we can extract both the temporal evolution of the surface reflectivity and transmission, at 400 nm, for different spatial positions in the spots (and thus for different local fluences) from single series of images. At fluences well above the visible ablation threshold, a fast and large increase of the reflectivity is induced by the formation of a dense free-electron plasma. The maximum reflectivity value is reached within ≈1.5 ps, while the normalized transmission decreases within ≈400 fs. The subsequent temporal evolution of both transient reflectivity and transmission are consistent with the occurrence of surface ablation. In addition, the time-resolved images reveal the existence of a free-electron plasma distribution surrounding the visible ablation crater and thus formed at local fluences below the ablation threshold. The lifetime of this sub-ablation plasma is ≈50 ps, and its maximum electron density amounts to 5.5×10²² cm⁻³.     

Influence of the plasma parameters on the properties of aluminum oxide thin films deposited by laser ablation

The plasma produced by the ablation of a high purity Al₂O₃ target, using the fundamental line (1064 nm) of a Nd:YAG laser, was characterized. The laser fluence was varied in order to study its effect on the characteristics of the produced plasma as well as on the properties of the material deposited. Optical emission spectroscopy (OES) was used to determine the type of excited species present in the plasma. The mean kinetic energy of the ions and the maximum plasma density were determined from the time of flight (TOF) curves, obtained with a planar Langmuir probe. The obtained results reveal that the fast peak in the probe curve could be attributed to Al III, while the slow peak corresponds to the Al II. Aluminum oxide thin films were then deposited under the same conditions of the diagnosed plasma, in an attempt to correlate the plasma parameters with the properties of the deposited material. It was found that when Al II ion energies are lower than 461.0 eV the films deposited have structural characteristics similar to that of α-Al₂O₃, whereas at ion energies greater than 461.0 eV amorphous material was obtained.     

Enhanced production of fast multi-charged ions from plasmas formed at cleaned surface by femtosecond laser pulse

We present atomic, energy, and charge spectra of ions accelerated at the front surface of a silicon target irradiated by a high-contrast femtosecond laser pulse with an intensity of 3×10¹⁶ W/cm², which is delayed with respect to a cleaning nanosecond laser pulse of 3-J/cm² energy density. A tremendous increase in the number of fast silicon ions and a significant growth of their maximum charge in the case of the cleaned target from 5+ to 12+ have been observed. The main specific features of the atomic, energy, and charge spectra have been analyzed by means of one-dimensional hydrodynamic transient-ionization modeling. It is shown that fast highly charged silicon ions emerge from the hot plasma layer with a density a few times less than the solid one, and their charge distribution is not deteriorated during plasma expansion.This revised version was published online in August 2005 with a corrected cover date.     

Nonlinearity and time-resolved studies of ion emission in ultrafast laser ablation of graphite

We have investigated the laser fluence dependence of the ion emission process in ultrafast laser ablation of graphite using a time-of-flight technique. Two regimes of ion emission have been identified: (1) a highly nonlinear laser absorption process accompanied by generation of a transient electrical field on the surface and collisionless emission of ions due to electrostatic repulsion; (2) a saturation regime for laser power absorption characterised by nearly equal kinetic energy of ejected carbon clusters. We also show the effect of the surface temperature on the emitted clusters’ stability and the influence of nonlinearity on the intensity autocorrelation traces.     

Low-energy ion emission from a xenon gas-puff laser-plasma X-ray source

We have measured low-energy ion emission from a gas-puff laser-plasma X-ray source. The ions may cause the degradation of the condenser mirror of the extreme ultra-violet projection lithography system. A 0.7 J in 8 ns Nd:YAG laser at 1.06 μm was focused onto the xenon gas-puff target with an intensity of ∼10¹² W/cm². The silicon (111) plates, placed at a distance of 32 mm from the laser-interaction region, were exposed with the xenon ions. The average ion energy was measured to be less than 50 eV with a Faraday-cup detector placed close to the silicon plates. The xenon deposition occurred in the silicon plates with a depth of less than 40 nm. The deposition density was measured with a quadrupole secondary ion mass spectrometer to be 10²¹ /cm³ after 1500 laser shots. The energy-conversion efficiency from the laser energy into the ions is ∼0.1%/4 π sr/shot. For the lithography system, if we can remove such ion bombardment completely using novel techniques such as electro-magnetic devices or gas flow curtain techniques, the lifetime of the condenser mirror will be extended significantly. Received: 20 November 2000 / Published online: 9 February 2001     

Stimulated emission of x-rays from plasmas generated by short-pulse-laser-heating of solid targets

The problem of heating of a solid target to generate a nonequilibrium plasma by subnanosecond laser pulses is considered. For an appreciable absorption of energy from a Nd-glass laser, the critical density of the electrons in the plasma turns out to be 10²¹ cm⁻³. These electrons can be heated up to 10⁷ K or more by using pulses of about 10 picosecond duration and absorbed energy flux of the order of 10²¹ erg cm⁻² sec⁻¹. Starting from neutral atoms in a solid with a high atomic number, e.g., Z=26, for times in the picosecond regime the relevant rate equations are solved analytically to predict densities of the atoms at different ionization levels. It is shown that during such a short time the population density of the ions isoelectronic to neon builds up to a very large amount. This in turn leads to the population inversion in the 4s → 3p soft x-ray laser transition, via the electron-impact excitation of the 4s level of the isoelectronic neon ion. For the effective pumping times of the order of 5 picoseconds, a gain of the order of 10² db cm⁻¹ is predicted for the laser transition in Fe XVII, Co XVIII or Cu XX.