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1.
Direct numerical simulations with a C3-chemistry model have been performed to investigate the transient behavior and internal structure of flames propagating in an axisymmetric fuel jet of methane, ethane, ethylene, acetylene, or propane in normal earth gravity (1g) and zero gravity (0g). The fuel issued from a 3-mm-i.d. tube into quasi-quiescent air for a fixed mixing time of 0.3 s before it was ignited along the centerline where the fuel–air mixture was at stoichiometry. The edge of the flame formed a vigorously burning peak reactivity spot, i.e., reaction kernel, and propagated through a flammable mixture layer, leaving behind a trailing diffusion flame. The reaction kernel broadened laterally across the flammable mixture layer and possessed characteristics of premixed flames in the direction of propagation and unique flame structure in the transverse direction. The reaction kernel grew wings on both fuel and air sides to form a triple-flame-like structure, particularly for ethylene and acetylene, whereas for alkanes, the fuel-rich wing tended to merge with the main diffusion flame zone, particularly methane. The topology of edge diffusion flames depend on the properties of fuels, particularly the rich flammability limit, and the mechanistic oxidation pathways. The transit velocity of edge diffusion flames, determined from a time series of calculated temperature field, equaled to the measured laminar flame speed of the stoichiometric fuel–air mixtures, available in the literature, independent of the gravity level.  相似文献   

2.
This work analyses the classical Emmons (1956) solution of flat plate laminar flame combustion on a film of liquid fuel. A two-dimensional (2D) numerical model developed for this purpose has been benchmarked with experimental results available in the literature for methanol. In the parametric study, numerical predictions have been compared with Emmons classical solution. The study shows that the Emmons solution is valid in a range of Reynolds numbers where flame anchors near the leading edge of the methanol pool and the combustion zone is confined around the hydrodynamic and thermal boundary layers. However, in cases of low free stream velocities the combustion zone is beyond the boundary layer zone and the Emmons solution deviates. In cases of very high free stream velocities, the flame moves away from the leading edge and anchors at a location downstream. The Emmons solution is not applicable in this case as well. For the fuel considered in this study (methanol), accounting for thermal radiation, employing an optically thin radiation model, allows better agreement between experimental and numerical temperature profiles but does not affect the mass burning rates.  相似文献   

3.
A two-dimensional triple-flame numerical model of a laminar combustion process reflects flame asymmetric structural features that other analytical models do not generate. It reveals the pentasectional character of the triple flame, composed of the central pure diffusion-flame branch and the fuel-rich and fuel-lean branches, each of which is divided into two sections: a near-stoichiometric section and a previously unreported near-flammability-limits section with combined diffusion and premixed character. Results include propagation velocity, fuel and oxidiser mass fractions, temperature and reaction rates. Realistic stoichiometric ratios and reaction orders match experimental planar flame characteristics. Constant density, a one-step reaction, and a mixture fraction gradient at the inlet as the simulation parameter are imposed. The upstream equivalence ratio or the upstream reactant mass fractions are linear or hyperbolic functions of the transverse coordinate. The use here of experimental kinetics data differs from previous analytical works and results in flame asymmetry and different flammability limits. Upstream mixture composition gradient affects propagation velocity, flame curvature, diffusion flame reaction rate, and flammability limits. Flammability limits extend beyond those of a planar flame due to transverse heat and mass diffusion causing the pentasectional character.  相似文献   

4.
This work reports an experimental and kinetic modeling investigation on the laminar flame propagation of three butylbenzene isomers (n-butylbenzene, iso-butylbenzene and tert-butylbenzene)/air mixtures. The experiments were performed in a high-pressure constant-volume cylindrical combustion vessel at the initial temperature of 423 K, initial pressures of 1–10 atm, and equivalence ratios (?) of 0.7–1.5. The laminar burning velocities of butylbenzene/O2/He mixtures were also measured at 423 K, 10 atm and ? = 1.5 to provide additional experimental data under conditions that the butylbenzene/air experiments are susceptible of cellular instability. Comparison among the laminar burning velocities of butylbenzenes including both the three isomers investigated in this work and sec-butylbenzene investigated in our recent work [Combust. Flame 211 (2020) 18–31] shows remarkable fuel isomeric effects, that is, iso-butylbenzene has the slowest laminar burning velocities, followed by n-butylbenzene and tert-butylbenzene, while sec-butylbenzene has the fastest laminar burning velocities. A kinetic model for butylbenzene combustion was developed to simulate the laminar flame propagation of butylbenzenes. Sensitivity analysis was performed to reveal important reactions in laminar flame propagation of butylbenzenes, including both small species reactions and fuel-specific reactions. Kinetic effects are concluded to result in the different laminar burning velocities of four butylbenzene isomers. Small species reactions control the laminar flame propagation under lean conditions, which results in small differences of laminar burning velocities. Chain termination reactions, especially fuel-specific reactions, have important contributions to inhibit the laminar flame propagation under rich conditions. The structural features of butylbenzene isomers can significantly affect the formation of some crucial radicals such as methyl, cyclopentadienyl and benzyl radicals under rich conditions, which leads to remarkable fuel isomeric effects on their laminar burning velocities, especially at high pressures.  相似文献   

5.
A numerical and experimental study is performed to investigate soot formation from jet fuel in a laminar coflow diffusion flame. The combustion chemistry of the fuel is simulated using (1) the MURI jet fuel surrogate (Dooley et al. 2012) with a modestly reduced Ranzi mechanism (Ranzi et al. 2012), and (2) the recently proposed HyChem model (Xu et al. 2018) combined with the KAUST PAH mechanism 2 (Wang et al. 2013). The two reaction mechanisms are coupled with a sectional soot model to simulate a coflow diffusion flame of methane doped with the MURI jet fuel surrogate. The combined laser extinction and two-angle elastic light scattering method is used to perform non-intrusive in situ measurements of soot volume fraction, primary particle diameter and number density. The good agreement including soot particle size and number density between the experimental data and the simulation results computed with the reduced Ranzi mechanism demonstrate the robustness of the soot model to changes in fuel composition, as the model parameters are unchanged with a previous numerical study of soot formation of n-propylbenzene/n-dodecane mixtures (Zhang and Thomson, 2018). The computation with the combined HyChem/KAUST mechanism predicts similar results as the computation with the detailed chemistry of the reduced Ranzi mechanism for fuel breakdown, thus the basic premise of the HyChem model that the fuel decomposition process can be greatly simplified with the lumped reaction steps is supported. The results also show that by adding a PAH growth scheme to the HyChem model, the approach can be used to predict soot formation from jet fuel combustion in a laminar coflow diffusion flame. Finally, the dependency of the soot prediction on PAH chemistry is discussed and it is suggested that more experimental data is needed to validate the PAH mechanism and improve the predictive accuracy of the model.  相似文献   

6.
The study of edge flames has received increased attention in recent years. This work reports the results of a recent study into two-dimensional, planar, propagating edge flames that are remote from solid surfaces (called here, “free-layer” flames, as opposed to layered flames along floors or ceilings). They represent an ideal case of a flame propagating down a flammable plume, or through a flammable layer in microgravity. The results were generated using a new apparatus in which a thin stream of gaseous fuel is injected into a low-speed laminar wind tunnel thereby forming a flammable layer along the centerline. An airfoil-shaped fuel dispenser downstream of the duct inlet issues ethane from a slot in the trailing edge. The air and ethane mix due to mass diffusion while flowing up towards the duct exit, forming a flammable layer with a steep lateral fuel concentration gradient and smaller axial fuel concentration gradient. We characterized the flow and fuel concentration fields in the duct using hot wire anemometer scans, flow visualization using smoke traces, and non-reacting, numerical modeling using COSMOSFloWorks. In the experiment, a hot wire near the exit ignites the ethane-air layer, with the flame propagating downwards towards the fuel source. Reported here are tests with the air inlet velocity of 25 cm/s and ethane flows of 967-1299 sccm, which gave conditions ranging from lean to rich along the centerline. In these conditions the flame spreads at a constant rate faster than the laminar burning rate for a premixed ethane-air mixture. The flame spread rate increases with increasing transverse fuel gradient (obtained by increasing the fuel flow rate), but appears to reach a maximum. The flow field shows little effect due to the flame approach near the igniter, but shows significant effect, including flow reversal, well ahead of the flame as it approaches the airfoil fuel source.  相似文献   

7.
以往关于层流火焰速度的理论分析均只考虑单组分燃料,本文对双组分燃料的平面火焰进行了大活化能渐近理论分析。在理论分析中,将火焰结构分为预热区、化学反应区和平衡区,并在大活化能假设下对各个区域分别求解了关于温度与燃料质量分数的微分方程。根据每两个区域分界面上满足的结合条件,本文推导出了双组分燃料的层流火焰速度模型。该模型表明双组分燃料层流火焰速度的平方为各个单组分燃料层流火焰速度平方的加权平均。  相似文献   

8.
A thermally thick slab of polymethyl methacrylate was used to study the effects of the inclination angle of a fuel surface on upward flame spread. While investigation of upward spread over solid fuels has typically been restricted to an upright orientation, inclination of the fuel surface from the vertical is a common occurrence that has not yet been adequately addressed. By performing experiments on 10 cm wide by 20 cm tall fuel samples it was found that the maximum flame-spread rate, occurring nearly in a vertical configuration, does not correspond to the maximum fuel mass-loss rate, which occurs closer to a horizontal configuration. A detailed study of both flame spread and steady burning at different angles of inclination revealed the influence of buoyancy-induced flows in modifying heat-flux profiles ahead of the flame front, which control flame spread, and in affecting the heat flux to the burning surface of the fuel, which controls fuel mass-loss rates.  相似文献   

9.
Due to recent interest in methanol economy, it is seen that a numerical study of combustion of methanol in a comprehensive manner is necessary. Motivated from this interest and based on the studies from literature, a numerical study on prediction of structures of non-premixed methanol-air flames in laminar forced convective environment is reported. Two-dimensional, planar and axisymmetric, computational domains are considered. Corresponding governing equations for conservation of mass, momentum, species and energy have been solved using Ansys FLUENT. The numerical model incorporates multi-component diffusion, variable thermal and physical properties, a short chemical kinetics mechanism with 18 species and 38 elementary reactions, and a non-luminous thermal radiation model. Homogeneous flames in opposed flow and heterogeneous flames in cross-flow and co-flow configurations are studied. For heterogeneous flames, interface conditions at the liquid methanol surface are defined systematically using a user-defined function. Numerical results are validated against the experimental results available in literature. Results in terms of mass burning rates, flow, species and temperature fields have been presented to describe the flame characteristics.  相似文献   

10.
Laminar flame speeds of premixed jet fuel/air with the addition of hydrogen, methane and ethylene are measured in a constant-volume bomb at an initial temperature of 420 K, initial pressure of 3 atm, equivalence ratios of 0.6–1.5 and gas mass fractions of 0–50%. The experimental results show that the addition of hydrogen and ethylene can significantly improve the laminar flame speed of the liquid jet fuel, while the addition of methane shows a weak inhibitory effect, and these effects are relatively remarkable on the fuel-rich conditions. The laminar flame speed of the dual fuels/air is linearly dependent on the additional gas mass fraction. A kinetic analysis indicates that the gas addition causes both thermodynamic and chemical kinetic effects on the laminar flame speed of the dual fuels/air. The adiabatic temperature increases and decreases with the addition of hydrogen/ethylene and methane, respectively. A sensitivity analysis shows that the reactions concerning to the H, CH3 and C2H3 radicals become significant with the addition of hydrogen, methane and ethylene, respectively, and that the different values of the rate of product (ROP) of these species via the critical reactions lead to a different promotional or inhibitory effect on the fuel-rich and fuel-lean conditions.  相似文献   

11.
Using a detailed two-dimensional numerical model, a systematic investigation has been made to study the effect of fuel Lewis number (LeF = α/DF) and mass transfer on flame spread over thin solids. The fuel Lewis number affects the flame spread rates for both concurrent and opposed flames over thin fuels. The dependence of the flame spread rate on LeF for these two spreading modes is, however, not the same. In opposed flame spreads (zero-gravity, self-propagation, and normal gravity downward propagation), the flame spread rate vs. LeF curve is non-monotonic with a maximum value occurring at an intermediate value of LeF = 0.5. In steady, concurrent spread in zero-gravity with low-speed flow and a constant flame length, the flame spread rate decreases with LeF in a monotonic manner. By using the computational model as a tool, the effects of fuel mass diffusion perpendicular to and parallel with the solid surface are isolated to obtain more physical insight on the two-dimensional aspect of fuel mass transfer on flame spread. In addition, the model has also been used to decouple the solid evaporation process so that the fuel diffusion effect in the gas-phase can be isolated. Both of these theoretical exercises contribute to the understanding of mass transfer effects on the flame spreading phenomena over solids.  相似文献   

12.
Intricacies associated with the estimation of laminar flame speed using the axisymmetric Bunsen flame technique were assessed, through parametric direct numerical simulations. The study involved methane-air mixtures at atmospheric pressure and temperature, and both the flame cone angle and flame surface area methods were utilized to estimate the laminar flame speeds based on conditions used in recent relevant experimental studies. The results provided insight into the details of the flame structure and allowed for the assessment of various non-idealities and the attendant uncertainties associated with the estimation of laminar flame speeds. Additionally, molecular transport effects were investigated by altering the fuel diffusivity, in order to evaluate its impact on the flame structure and propagation under the presence of negative stretch. The modification of fuel diffusivity was found to affect the burning rate as stretch varies. Under fuel rich conditions, decreasing the fuel diffusivity was found to have an opposite effect on the heat release and thus the burning rate, when compared to positively stretched flames that have been investigated recently in a similar manner. The reported results are expected to provide guidance in flame propagation experiments using the convenient Bunsen flame method at near-atmospheric or elevated pressures, as well as insight into the effects of negative stretch that has, compared to positive, attracted less attention in past studies.  相似文献   

13.
The recently reported, experimentally observed, unusual behaviour of organic gellant-based fuel droplets which, under appropriate ambient thermal conditions, evaporate and burn in an oscillatory fashion is incorporated in a phenomenological manner in a model of a two-dimensional arbitrary multi-size spray diffusion flame. Non-unity Lewis numbers are permitted for the fuel vapour and oxidant. A combined analytical/numerical solution of the governing equations is presented and used to investigate how a spray's initial polydispersity and the frequency of oscillatory evaporation influence the combustion field. It is demonstrated that the initial droplet size distribution and the frequency of evaporation of the burning gel droplets can have an acute impact both on the homogeneous diffusion flame shape, height and width and on the thermal field downstream of the flame front. Hot spots of individual (or clusters of) burning droplets can be created and under certain operating conditions can lead to hotter temperatures than experienced in the main homogeneous flame. The intensity of these hotspots, their number and location are sensitive to spray related parameters. In realistic combustion chambers there is a danger inherent in the existence of hotspots in undesirable regions as they can damage the structural integrity. Other computed results demonstrate that, in relation to the spray diffusion flames obtained using an equivalent purely liquid fuel spray, the use of a gel fuel spray can lead, under certain operating conditions, to a reduction in flame height and temperature. The latter effect is critical when considering flame extinction.  相似文献   

14.
Soot formation from combustion devices, which tend to operate at high pressure, is a health and environmental concern, thus investigating the effect of pressure on soot formation is important. While most fundamental studies have utilised the co-flow laminar diffusion flame configuration to study the effect of pressure on soot, there is a lack of investigations into the effect of pressure on the flow field of diffusion flames and the resultant influence on soot formation. A recent work has displayed that recirculation zones can form along the centreline of atmospheric pressure diffusion flames. This present work seeks to investigate whether these zones can form due to higher pressure as well, which has never been explored experimentally or numerically. The CoFlame code, which models co-flow laminar, sooting, diffusion flames, is validated for the prediction of recirculation zones using experimental flow field data for a set of atmospheric pressure flames. The code is subsequently utilised to model ethane-air diffusion flames from 2 to 33 atm. Above 10 atm, recirculation zones are predicted to form. The reason for the formation of the zones is determined to be due to increasing shear between the air and fuel steams, with the air stream having higher velocities in the vicinity of the fuel tube tip than the fuel stream. This increase in shear is shown to be the cause of the recirculation zones formed in previously investigated atmospheric flames as well. Finally, the recirculation zone is determined as a probable cause of the experimentally observed formation of a large mass of soot covering the entire fuel tube exit for an ethane diffusion flame at 36.5 atm. Previously, no adequate explanation for the formation of the large mass of soot existed.  相似文献   

15.
Flame shape is an important observed characteristic of flames that can be used to scale flame properties such as heat release rates and radiation. Flame shape is affected by fuel type, oxygen levels in the oxidiser, inverse burning and gravity. The objective of this study is to understand the effect of high oxygen concentrations, inverse burning, and gravity on the predictions of flame shapes. Flame shapes are obtained from recent analytical models and compared with experimental data for a number of inverse and normal ethane flame configurations with varying oxygen concentrations in the oxidiser and under earth gravity and microgravity conditions. The Roper flame shape model was extended to predict the complete flame shapes of laminar gas jet normal and inverse diffusion flames on round burners. The Spalding model was extended to inverse diffusion flames. The results show that the extended Roper model results in reasonable predictions for all microgravity and earth gravity flames except for enhanced oxygen normal diffusion flames under earth gravity conditions. The results also show trends towards cooler flames in microgravity that are in line with past experimental observations. Some key characteristics of the predicted flame shapes and parameters needed to describe the flame shape using the extended Roper model are discussed.  相似文献   

16.
燃烧法合成碳纳米管的实验方案设计   总被引:2,自引:0,他引:2  
碳纳米管是一种新型的碳材料,其合成方法多种多样。燃烧法是一种新兴的合成方法,燃烧过程提供用于碳纳米管生长的高温环境,同时也提供足够的烃原料。目前,用于合成碳纳米管的原料包括气体燃料和液体燃料,火焰类型主要有层流扩散火焰、逆流扩散火焰和预混火焰等。影响炭纳米管火焰合成的因素主要有气体成分,温度,催化剂,燃氧比和采样条件。我们采用甲烷扩散火焰用于实验研究炭纳米管的合成条件。实验系统包括扩散火焰喷嘴,混和段,质量流量计,取样探针和基板,气源。内径5 mm的喷嘴与内径100 mm的钢筒同轴。实验测得在气量为0.20 SLM时火焰高度为 3.5 cm。涂覆有催化剂的基板水平朝下置于火焰中采样,并将采集的样品进行电镜分析。本文还对燃烧法合成碳纳米管的机理进行了分析。  相似文献   

17.
We have investigated the downward flame spread over a thin solid fuel. Hydrogen, methane, or propane, included in the gaseous product of pyrolysis reaction, is added in the ambient air. The fuel concentration is kept below the lean flammability limit to observe the partially premixing effect. Both experimental and numerical studies have been conducted. Results show that, in partially premixed atmospheres, both blue flame and luminous flame regions are enlarged, and the flame spread rate is increased. Based on the flame index, a so-called triple flame is observed. The heat release rate ahead of the original diffusion flame is increased by adding the fuel, and its profile is moved upstream. Here, we focus on the heat input by adding the fuel in the opposed air, which could be a direct factor to intensify the combustion reaction. The dependence of the flame spread rate on the heat input is almost the same for methane and propane/air mixtures, but larger effect is observed for hydrogen/air mixture. Since the deficient reactant in lean mixture is fuel, the larger effect of hydrogen could be explained based on the Lewis number consideration. That is, the combustion is surely intensified for all cases, but this effect is larger for lean hydrogen/air mixture (Le < 1), because more fuel diffuses toward the lean premixed flame ahead of the original diffusion flame. Resultantly, the pyrolysis reaction is promoted to support the higher flame spread rate.  相似文献   

18.
Forced, time-varying laminar flames help bridge the gap between laminar and turbulent combustion as they reside in an ever-changing flow environment. A distributed-memory parallel computation of a time-dependent sooting ethylene/air coflow diffusion flame, in which a periodic fluctuation (20 Hz) is imposed on the fuel velocity for four different amplitudes of modulation, is presented. The chemical mechanism involves 66 species, and a soot sectional model is employed with 20 soot sections. The governing equations are discretised using finite differences and solved implicitly using a damped modified Newton's method. The solution proceeds in parallel using strip domain decomposition over 40 central processing units (CPUs) until full periodicity is attained. For forcing amplitudes of 30%, 50%, 70% and 90%, a complete cycle of numerical predictions of the time-resolved soot volume fraction is presented. The 50%, 70% and 90% forcing cases display stretching and pinching off of the sooting region into an isolated oval shape. In the 90% forcing case, a well-defined hollow shell-like structure of the soot volume fraction contours occurs, in which the interior of the isolated sooty region has significantly lower soot concentrations than the shell. Preliminary comparisons are made with experimental measurements of the soot volume fraction for the 50% forcing case. The experimental results are qualitatively consistent with the model predictions.  相似文献   

19.
Rich premixed turbulent n-dodecane/air flames at diesel engine conditions are analyzed using direct numerical simulations. The conditions correspond to a parametric variation of the Engine Combustion Network Spray A (pressure 60 atm; oxidizer oxygen level and temperature 21% and 900 K, respectively; fuel temperature 363 K). Three simulations with equivalence ratios of 3, 5, and 7 are performed with a Karlovitz number (Ka, based on flame time) of order 100 to match the estimated Ka of the rich premixed combustion region in Spray A. At these conditions, the reference laminar flames exhibit a complex structure which involves both low-temperature chemistry (LTC) and high-temperature chemistry over a wide range of length scales. In the presence of turbulence, the flame structure is strongly affected in physical space and the reaction zone exhibits a very complex structure in which broken, distributed, and thin regions co-exist, especially for the leanest case. However, the contribution of the LTC pathway is only weakly affected by turbulence. In progress variable space, the mean flame structure, including the chemical source terms, is found to match remarkably well that of the corresponding unity Lewis number laminar flame, particularly for the ?= 3 and 5 cases. This behavior is attributed to the strong turbulent mixing occurring throughout the flames/reaction zones, which suppresses differential diffusion effects. Nevertheless, large conditional fluctuations around the mean chemical source terms are identified. These are found to correlate very well with radical species mass fractions such as OH. In addition, a similar functional dependence is obtained from counterflow laminar flames. As such, it appears from these results that laminar flame models have a potential to be used to represent the thermochemical state of rich premixed turbulent flames under diesel engine conditions.  相似文献   

20.
Micro direct-injection (DI) strategy is often used to extend the operation range of the reactivity controlled compression ignition (RCCI) to high engine load, but its combustion process has not been well understood. In this study, the ignition and flame development of the micro-DI RCCI strategy were investigated on a light-duty optical engine using formaldehyde planar laser-induced fluorescence (PLIF) and high-speed natural flame luminosity imaging techniques. The premixed fuel was iso-octane and an oxygenated fuel of polyoxymethylene dimethyl ethers (PODE) was employed for DI. The fuel-air equivalence ratio of DI was kept at 0.09 and the premixed equivalence ratio was varied from 0 to 1. RCCI strategies with early and late DI timing at –25° and –5° crank angle after top dead center were studied, respectively. Results indicate that the early micro-DI RCCI features a single-stage high-temperature heat release (HTHR). The combustion in the low-reactivity region shows a combination of flame front propagation and auto-ignition. The late micro-DI RCCI presents a two-stage HTHR. The second-stage HTHR is owing to the combustion in the low-reactivity region that is dominated by flame front propagation when the premixed equivalence ratio approaches 1. For both early and late micro-DI RCCI, the intermediate-temperature heat release (ITHR) of iso-octane, indicated by formaldehyde, takes place in the low-reactivity region before the arrival of the flame front. This is quite different from the flame front propagation in spark-ignition (SI) engine that shows no ITHR in the unburned region. The DI fuel mass is a key factor that affects the combustion in the low-reactivity region. If the DI fuel mass is quite low, there is more possibility of flame front propagation; otherwise, sequential auto-ignition dominates. The emergence of the flame front propagation in micro-DI RCCI strategy reduces its combustion rate and peak pressure rise rate.  相似文献   

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