Deconvolution filtering of ground-based LIDAR returns from tropospheric aerosols

A deconvolution filtering model of multiple scattering in ground-based single field of view (SFOV) LIDAR returns is described. It is based on time series deconvolution techniques. The contribution of multiply scattered photons in SFOV LIDAR returns can be numerically modeled by processing LIDAR signals without additional information about aerosol properties and measurement geometry. Deconvolution results are in good agreement with those performed by Monte Carlo calculations, showing that the significance of multiply scattered photons is strongly correlated with aerosol concentration. It is found that, for ground-based LIDAR, the contribution of multiply scattered photons to LIDAR signals is typically below 5% in a clear urban atmosphere, and up to 14% in a very dirty urban atmosphere in Hong Kong during winter seasons. Received: 8 October 2002 / Revised version: 29 January 2003 / Published online: 22 May 2003 RID="*" ID="*"Corresponding author. Fax: +81-298/51-8229, E-mail: gao@proteo.gr.jp RID="**" ID="**"Present address: Preteomics Lab., Amakubo 1-16-1, Tsukuba 305-0005, Japan     

Optical inhomogeneity model for evaporated Y2O3 obtained from physical thickness measurement

A multiparameter fitting with additional parameters for film inhomogeneity based on transmission results is used to get film inhomogeneity information and to compare different models for film structure. For a number of evaporated materials similar results from transmission fitting have been obtained by using a model consisting of two sublayers with a constant difference in refractive indices between them, either with a thin sublayer in the contact with a substrate or with air. As additional information, we obtained the film physical thickness result from step profile measurements for an oxygen-doped Y₂O₃ film on a fused silica and we compared it with the fit results for this coating. The result closest to the profilometry one has been achieved for a model with a thinner sublayer in contact with the substrate. The differences are great enough to assert that Y₂O₃ films on a fused silica possess a higher refractive index in the first stages of growth and then, after some transition, the main material with smaller refractive index grows on it.     

Fisher Information of Wavefunctions： Classical and Quantum

A parametric quantum mechanical wavefunction naturally induces parametric probability distributions by taking absolute square, and we can consider its classical Fisher information. On the other hand, it also induces parametric rank-one projections which may be viewed as density operators, and we can talk about its quantum Fisher information. Among many versions of quantum Fisher information, there are two prominent ones. The first, defined via a quantum score function, was introduced by Helstrom in 1967 and is well known. The second, defined via the square root of the density operator, has its origin in the skew information introduced by Wigner and Yanase in 1963 and remains relatively unnoticed. This study is devoted to investigating the relationships between the classical Fisher information and these two versions of quantum Fisher information for wavefunctions. It is shown that the two versions of quantum Fisher information differ by a factor 2 and that they dominate the classical Fisher information. The non-coincidence of these two versions of quantum Fisher information may be interpreted as a manifestation of quantum discord. We further calculate the difference between the Helstrom quantum Fisher information and the classical Fisher information, and show that it is precisely the instantaneous phase fluctuation of the wavefunctions.     

Promotors,poisons and surfactants: Electronic effects of surface doping on metals

The interaction of adsorbates with metal surfaces is discussed. It is shown that the evanescent charge density produced by occupied sp derived surface states yields a considerable contribution to the Pauli repulsion experienced by adsorbate particles with a closed-shell electronic structure, e.g. rare-gases or molecules such as H₂ or N₂. For rare-gases this results in a reduction of the binding energy in the presence of occupied surface states, for molecules this gives rise to an additional contribution to the dissociation barrier. Suitable surface dopants are able to depopulate surface states and thereby to reduce the dissociation barrier. Such dopants can substantially promote catalytic reactions in which the dissociation from the gas phase or a physisorbed precursor is the rate limiting step. In contrast to closed-shell systems the bonding interaction for metal adsorbates on metal substrates is enhanced by occupied surface states. This leads to an extra diffusion barrier at steps, because the surface state amplitude drops to zero at upper step edges. The additional step-edge barrier, which is a kinetic hindrance for layer-by-layer growth, can be reduced by surface dopants depopulating the corresponding surface state. Such dopants promote layer-by-layer growth and act therefore as surfactants. It is concluded that the effect of promoters in catalysis and of surfactants in metal epitaxy is in part due to the same basic mechanism, namely the depopulation of surface states.     

Multivariate data analysis for depth resolved chemical classification and quantification of sulfur in SNMS

The quantification of elements in quadrupole based SNMS is hampered by superpositions of atomic and cluster signals. Moreover, the conventional SNMS data evaluation employs only atomic signals to determine elemental concentrations, which not allows any chemical specifications of the determined elements. Improvements in the elemental quantification and additional chemical information can be obtained from kinetic energy analysis and the inclusion of molecular signals into mass spectra evaluation. With the help of multivariate data analysis techniques, the combined information is used for the first time for a quantitative and chemically distinctive determination of sulfur. The kinetic energy analysis, used to solve the interference of sulfur with O₂ at masses 32-34 D, turned out to be highly important for the new type of evaluation.     

Prolongation of the fluorescence lifetime of plasma channels in air induced by femtosecond laser pulses

The lifetime of plasma channels induced by femtosecond laser pulses is investigated by detecting the decay time of the fluorescence signals from ions. It is found that the lifetime of the plasma can be prolonged to the order of microseconds when an additional sub-nanosecond laser pulse is injected into the channel. This prolongation is due to the heating and further ionization through the inverse bremsstrahlung absorption of the post-pulse.     

Social behavior of bacteria: from physics to complex organization

I describe how bacteria develop complex colonial patterns by utilizing intricate communication capabilities, such as quorum sensing, chemotactic signaling and exchange of genetic information (plasmids) Bacteria do not store genetically all the information required for generating the patterns for all possible environments. Instead, additional information is cooperatively generated as required for the colonial organization to proceed. Each bacterium is, by itself, a biotic autonomous system with its own internal cellular informatics capabilities (storage, processing and assessments of information). These afford the cell certain plasticity to select its response to biochemical messages it receives, including self-alteration and broadcasting messages to initiate alterations in other bacteria. Hence, new features can collectively emerge during self-organization from the intra-cellular level to the whole colony. Collectively bacteria store information, perform decision make decisions (e.g. to sporulate) and even learn from past experience (e.g. exposure to antibiotics)-features we begin to associate with bacterial social behavior and even rudimentary intelligence. I also take Schrdinger’s’ “feeding on negative entropy” criteria further and propose that, in addition organisms have to extract latent information embedded in the environment. By latent information we refer to the non-arbitrary spatio-temporal patterns of regularities and variations that characterize the environmental dynamics. In other words, bacteria must be able to sense the environment and perform internal information processing for thriving on latent information embedded in the complexity of their environment. I then propose that by acting together, bacteria can perform this most elementary cognitive function more efficiently as can be illustrated by their cooperative behavior.     

The distribution of counterions around synthetic rod-like polyelectrolytes in solution

An investigation of the radial distribution of the counterions of a synthetic rodlike polyelectrolyte in aqueous solution is presented. The cationic polyelectrolyte used here has a poly(p-phenylene) backbone. For typical molecular weights the macroion comprises approximately one persistence length (ca. 20 nm) and effects of finite stiffness may be disregarded. Each repeating unit bears four charges which leads to a charge parameter of ξ = 6.65. The distribution of the iodide counterions around this highly charged macroion is studied by small-angle X-ray scattering (SAXS) in dilute aqueous solution. These investigations are supplemented by measurements using anomalous small-angle X-ray scattering (ASAXS) that furnishes additional information about the contrast of the macroion. Data taken at high scattering angles give indication for contributions caused by the longitudinal fluctuations of the counterions. After correction for this effect the experimental results are compared to intensities calculated by use of the Poisson-Boltzmann (PB)-cell model. It is found that the PB-cell model describes the corrected data at intermediate and high scattering angles. Deviations at low scattering angle are attributed to the mutual interaction of the rod-like polyelectrolyte that can be described in terms of an effective structure factor. Data taken at lowest scattering angles point to a weak attraction between the rod-like macroions. Received: 27 July 2001 and Received in final form 27 March 2002     

Voltage-controlled storage and retrieval of an infrared-light pulse in a quantum-dot molecule

Dynamic storage and retrieval of a weak infrared (IR)-light pulse are investigated theoretically with feasible parameters in an asymmetric double quantum dot system, a quantum dot molecule (QDM). It is shown that, with a voltage-controlled tunneling, we are able to store and retrieve the IR signal pulse in this three-subband QDM medium by slowly switching off and on the tunneling. The scheme proposed may open up the electrical controllability of quantum optical information storage and retrieval, which is expected to be useful in quantum information science in an asymmetric double quantum dot controlled by voltage.     

用多量子滤波提高分辨率

本文建议使用多量子滤波方法来提高一维谱的分辨率,从而可从堆集在一起的谱中获得耦合的信息,并从理论上证明了此方法的原理主要是由于反相磁化信号的测量而不是正常磁化信号,它与弛豫的作用无关。     

Information-theoretic limits of control

Fundamental limits on the controllability of physical systems are discussed in the light of information theory. It is shown that the second law of thermodynamics, when generalized to include information, sets absolute limits to the minimum amount of dissipation required by open-loop control. In addition, an information-theoretic analysis of control systems shows feedback control to be a zero sum game: each bit of information gathered from a dynamical system by a control device can serve to decrease the entropy of that system by at most one bit additional to the reduction of entropy attainable without such information. Consequences for the control of discrete state systems and chaotic maps are discussed.     

Magnetic excitations in charge ordered a' - {N_a}{V_2}{O_5}

An investigation of the spin excitation spectrum of charge ordered (CO) NaV₂O₅ is presented. We discuss several different exchange models which may be relevant for this compound, namely in-line and zig-zag chain models with weak as well as strong inter-chain coupling and also a ladder model and a CO/MV (mixed valent) model. We put special emphasis on the importance of large additional exchange across the diagonals of V-ladders and the presence of exchange anisotropies on the excitation spectrum. It is shown that the observed splitting of transverse dispersion branches may both be interpreted as anisotropy effect as well as acoustic-optic mode splitting in the weakly coupled chain models. In addition we calculate the field dependence of excitation modes in these models. Furthermore we show that for strong inter-chain coupling, as suggested by recent LDA + U results, an additional high energy optical excitation appears and the spin gap is determined by anisotropies. The most promising CO/MV model predicts a spin wave dispersion perpendicular to the chains which agrees very well with recent results obtained by inelastic neutron scattering. Received 30 April 1999 and Received in final form 5 October 1999     

Interband thermoluminescence of semiconductors and semiconductor nanocrystals in the near-infrared

The thermally excited luminescence of undoped semiconductors and semiconductor nanocrystals near the band gap is explored by a simple and unconventional experimental technique. Luminescence spectra are obtained at ambient conditions after slightly heating the samples to approximately 100 °C without using any additional electronic or optical means of excitation. In our investigations, bulk GaAs, bulk InP and semiconductor doped glasses are studied. We show that absorption properties and band gap positions obtained directly from emission spectra not only correspond well to those obtained from transmission measurements, but also yield additional information about the role of defects giving rise to emission from within the band gap.     

Quantum Stackelberg Duopoly of Continuous Distributed Asymmetric Information

The minimal quantization structure is employed to investigate the quantum version of the Stackelberg duopoly with continuous distributed asymmetric information, i.e a continuous distribution while the second mover has the first mover has incomplete information that obeys complete information. It is found that the effects of the positive quantum entanglement on the outcomes exhibit many interesting features due to the information asymmetry. Moreover, although the first-mover advantage is counteracted by the information asymmetry, the positive quantum entanglement still enhances the first-mover advantage and improves the first-mover tolerance of the information asymmetry beyond the classical limit.     

Waiting times and noise in single particle transport

The waiting time distribution w(τ), i.e. the probability for a delay τ between two subsequent transition (‘jumps’) of particles, is a statistical tool in (quantum) transport. Using generalized Master equations for systems coupled to external particle reservoirs, one can establish relations between w(τ) and other statistical transport quantities such as the noise spectrum and the Full Counting Statistics. It turns out that w(τ) usually contains additional information on system parameters and properties such as quantum coherence, the number of internal states, or the entropy of the current channels that participate in transport.     

First-principles density-functional calculations on the field emission properties of BN nanocones

The first-principles density-functional theory is used to study the geometrical structures and field emission properties of different boron nitride nanocones with 240 disclination. It is found that the nanocones can be stable under applied electric field and the emission current is sensitively dependent on the tips of nanocones. The nanocones with homonuclear bonds at the tip can introduce additional energy states near Fermi level, which can reduce the ionization potential and increase the emission current of these boron nitride nanocones. This investigation indicates that the boron nitride nanocone can be a promising candidate as a field emission electron source.