Structural and optical properties of laser irradiated nano structured cadmium oxide thin film synthesized by sol-gel spin coating method

Cadmium oxide CdO nanostructured thin films are synthesized using sol-gel spin coating method. The prepared samples of CdO thin films are irradiated with 10 mJ laser from pulsed Q-Switched Nd:YAG laser at 1064 and 532 nm wavelength. The samples were exposed to 45 pulses of 7 ns pulse duration. Morphology and structural analysis were carried out with scanning electron microscope (SEM) micrographs and X-ray diffraction (XRD) patterns. Optical investigations were obtained with spectrometer and fluorospectrometer from Shimadzu. SEM micrographs confirm the nanostructure of the CdO film and indicate agglomeration of nanoparticles with laser irradiation. XRD patterns show decrease in the intensity of orientation peaks after laser irradiation. Variation in band gap energy, absorption peaks, and photoluminescence spectra with laser irradiation are observed.     

高峰值功率KDP晶体四倍频266nm紫外激光器

报道了一种灯泵浦结构的Nd:YAG晶体电光调Q高峰值功率266nm紫外激光器。结合磷酸二氢钾(KDP)晶体性质,基于倍频理论,分析了考虑走离效应情况下存在相位失配量时KDP晶体长度对转换效率的影响。该激光器采用紧凑的平平腔结构,灯泵浦Nd:YAG晶体电光调Q 1064nm激光作为基频光,腔外采用Ⅱ类匹配磷酸钛氧钾(KTP)和Ⅰ类匹配KDP分别作为二倍频和四倍频晶体。利用能量计、示波器等仪器进行测量,激光器重复频率1Hz时,获得脉宽6.0ns,单脉冲能量35mJ的266nm紫外激光输出,峰值功率高达5.83 MW;当重复频率10Hz时,获得单脉冲能量28.9mJ的266nm紫外激光。532~266nm转换效率最高可达31.9%。利用该高峰值功率、窄脉宽266nm紫外激光器,能够实现激光打标、激光雕刻。     

XRD and SEM analysis of a laser-irradiated cadmium

A pulsed Nd:YAG laser (10 mJ, 12 ns, 1064 nm) was employed to study the IR irradiation effects on metallic samples of cadmium. The laser was irradiated for 100, 200, and 300 shots under a vacuum ～10^?3 Torr. The results were investigated using a Hi Tech S3000H Scanning Electron Microscope (SEM) and X’pert Pro PANalytical X-ray Diffractometer (XRD). The micrographs obtained from SEM reveal that the surface morphological changes have occurred in the form of a crater. The forward expansion of plasma into an ambient gas coupled with the recondensation of the target surface results in the formation of debris. Large temperature gradients produce variations in the thermal resistance that leads to the distributed shape of the heat-affected zone. The hydrodynamic effects are apparent with a liquid flow to form the recast material around the periphery of the laser focal area. The turbulent resolidified material is formed when surface asperities are accelerated away from the liquid surface during each laser pulse due to melting followed by the thermal expansion of the liquid. The positive feed back of the repeated pulses resulted in the form of ripples. Grains appear on the surface as evidence of heterogeneous nucleation. The confirmation of the formation of these structures has been done by X-ray Diffractometer (XRD).     

Laser-diode-pumped Nd:YVO<Subscript>4</Subscript>/Nd:YAG MOPA burst-mode laser

We report a high-repetition-rate, high-peak-power laser diode (LD) pumped burst-mode 1064 nm laser from a Nd:YVO₄/Nd:YAG master oscillator power amplifier. 10–100 kHz pulse burst in a duration up to 2 ms is achieved in LD end-pumped Nd:YVO₄ acousto-optically Q-switched laser. After amplification with LD side-pumped Nd:YAG rod amplifiers, the single pulse energy reaches 73 mJ in 10 kHz pulse burst laser with a peak power of 7.8 MW.     

Surface morphologic and structural analysis of IR irradiated silver

The microstructural morphological changes in laser irradiated targets are investigated. Nd:YAG laser (1064 nm, ∼12 ns nominal, 1.1 MW) is used to irradiate 4 N pure (99.99%) fine polished and annealed silver samples in ambient air and under vacuum ∼10⁻⁶ Torr. The laser spot size and power density at tight focus are 12 μm and 3×10¹¹ W/cm², respectively. SEM micrographs and X-ray diffractograms of the exposed and unexposed targets reveal the surface texture and structural changes, respectively. Amongst the ablation mechanisms involved, exfoliation and hydrodynamic sputtering are found to be dominant. Surface modifications appear in the form of craters and ripples formation. Heat is conducted non-uniformly through narrow channels at the surface. Thermal stresses induced by the laser do not disturb inter planar distance of the target. On the other hand irradiation causes significant variations in grain size and diffracted X-rays intensities.     

二极管激光侧面泵浦腔内倍频Nd：YAG板条激光器研究

用准连续６０Ｗ的二极管激光列阵侧面泵浦“之”字形Ｎｄ：ＹＡＧ板条激光器，当泵浦功率为４５Ｗ，脉宽为４００μｓ时，得到３．５ｍＪ的激光输出。用ＫＤ＊Ｐ电光开关调Ｑ，得到１８ｎｓ（ＦＷＨＭ）、２ｍＪ的脉冲激光输出，用ＫＴＰ晶体作腔内倍频，得到１５ｎｓ、０．８５ｍＪ的二次谐波激光输出。在腔内无调Ｑ元件且腔长小于５ｃｍ时，于近阈值处得到单频绿光输出，而当泵浦功率稍大，腔内有数个纵模振荡时，观察到激光的反相态，并用数值模拟的结果对此作了解释。     

High-energy single longitudinal mode 1 ns all-solid-state 266 nm lasers

A single longitudinal mode (SLM) short pulse high energy all-solid-state ultraviolet laser is demonstrated in this paper. Through the use of a master oscillator power amplifier (MOPA) architecture, we have been able to provide high-energy outputs with the combination of short pulses, good beam quality and SLM typically produced by a 1064 nm Nd:YAG laser. The passively Q-switched SLM Nd:YAG laser in a twisted-mode cavity is operated as the seed source. After the seed is amplified by a double-pass pre-amplifier and a single-pass main-amplifier, the 100 μJ, 1064 nm, ∼1 ns seeding pulse was amplified up to 400 mJ energy in the total pulse train. Using a KTP crystal for second-harmonic generation and a CLBO for fourth-harmonic generation, we successfully obtained a short pulse, high energy ultraviolet laser of 266 nm, with the output energy of 108 mJ, pulse width 1 ns and M²<5. PACS 42.65.Ky; 42.72.Bj; 42.60.Da     

1.57 MW peak power pulses generated by a diode-pumped Q-switched Nd:LuAG ceramic laser

The pulse characteristics of a laser diode dual-end-pumped electro-optic Q-switched Nd:LuAG ceramic laser at various repetition rates are presented. The largest output pulse energy of 11 mJ is realized at the repetition rate of 100 Hz with pump energy of 84.3 mJ, and the slope efficiency in respect to pump pulse energy is 18.6%. The single pulse peak power reaches up to 1.57 MW. Using Nd:LuAG ceramic as the amplification medium seeded by an Nd:YAG laser of 5.2 mJ, a 10.3 mJ amplified pulse is obtained with pump pulse energy of 42.8 mJ, corresponding to an extraction efficiency of 11.9%.     

Quantitative studies of copper plasma using laser induced breakdown spectroscopy

In the present work, we present the spatial evolution of the copper plasma produced by the fundamental harmonic (1064 nm) and second harmonic (532 nm) of a Q-switched Nd:YAG laser. The experimentally observed line profiles of neutral copper have been used to extract the electron temperature using the Boltzmann plot method, whereas, the electron number density has been determined from the Stark broadening. Besides we have studied the variation of electron temperature and electron number density as a function of laser energy at atmospheric pressure. The Cu I lines at 333.78, 406.26, 465.11 and 515.32 nm are used for the determination of electron temperature. The relative uncertainty in the determination of electron temperature is ≈10%. The electron temperature calculated for the fundamental harmonic (1064 nm) of Nd:YAG laser is 10500–15600 K, and that for the second harmonic (532 nm) of Nd:YAG laser is 11500–14700 K at a Q Switch delay of 40 μs. The electron temperature has also been calculated as a function of laser energy from the target surface for both modes of the laser. We have also studied the spatial behavior of the electron number density in the plume. The electron number densities close to the target surface (0.05 mm), in the case of fundamental harmonic (1064 nm) of Nd:YAG laser having pulse energy 135 mJ and second harmonic (532 nm) of Nd:YAG laser with pulse energy 80 mJ are 2.50×10¹⁶ and 2.60×10¹⁶ cm⁻³, respectively.     

1064nm纳秒激光脉冲激发的外腔式PbWO4拉曼激光器

研究了外腔式PbWO4拉曼激光器在纳秒脉冲抽运下的输出特性。利用主动调Q的Nd:YAG激光器产生的脉冲宽度为31.4ns,最大输出能量为200mJ的1064nm激光作为抽运源。拉曼激光谐振腔采用的是平凹腔设计。测量了输出的拉曼光脉宽与抽运能量的关系,分析了输出的拉曼光脉冲波形图和光谱图,测量了输出的拉曼光脉冲能量与抽运能量的关系,计算了转换效率与抽运能量的关系。当注入抽运光能量达到42mJ时,得到了一阶斯托克斯光脉冲的最大能量和转换效率分别为10mJ和24%,获得外腔式PbWO4拉曼激光器的一阶斯托克斯光脉冲波长为1177.6nm,典型的一阶斯托克斯光脉冲脉宽为20ns。     

Passively Q-switched,high peak power Nd:YAG laser pumped by QCW diode laser

A Nd:YAG laser passively Q-switched by a Cr:YAG showed a high single pulse energy of 53.0 mJ and 5.1 MW peak power. The laser was pumped by quasi-continuous-wave diode bars from single side. The Q-switched pulse had optical-to-optical efficiency of 12% and average temporal duration of 10.4 ns when Cr:YAG with initial transmission of 9.0% was used. Intense pumping as well as very low initial transmission of the saturable absorber gave very high peak power.     

LD侧面泵浦电光调Q532nm脉冲激光器

 为了实现高可靠、窄脉宽、高峰值功率激光输出,采用侧面泵浦技术和电光调Q技术,设计出一种激光二极管侧面泵浦电光调Q全固态绿光激光器。采用结构简单、紧凑的平-平腔设计,其端镜和输出镜均为平面镜,获得较稳定的侧面泵浦Nd∶YAG腔外倍频KTP脉冲绿光激光输出。当泵浦电流为120A,重复频率为600Hz时,获得脉冲绿光的最高输出平均功率为3.62W,1064nm到532nm的转换效率为15.3%,其脉宽为21ns,峰值功率为300kW, 单脉冲能量为6.01mJ。实验结果表明：该激光器稳定性可靠,输出激光脉宽较窄、峰值功率高。     

Passively Q-switched Nd3+:YAG laser with corner cube

A passively Q-switched Nd3+:YAG laser with corner cube is theoretically and experimentally studied. We analyze the polarization variation in cavity and simulate the peak power, pulse energy and pulse width changed with the rotation angle of corner cube numerically. An experiment is made to verify the theoretical results. With rotating the angle of corner cube about the axis the variation range of peak power is 1.77 MW (from 10.36 to 8.59 MW), and that of pulse energy is 14.9 mJ (from 159.5 to 174.4 mJ), the fluctuation of pulse width is 2.95 ns. The experimental results agree with the theoretical analysis to the extent of variation rules. The most dynamic to static energy ratio of 62.5% is achieved.     

二极管侧泵浦单横模1kHz电光Q开关激光器

 本文介绍了二极管侧泵浦Nd:YAG板条1kHz重复频率Q开关激光器的研制,实验获得最大单脉冲能量0.712mJ,脉宽小于10ns的输出。对Nd:YAG板条进行了三种冷却方式的比较实验,实验证明DPL在高重复频率工作时,激光介质的热效应是影响高重复频率工作的激光器效率的重要因素。     

6.1 MW, 10 kHz Side-Pumped Burst-Mode Nd:YAG Laser

We present a compact high-peak-power, high-repetition-rate burst-mode laser from a master-oscillator power amplifier (MOPA) at 1064 nm for laser-based measurement applications. The oscillator is an 808 nm pulsed laser diode side-pumped acousto-optical (A-O) Q-switched Nd:YAG laser at repetition rates ranging from 10–100 kHz, producing a pulse train with a pulse number of 2–25. The maximum output energy of the oscillator is 15.6 mJ at 10 kHz, whereas it is 1.7 mJ at 100 kHz. After twostage amplifiers, a single-pulse energy of 85.2 mJ with a pulse-width of 14.5 ns is achieved at 10 kHz, which produces a peak power of 6.1 MW. At 100 kHz, the total burst energy reaches 220 mJ with a single-pulse energy of 8.8 mJ in the pulse burst laser system.     

Vacuum-cored hollow waveguide for transmission of high-energy, nanosecond Nd:YAG laser pulses and its application to biological tissue ablation

A vacuum-cored hollow waveguide has been found to transmit 1064-nm, Q-switched Nd:YAG laser pulses. With this scheme, laser-induced air breakdown was completely suppressed, and the laser-induced damage threshold of the waveguide's inner coating was significantly increased. With a 1-m-long, 1-mm inner-diameter, cyclic olefin polymer-coated silver hollow waveguide, the maximum transmitted laser energy was as great as 158 mJ/pulse (20.1 J/cm(2)), at a repetition rate of 10 Hz in a 90 degrees -bent waveguide condition. The corresponding transmitted peak laser power was 17.6 MW. With the transmitted laser pulses, deep ablation of myocardium tissues was demonstrated in vitro.     

溶胶-凝胶光学薄膜的激光损伤研究

 采用溶胶-凝胶工艺制备了SiO₂与ZrO₂单层介质膜，用输出波长1.06μm，脉宽15ns的电光调Q激光系统产生的强激光进行辐照实验。观察了光学薄膜经强激光辐照后的损伤情况，讨论了溶胶 凝胶光学薄膜在强激光照射下的损伤机理，提出了溶剂替换、紫外光处理、添加有机粘接剂等提高溶胶 凝胶光学薄膜激光损伤阈值的方法。     

Structural changes in tin oxide thin film with laser exposure

The effects of laser irradiation on the surface, structure and optical properties of SnO thin films deposited on glass substrates using electron beam evaporation, are investigated. The thin film samples are irradiated using fundamental beam at 1064 nm from Q-switched Nd:YAG pulsed laser with different power densities. Structural morphology of the film is investigated using XRD patterns and AFM image. Both XRD pattern and AFM image show increase in grain size of the film with increasing laser power density. Other optical phenomena, photoluminescence emission, transmission, refractive index determination and optical band gaps calculations are also carried out at various laser power densities. Results from all these investigations reveal expansion in grain size of the crystalline SnO thin film with increasing laser power density.     

激光二极管列阵侧面泵浦Nd：YLF激光器

报道准连续６０Ｗ激光二极管列阵侧面泵浦Ｎｄ：ＹＬＦ固体激光器的研究结果，当器件的动转重复频率为３０Ｈｚ时，得到４．４ｍＪ的１．０４７μｍ激光输出，光－光转换效率达到１８．３％，斜率效率达２４．４％。声光和电光调Ｑ，得到能量为２．２ｍＪ，脉宽分别为５０ｎｓ和３０ｎｓ的脉冲输出。     

ZrO2/ SiO2多层膜的化学法制备研究

 分别以ZrOCl₂·8H₂O 和正硅酸乙酯为原料,采用溶胶-凝胶工艺制备了性能稳定的ZrO₂和SiO₂溶胶。用旋转镀膜法分别在K9玻璃和单晶硅片上制备了ZrO₂/ SiO₂多层膜。采用溶剂替换和紫外光处理等手段,有效地解决了ZrO₂/SiO₂多层膜中膜层开裂和膜间渗透等问题。应用扫描电子显微镜观测了薄膜的表面和剖面微观形貌,并用椭偏仪测得薄膜的厚度和折射率,研究了薄膜厚度、折射率与热处理温度、紫外光处理时间的关系,对所获得薄膜的紫外-可见、红外光谱进行了分析。用输出波长1064nm ,脉宽15ns 的电光调Q光系统产生的强激光进行了单层膜的辐照实验,结果发现溶剂替换后激光损伤阈值有所提高。