共查询到20条相似文献,搜索用时 640 毫秒
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X-射线荧光光谱分析技术的发展 总被引:4,自引:0,他引:4
归纳了X-射线荧光光谱分析技术发展的进程。从现代控制技术的改善、仪器检测性能的提高、元素检测范围的扩大等8方面阐述了波长色散X-射线荧光光谱技术的进展,还就能量色散X-射线荧光光谱仪的X射线管和探测器技术的快速发展及近10年来我国在X-射线荧光光谱分析方法方面的论文发表情况进行了总结,对近年来X-射线荧光光谱仪的发展趋势———手持式、偏振、微束分析等进行了评述,并对其技术的发展方向进行了展望。 相似文献
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X射线荧光光光谱分析 总被引:3,自引:0,他引:3
评述了我国在2007~2008年X射线荧光光谱,包括质子激发的X射线光谱的发展和应用,内容包括仪器、软件、仪器改造、仪器维护和维修、基础研究和分析方法研究及其应用. 相似文献
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X射线荧光光谱法在稀土元素分析中的应用 总被引:6,自引:0,他引:6
本文研究了X射线荧光光谱在混合稀土氧化物和高纯稀土氧化物分析中的应用,并探讨了在常量分析中影响分析准确度和精密度的主要因素;样品及标样制备,基体效应校正方法在痕量分析中降低检测限的方法,选择最佳测量条件,降低背景,与分离富集手段相结合,取得满意的结果。 相似文献
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M. Bos 《Analytica chimica acta》2005,545(1):92-98
Existing theory was used to develop a fundamental parameter (FP) computer program for quantitative X-ray fluorescence (XRF) spectrometry in which scattering interactions are taken into account. The program is suited for polychromatic radiation and composite samples and is used to estimate the errors that result from neglecting the scattering contributions in the analysis of samples in a low Z matrix when the spectrometer is calibrated either on pure elements or on standards similar to the samples. 相似文献
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The energy-dispersive X-ray fluorescence spectrometer for analysis of conventional and micro-samples using pinhole collimators of various sizes is developed. The measurements can be performed in the air or, in order to decrease the absorption of long-wavelength radiation of low-Z elements, in helium atmosphere. The sample is excited by the air-cooled Rh target X-ray tube of ca. 100 μm nominal focal spot size and maximum power 75 W. The X-ray spectra of the samples are collected by thermoelectrically cooled Si-PIN detector. The tungsten pinhole collimators of the size holes from 50 to 2000 μm are placed between primary filter and analyzed sample to reduce size of analyzed area. The sample can be moved using the X–Y stage. The position of the sample is monitored by CCD camera and two laser pointers. The beam spot sizes for various collimators are evaluated by the thin-wire and knife-edge methods. Beside the beam spot sizes, the loss of radiation intensity and the changes of spectral distribution of the incident radiation caused by applying various collimators are also investigated. The sample-surface-down geometry in the designed spectrometer allows for a simple analysis of various samples: solutions, loose powders, solid samples of conventional size and micro-samples. 相似文献
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Marijan Nečemer Peter Kump Janez Ščančar Radojko Jaćimović Jurij Simčič Primož Pelicon Miloš Budnar Zvonka Jeran Paula Pongrac Marjana Regvar Katarina Vogel-Mikuš 《Spectrochimica Acta Part B: Atomic Spectroscopy》2008
Phytoremediation is an emerging technology that employs the use of higher plants for the clean-up of contaminated environments. Progress in the field is however handicapped by limited knowledge of the biological processes involved in plant metal uptake, translocation, tolerance and plant–microbe–soil interactions; therefore a better understanding of the basic biological mechanisms involved in plant/microbe/soil/contaminant interactions would allow further optimization of phytoremediation technologies. In view of the needs of global environmental protection, it is important that in phytoremediation and plant biology studies the analytical procedures for elemental determination in plant tissues and soil should be fast and cheap, with simple sample preparation, and of adequate accuracy and reproducibility. The aim of this study was therefore to present the main characteristics, sample preparation protocols and applications of X-ray fluorescence-based analytical techniques (energy dispersive X-ray fluorescence spectrometry—EDXRF, total reflection X-ray fluorescence spectrometry—TXRF and micro-proton induced X-ray emission—micro-PIXE). Element concentrations in plant leaves from metal polluted and non-polluted sites, as well as standard reference materials, were analyzed by the mentioned techniques, and additionally by instrumental neutron activation analysis (INAA) and atomic absorption spectrometry (AAS). The results were compared and critically evaluated in order to assess the performance and capability of X-ray fluorescence-based techniques in phytoremediation and plant biology studies. It is the EDXRF, which is recommended as suitable to be used in the analyses of a large number of samples, because it is multi-elemental, requires only simple preparation of sample material, and it is analytically comparable to the most frequently used instrumental chemical techniques. The TXRF is compatible to FAAS in sample preparation, but relative to AAS it is fast, sensitive and multi-elemental. The micro-PIXE technique requires rather expensive instrumentation, but offers multi-elemental analysis on the tissue and cellular level. 相似文献
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F. Rizzo G.P. Cirrone G. Cuttone A. Esposito S. Garraffo G. Pappalardo L. Pappalardo F.P. Romano S. Russo 《Microchemical Journal》2011,97(2):286-290
In the last years a non-destructive protocol of analysis, based on the combined use of the portable PIXE-alpha (particles induced X-ray emission), the XRF (X-ray florescence) spectrometers and of the new DPAA (deep protons activation analysis) method, was developed at the LANDIS laboratory of the INFN-LNS and IBAM-CNR, in order to characterise late Roman nummi dating from 294 onwards. The main aim of the investigation was the determination of the silver content of the coins produced in different periods of time and the study of the technique used for their manufacturing.The present paper discusses the results obtained from the analysis of 15 coins dated back to 308–311 A.D. produced at Carthago during the domination of the usurper L. Domitius Alexander. The obtained analytical data allowed to make some considerations about the minting of silvered bronze coins during this historical period. 相似文献
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Christian Mans Stephanie Hanning Christoph Simons Anne Wegner Anton Janβen Martin Kreyenschmidt 《Spectrochimica Acta Part B: Atomic Spectroscopy》2007
For the adoption of the EU directive “Restriction on use of certain Hazardous Substances” and “Waste Electrical and Electronic Equipment” using X-ray fluorescence analysis suitable standard materials are required. 相似文献
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X射线荧光光谱法测定洗衣粉中硅、铝、磷、硫的初步研究 总被引:2,自引:0,他引:2
用X射线荧光光谱法测定了洗衣粉中硅,铝,磷,硫的含量,并与化学法进行了比较。结果表明,本法样品处理简单,分析速度快,可用于快速确定洗衣粉的化学成分。 相似文献
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Benjamin E. Naes Sayuri Umpierrez Scott Ryland Cleon Barnett Jose R. Almirall 《Spectrochimica Acta Part B: Atomic Spectroscopy》2008
Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), micro X-ray fluorescence spectroscopy (μXRF), and laser induced breakdown spectroscopy (LIBS) are compared in terms of discrimination power for a glass sample set consisting of 41 fragments. Excellent discrimination results (> 99% discrimination) were obtained for each of the methods. In addition, all three analytical methods produced very similar discrimination results in terms of the number of pairs found to be indistinguishable. The small number of indistinguishable pairs that were identified all originated from the same vehicle. The results also show a strong correlation between the data generated from the use of µXRF and LA-ICP-MS, when comparing µXRF strontium intensities to LA-ICP-MS strontium concentrations. A 266 nm laser was utilized for all LIBS analyses, which provided excellent precision (< 10% RSD for all elements and < 10% RSD for all ratios, N = 5). The paper also presents a thorough data analysis review for forensic glass examinations by LIBS and suggests several element ratios that provide accurate discrimination results related to the LIBS system used for this study. Different combinations of 10 ratios were used for discrimination, all of which assisted with eliminating Type I errors (false exclusions) and reducing Type II errors (false inclusions). The results demonstrate that the LIBS experimental setup described, when combined with a comprehensive data analysis protocol, provides comparable discrimination when compared to LA-ICP-MS and μXRF for the application of forensic glass examinations. Given the many advantages that LIBS offers, most notably reduced complexity and reduced cost of the instrumentation, LIBS is a viable alternative to LA-ICP-MS and μXRF for use in the forensic laboratory. 相似文献