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1.
Liang Liao Yi Pang Liming Ding Frank E. Karasz 《Journal of polymer science. Part A, Polymer chemistry》2003,41(20):3149-3158
A soluble cyano‐substituted poly[(1,3‐phenylene vinylene)‐alt‐(1,4‐phenylene vinylene)] derivative ( 9 ) was synthesized and characterized. Comparison between 9 and its model compound ( 10 ) showed that the chromophore in 9 remained to be well defined as a result of a π‐conjugation interruption at adjacent m‐phenylene units. The attachment of a cyano substituent only at the β position of the vinylene allowed the maximum electronic impact of the cyano group on the optical properties of the poly(p‐phenylene vinylene) material. At a low temperature (?108 or ?198 °C), the vibronic structures of 9 and 10 were partially resolved. The absorption and emission spectra of a film of 9 were less temperature‐dependent than those of a film of 10 , indicating that the former had a lower tendency to aggregate. A light‐emitting diode (LED) based on 9 emitted yellow light (λmax ≈ 578 nm) with an external quantum efficiency of 0.03%. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3149–3158, 2003 相似文献
2.
Liang Liao Liming Ding Frank E. Karasz Yi Pang 《Journal of polymer science. Part A, Polymer chemistry》2004,42(2):303-316
Poly[(2‐alkyloxy‐5‐methyl‐1,3‐phenylenevinylene)‐alt‐(1,3‐phenylenevinylene)]s ( 8 ) and poly[(2‐alkyloxy‐5‐methyl‐1,3‐phenylenevinylene)‐alt‐(1,4‐phenylenevinylene)]s ( 10 ) were synthesized by the Wittig reaction to provide materials containing 45–62% cis‐vinylene bonds. The optical characteristics of 8 and 10 were compared with those of their respective isomers, 3 and 4 , the cis‐vinylene contents of which were significantly lower (9–16%). Although a greater fraction of cis‐CH?CH linkages caused the absorption maximum (λmax) of 8 and 10 to be slightly blueshifted (by ~3–6 nm) from that of 3 and 4 , the impact of the vinylene bond geometry appeared to be negligible on their fluorescence spectra. The fluorescence quantum efficiencies of 8 and 10 were estimated to be approximately 0.25 and 0.72, respectively. Both 8 (λmax ≈ 445 or 462 nm) and 10 (λmax ≈ 480 or 506 nm) were electroluminescent, showing effective color tuning by the controlled insertion of m‐phenylene moieties. The external electroluminescence quantum efficiencies were determined to be 4.26 × 10?3% for 8 and 0.63% for 10 . The cis/trans‐vinylene bond ratio had a great impact on the electroluminescence device performance of 8 but a much smaller impact on the performance of 10 . © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 303–316, 2004 相似文献
3.
Panayiotis Karastatiris John A. Mikroyannidis Ioakim K. Spiliopoulos Mihalis Fakis Peter Persephonis 《Journal of polymer science. Part A, Polymer chemistry》2004,42(9):2214-2224
Two new poly(phenylene vinylene)s containing m‐terphenyl or 2,6‐diphenylpyridine kinked units along the main chain were synthesized and were used as luminescent and laser materials. They were prepared from Heck coupling of 2,5‐didodecyloxy‐1,4‐divinylbenzene with 4,4″‐dibromo‐3′‐phenyl‐m‐terphenyl or 2,6‐di(4‐bromophenyl)‐4‐phenylpyridine. The kinked units along the main chain caused a partial interruption of the conjugation leading to emission at a shorter wavelength as compared with poly(p‐phenylene vinylene). The polymers presented blue‐green emission in solution and green‐yellow emission in the solid state with photoluminescence maxima at 465–497 and 546–550 nm, respectively. Polymer containing 2,6‐diphenylpyridine segments emitted at a longer wavelength than that containing m‐terphenyl and displayed higher quantum yields in solution (0.61 and 0.40, respectively). The influence of the solvent and polymer concentration on the photoluminescence characteristics was investigated. The photoluminescence properties of protonated polymer containing 2,6‐diphenylpyridine segments were investigated both in solution and in film. Amplified spontaneous emission and tunable laser action were also obtained from the two polymers. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2214–2224, 2004 相似文献
4.
Yun‐Hi Kim Sang‐Yun Jung Sung Ouk Jung Moon‐Hak Park Soon‐Ki Kwon 《Journal of polymer science. Part A, Polymer chemistry》2006,44(16):4923-4931
The new poly(arylene vinylene) derivatives, which are composed of biphenylene vinylene phenylene vinylene, biphenylene vinylene m‐phenylene vinylene, terphenylene vinylene phenylene vinylene, and terphenylene vinylene m‐phenylene vinylene as backbone and bulky fluorene pendants at each vinyl bridge, were designed, synthesized, and characterized. The obtained polymers showed weight‐average molecular weights of 11,100–39,800 with polydispersity indexes ranging from 1.5 to 2.1. The resulting polymers were amorphous with high thermal stability and readily soluble in common organic solvents. The obtained polymers showed blue emission (λmax = 456–475 nm) in PL spectra, and polymer 4 containing terphenylene vinylene m‐phenylene vinylene showed the most blue shifted blue emission (λmax = 456 nm). The double layer light‐emitting diode devices fabricated by using obtained polymers as emitter emitted bright blue light. The device showed turn on voltage around 6.5 V and brightness of 70–250 cd/m2. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4923–4931, 2006 相似文献
5.
Yoon Soo Han Sang Dae Kim Lee Soon Park Dong Uk Kim Younghwan Kwon 《Journal of polymer science. Part A, Polymer chemistry》2003,41(16):2502-2511
Four different types of conjugated copolymers, consisting of alternating structures of phenothiazinylene vinylene and phenylene vinylene derivatives such as phenylene vinylene, 1,1′‐biphenyl‐4,4′‐ylene vinylene, 2‐methoxy‐5‐(2‐ethylhexyloxy)‐1,4‐phenylene vinylene, and 9,10‐anthrylene vinylene, were prepared by Horner–Emmons condensation between appropriate diphosphonates and dialdehydes. Single‐layer and double‐layer light‐emitting diodes were fabricated with the synthesized conjugated polymers, and their electroluminescent properties were investigated. Poly(N‐2‐ethylhexyl‐3,6‐phenothiazinylene vinylene‐alt‐9,10‐anthrylene vinylene), containing phenothiazinylene vinylene and anthrylene vinylene as repeat units, emitted a reddish‐orange color with Commission Internationale de l'Eclairage coordinates of x = 0.6173 and y = 0.3814 that was very similar to the National Television System Committee standard red, and it showed a bipolar carrier‐injection/transporting capability caused by electron‐withdrawing anthracene and electron‐donating amino groups. Poly[N‐2‐ethylhexyl‐3,6‐phenothiazinylene vinylene‐alt‐2‐methoxy‐5‐(2‐ethylhexyloxy)‐1,4‐phenylene vinylene], containing phenothiazinylene vinylene and dialkoxy phenylene vinylene moieties, showed excellent hole‐injection/transporting capability. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2502–2511, 2003 相似文献
6.
Xufeng Wu Gaoquan Shi Liangti Qu Jiaxin Zhang Feng'en Chen 《Journal of polymer science. Part A, Polymer chemistry》2003,41(3):449-455
Poly(p‐phenylene vinylene) (PPV), poly(2,5‐dioctyl‐p‐phenylene vinylene) (PDOPPV), and poly[2‐methoxy‐5‐(2′‐ethylhexyloxy)‐p‐phenylene vinylene] (MEHPPV) were synthesized by a liquid–solid two‐phase reaction. The liquid phase was tetrahydrofuran containing 1,4‐bis(bromomethyl)benzene, 1,4‐bis(chloromethyl)‐2,5‐dioctylbenzene, or 1,4‐bis(chloromethyl)‐2‐methoxyl‐5‐(2′‐ethylhexyloxy)benzene as the monomer and a certain amount of tetrabutylammonium bromide as a phase‐transfer catalyst. The solid phase consisted of potassium hydroxide particles with diameters smaller than 2 mm. The experimental results demonstrated that the reaction conversions of PPV and PDOPPV were fairly high (~65%), but the conversion of MEHPPV was only 45%. Moreover, gelation was found in the polymerization processes. As a result, PPV was insoluble and PDOPPV and MEHPPV were partially soluble in the usual organic solvents, such as tetrahydrofuran and chloroform. Soluble PDOPPV and MEHPPV were obtained with chloromethylbenzene or bromomethylbenzene as a retardant regent. The molar mass of soluble PDOPPV was measured to be 2 × 104 g mol?1, and that of MEHPPV was 6 × 104 g mol?1. A thin, compact film of MEHPPV was formed via spin coating, and it emitted a yellow light. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 449–455, 2003 相似文献
7.
Kotohiro Nomura Yoshitaka Miyamoto Hisao Morimoto Yves Geerts 《Journal of polymer science. Part A, Polymer chemistry》2005,43(23):6166-6177
Factors affecting the syntheses of high‐molecular‐weight poly(2,5‐dialkyl‐1,4‐phenylene vinylene) by the acyclic diene metathesis polymerization of 2,5‐dialkyl‐1,4‐divinylbenzenes [alkyl = n‐octyl ( 2 ) and 2‐ethylhexyl ( 3 )] with a molybdenum or ruthenium catalyst were explored. The polymerizations of 2 by Mo(N‐2,6‐Me2C6H3) (CHMe2 Ph)[OCMe(CF3)2]2 at 25 °C was completed with both a high initial monomer concentration and reduced pressure, affording poly(p‐phenylene vinylene)s with low polydispersity index values (number‐average molecular weight = 3.3–3.65 × 103 by gel permeation chromatography vs polystyrene standards, weight‐average molecular weight/number‐average molecular weight = 1.1–1.2), but the polymerization of 3 was not completed under the same conditions. The synthesis of structurally regular (all‐trans), defect‐free, high‐molecular‐weight 2‐ethylhexyl substituted poly(p‐phenylene vinylene)s [poly 3 ; degree of monomer repeating unit (DPn) = ca. 16–70 by 1H NMR] with unimodal molecular weight distributions (number‐average molecular weight = 8.30–36.3 × 103 by gel permeation chromatography, weight‐average molecular weight/number‐average molecular weight = 1.6–2.1) and with defined polymer chain ends (as a vinyl group, ? CH?CH2) was achieved when Ru(CHPh)(Cl)2(IMesH2)(PCy3) or Ru(CH‐2‐OiPr‐C6H4)(Cl)2(IMesH2) [IMesH2 = 1,3‐bis(2,4,6‐trimethylphenyl)‐2‐imidazolidinylidene] was employed as a catalyst at 50 °C. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 6166–6177, 2005 相似文献
8.
Roberto Grisorio Piero Mastrorilli Gian Paolo Suranna Pinalysa Cosma Luisa De Marco Michele Manca Giuseppe Gigli 《Journal of polymer science. Part A, Polymer chemistry》2011,49(4):842-847
This article describes the synthesis and properties of the first poly(arylene‐vinylene)‐based sensitizers for application in dye‐sensitized solar cells (DSSC). The polymers were prepared by the Suzuki–Heck copolymerization of potassium vinyltrifluoroborate (PVTB) with a mixture of dibromoaryl comonomers designed to obtain macromolecules able to bind onto the photoelectrode by means of carboxyphenylene units. The copolymerization reactions were carried out in the presence of an excess of PVTB to lower the molecular weights of the polymers, which were obtained as soluble materials. The polymers poly[(9,9‐didodecyl‐2,7‐fluorenylene)‐vinylene‐co‐(carboxy‐2,5‐phenylene)‐vinylene] ( P1 ), poly[(9,9‐didodecyl‐2,7‐fluorenylene)‐vinylene‐co‐(carboxy‐2,5‐phenylene)‐vinylene‐co‐(4,7‐benzothiadiazolylene)‐vinylene] ( P2 ), and poly[(9,9‐didodecyl‐2,7‐fluorenylene)‐vinylene‐co‐(carboxy‐2,5‐phenylene)‐vinylene‐co‐2,5‐thienylene‐vinylene] ( P3 ) were used in DSSC devices, obtaining conversion efficiencies up to 0.88% ( P3 ). © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
9.
Polymers with alternating anthracene and phenylene building blocks linked by ethynylene and/or vinylene units: Studying structure‐properties‐relationships 下载免费PDF全文
Sameh Boudiba Aleš Růžička Christoph Ulbricht Sandra Enengl Christina Enengl Jacek Gasiorowski Cigdem Yumusak Veronika Pokorná Drahomír Výprachtický Kurt Hingerl Dietrich R. T. Zahn Francesca Tinti Nadia Camaioni Sabrina Bouguessa Abdelkrim Gouasmia Věra Cimrová Daniel Ayuk Mbi Egbe 《Journal of polymer science. Part A, Polymer chemistry》2017,55(1):129-143
Four conjugated polymers ( P1 – P4 ) consisting of alternating anthracene‐9,10‐diyl and 1,4‐phenylene building blocks connected via ethynylene as well as vinylene ( P1 and P2 ), ethynylene‐only ( P3 ), and vinylene‐only ( P4 ) moieties, respectively, were synthesized and studied. The phenylene units in all four polymers bear 2‐ethylhexyloxy side‐chains to promote good solubility. The three polymers with vinylene units ( P1 , P2 , and P4 ) were prepared using the Horner–Wadsworth–Emmons reaction. For the synthesis of the arylene‐ethynylene polymer P3, the palladium‐catalyzed Sonogashira cross‐coupling reaction was used. The polymers were characterized by NMR, Fourier transform infrared spectroscopy, and Raman spectroscopy. Photophysical, absorption and photoluminescence, and electrochemical properties were studied. Spectroscopic ellipsometry measurements were performed to gain more insight on the optical properties. In addition, the transport properties were investigated using admittance spectroscopy. The bulk hole mobility and its dependence on the electric field were evaluated for P1 and P2 . © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 129–143 相似文献
10.
Hong‐Cheu Lin Chien‐Min Tsai Guan‐Hao Huang Jyh‐Ming Lin 《Journal of polymer science. Part A, Polymer chemistry》2006,44(2):783-800
Several series of light‐emitting oligo(p‐phenylene‐vinylene)s (BIII and BV series containing three‐ and five‐conjugated phenylene rings) with various side groups and end groups attached to the cores were synthesized and characterized. The analogous PBV polymers, derived from the BV series, were also synthesized and investigated. Blue and greenish light emissions were observed in the photoluminescence (PL) and electroluminescence (EL) spectra of the blend and pure films with these π‐conjugated structures. In contrast to the three‐conjugated ring oligomers, the five‐conjugated ring derivatives (oligomers and polymers) had larger maximum emission wavelength values of PL and EL emissions. Mesomorphism was introduced into the BV series by the replacement of three‐conjugated rings (BIII series) with five‐conjugated phenyl cores (BV series). The liquid‐crystalline properties of the BV series with end groups (on both end rings) were better than those of analogous BV‐OC8 without end groups. Polarized PL emissions were obtained by the alignment of liquid‐crystalline phase in rubbing cells. Upon heating, different PL emission wavelengths and intensities were observed in various phases. Not only the solubility and thermal properties but also the PL and EL properties could be effectively adjusted by the attachment of flexible alkoxy groups either on the central rings or on both end rings of the conjugated cores. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 783–800, 2006 相似文献
11.
Yang‐Liang Fan King‐Fu Lin 《Journal of polymer science. Part A, Polymer chemistry》2005,43(12):2520-2526
The presence of cis‐vinylene bonds in Gilch‐polymerized poly[2‐methoxy‐5‐(2′‐ethyl‐hexyloxy)‐1,4‐phenylene vinylene] is reported. Through fractionation, species with a weight‐average molecular weight of less than 37,000 exhibited an abnormal blueshift of photoluminescence spectra in toluene solutions, and this was attributed to the presence of cis‐vinylene bonds, as verified by NMR spectroscopy. Surprisingly, the fractionated species (~1 wt %) with a weight‐average molecular weight of 5000 were mostly linked by the cis‐vinylene bonds. The concentration decreased with the molecular weight until a molecular weight of 37,000 was reached; at that point, the polymer chains contained mainly trans‐vinylene bonds. Obviously, the formation of cis‐vinylene bonds strongly inhibited the growth of polymer chains during Gilch polymerization. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 2520–2526, 2005 相似文献
12.
In this paper, the electroluminescent properties of a new partially‐conjugated hyperbranched poly (p‐phenylene vinylene) (HPPV) were studied. The single layer light‐emitting device with HPPV as the emitting layer emits blue‐green light at 496 nm, with a luminance of 160 cd/m2 at 9 V, a turn‐on voltage of 4.3 V and an electroluminescent efficiency of 0.028 cd/A. By doping an electron‐transport material [2‐(4‐biphenylyl)‐5‐phenyl‐1,3,4‐oxadiazole, PBD] into the emitting layer and inserting a thin layer of tris(8‐hydroxy‐quinoline)aluminum (Alq3) as electron transporting/hole blocking layer for the devices, the electroluminescent efficiency of 1.42 cd/A and luminance of 1700 cd/m2 were achieved. The results demonstrate that the devices with the hyperbranched polymers as emitting material can achieve high efficiency through optimization of device structures. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
13.
Rupei Tang Yutao Chuai Caixia Cheng Fu Xi Dechun Zou 《Journal of polymer science. Part A, Polymer chemistry》2005,43(14):3126-3140
A series of new poly(p‐phenylene vinylene) derivatives with different dendritic pendants—poly{2‐[3′,5′‐bis(2″‐ethylhexyloxy)benzyloxy]‐1,4‐phenylenevinylene} (BE–PPV), poly{2‐[3′,5′‐bis(3″,7″‐dimethyl)octyloxy]‐1,4‐phenylenevinylene} (BD–PPV), poly(2‐{3′,5′‐bis[3″,5″‐bis(2?‐ethylhexyloxy)benzyloxy]benzyloxy}‐1,4‐phenylenevinylene) (BBE–PPV), poly(2‐{3′,5′‐bis[3″,5″‐bis(3?,7?‐dimethyloctyloxy)benzyloxy]benzyloxy}‐1,4‐phenylenevinylene) (BBD–PPV), and poly[(2‐{3′,5′‐bis[3″,5″‐bis(2?‐ethylhexyloxy)benzyloxy]benzyloxy}‐1,4‐phenylenevinylene)‐co‐(2‐{3′,5′‐bis[3″,5″‐bis(3?,7?‐dimethyloctyloxy)benzyloxy]benzyloxy}‐1,4‐phenylenevinylene)] (BBE‐co‐BBD–PPV; 1:1)—were successfully synthesized according to the Gilch route. The structures and properties of the monomers and the resulting conjugated polymers were characterized with 1H and 13C NMR, elemental analysis, gel permeation chromatography, thermogravimetric analysis, ultraviolet–visible absorption spectroscopy, photoluminescence, and electroluminescence spectroscopy. The obtained polymers possessed excellent solubility in common solvents and good thermal stability, with a 5% weight loss temperature of more than 328 °C. The weight‐average molecular weights and polydispersity indices of BE–PPV, BD–PPV, BBE–PPV, BBD–PPV, and BBE‐co‐BBD–PPV (1:1) were in the range of 1.33–2.28 × 105 and 1.35–1.53, respectively. Double‐layer light‐emitting diodes (LEDs) with the configuration of indium tin oxide/polymer/tris(8‐hydroxyquinoline) aluminum/Mg:Ag/Ag devices were fabricated, and they emitted green‐yellow light. The turn‐on voltages of BE–PPV, BD–PPV, BBE–PPV, BBD–PPV, and BBE‐co‐BBD–PPV (1:1) were approximately 5.6, 5.9, 5.5, 5.2, and 4.8 V, respectively. The LED devices of BE–PPV and BD–PPV possessed the highest electroluminescent performance; they exhibited maximum luminance with about 860 cd/m2 at 12.8 V and 651 cd/m2 at 13 V, respectively. The maximum luminescence efficiency of BE–PPV and BD–PPV was in the range of 0.37–0.40 cd/A. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 3126–3140, 2005 相似文献
14.
Liang Liao Yi Pang Liming Ding Frank E. Karasz Philip R. Smith Michael A. Meador 《Journal of polymer science. Part A, Polymer chemistry》2004,42(23):5853-5862
Soluble yellow/orange‐emitting poly[tris(2,5‐dihexyloxy‐1,4‐phenylenevinylene)‐alt‐(1,3‐phenylenevinylene)] derivatives ( 6 ) were synthesized and characterized. These polymers contained oligo(p‐phenylene vinylene) chromophores of equal conjugation length, which were jointed via a common m‐phenylene unit. An optical comparison of 6 and its model compound ( 8 ) at room temperature and low temperatures revealed the similarity in their absorption and fluorescence band structures. The vibronic band structure of 6 was assigned with the aid of the spectroscopic data for 8 at the low temperatures. 6 was electroluminescent and had an emission maximum wavelength at approximately 565 nm. With the device indium tin oxide/PEDOT/ 6 /Ca configuration, the polymer exhibited an external quantum efficiency as high as 0.25%. Simple substitution on m‐phenylene of 6 raised the electroluminescence output by a factor of about 10. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5853–5862, 2004 相似文献
15.
A new p‐phenylene–vinylene–thiophene‐based siloxane block copolymer has been synthesized. The copolymer consists of alternating rigid and flexible blocks. The rigid blocks are composed of phenylene–vinylene–thiophene‐based units, and the flexible blocks are derived from 1,3‐dialkyldisiloxane units. The former component acts as the chromophore, and allows fine tuning of band gap for blue‐light emission, while the latter imparts good solubility of the copolymer in organic solvents, and thus, should enhance processibility of the resulting copolymer. The thermal properties of the copolymer have been characterized by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The photoluminescence (PL) of the copolymer in solution and in cast film has been studied. The effects of concentration on the PL intensity of the new copolymer in polymer blends with poly(methyl methacrylate) (PMMA) and poly(vinyl carbazole) (PVK) have also been described. Efficient energy transfer from PVK to the new block copolymer in the blended film was observed. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 1450–1456, 2000 相似文献
16.
F. Bartha I. A. Howard P. Geerlings C. Van Alsenoy D. Vanderzande T. J. Cleij F. Bogr 《International journal of quantum chemistry》2006,106(8):1912-1923
We have calculated the optical and electronic properties of several conjugated organic polymers: poly(p‐phenylene‐vinylene) (PPV) and its derivatives. Cyano substitutions on the phenylene ring: poly(2,5‐dicyano‐p‐phenylene‐vinylene) (2,5‐DCN‐PPV) and on the vinylene linkage: poly(p‐phenylene‐7(,8)‐(di)cyano‐vinylene) are considered. In addition, poly(quinoxaline‐vinylene) (PQV) is studied. The infinite isolated quasi‐1D chains are treated with periodic boundary conditions, using atomic basis sets. In a comparative study of PPV, some issues regarding the selection of the functionals and basis sets are discussed and excitation energies derived from time‐dependent and from ordinary methods are compared. It is concluded that for these polymers the calculations are informative at the B3LYP/6‐31G** density functional theory (DFT) level. The absolute values might change with improved methods, but the similarity of the polymers suggests that the relative characterization is adequate. Band structures are communicated along with characteristics of the highest occupied and the lowest unoccupied crystal orbitals (HOCO and LUCO). Electron affinities, ionization potentials, valence and conduction bandwidths, and effective masses at the bandgap are given. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2006 相似文献
17.
Liang Liao Yi Pang Liming Ding Frank E. Karasz 《Journal of polymer science. Part A, Polymer chemistry》2004,42(8):1820-1829
Green‐emitting substituted poly[(2‐hexyloxy‐5‐methyl‐1,3‐phenylenevinylene)‐alt‐(2,5‐dihexyloxy‐1,4‐phenylenevinylene)]s ( 6 ) were synthesized via the Wittig–Horner reaction. The polymers were yellow resins with molecular weights of 10,600. The ultraviolet–visible (UV–vis) absorption of 6 (λmax = 332 or 415 nm) was about 30 nm redshifted from that of poly[(2‐hexyloxy‐5‐methyl‐1,3‐phenylenevinylene)‐alt‐(1,4‐phenylenevinylene)] ( 2 ) but was only 5 nm redshifted with respect to that of poly[(1,3‐phenylenevinylene)‐alt‐(2,5‐dihexyloxy‐1,4‐phenylenevinylene)] ( 1 ). A comparison of the optical properties of 1 , 2 , and 6 showed that substitution on m‐ or p‐phenylene could slightly affect their energy gap and luminescence efficiency, thereby fine‐tuning the optical properties of the poly[(m‐phenylene vinylene)‐alt‐(p‐phenylene vinylene)] materials. The vibronic structures were assigned with the aid of low‐temperature UV–vis and fluorescence spectroscopy. Light‐emitting‐diode devices with 6 produced a green electroluminescence output (emission λmax ~ 533 nm) with an external quantum efficiency of 0.32%. Substitution at m‐phenylene appeared to be effective in perturbing the charge‐injection process in LED devices. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1820–1829, 2004 相似文献
18.
Sung‐Ho Jin Hwan‐Hee Jung Chan‐Koo Hwang Dae‐Sung Koo Won Suk Shin Yeong‐Inn Kim Jae Wook Lee Yeong‐Soon Gal 《Journal of polymer science. Part A, Polymer chemistry》2005,43(21):5062-5071
A new series of copolymers with high brightness and luminance efficiency were synthesized using the Gilch polymerization method, and their electro‐optical properties were investigated. The weight‐average molecular weights (Mw) and polydispersities of the synthesized poly(9,9‐dioctylfluorenyl‐2,7‐vinylene) [poly(FV)], poly[2‐(3‐dimethyldodecylsilylphenyl)‐1,4‐phenylenevinylene] [poly(m‐SiPhPV)], and poly[9,9‐di‐n‐octylfluorenyl‐2,7‐vinylene]‐co‐(2‐(3‐dimethyldodecylsilylphenyl)‐1,4‐phenylene vinylene)] [poly(FV‐co‐m‐SiPhPV)] were found to be in the ranges of (8.7–32.6) × 104 and 2.3–5.4, respectively. It was found that the electro‐optical properties of the copolymers could be adjusted by controlling the feed ratios of the comonomers. Thin films of poly(FV), poly(m‐SiPhPV), and poly(FV‐co‐m‐SiPhPV) were found to exhibit photoluminescence quantum yields between 21% and 42%, which are higher than those of MEH‐PPV. Light‐emitting diodes were fabricated in ITO/PEDOT/light‐emitting polymer/cathode configurations using either double layer (LiF/Al) or triple layer (Alq3/LiF/Al) cathode structures. The performance of the polymer light‐emitting diodes (PLEDs) with triple layer cathodes was found to be better than that of the PLEDs with double layer cathodes in poly(FV) and poly(FV‐co‐m‐SiPhPV). The turn‐on voltages of the PLEDs were in the range of 4.5–6.0 V, with maximum brightness and luminance efficiency up to 9691 cd/m2 at 16 V and 3.27 cd/A at 13 V, respectively. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 5062–5071, 2005 相似文献
19.
Roberto Grisorio Claudia Piliego Paola Fini Pinalysa Cosma Piero Mastrorilli Giuseppe Gigli Gian Paolo Suranna Cosimo Francesco Nobile 《Journal of polymer science. Part A, Polymer chemistry》2008,46(18):6051-6063
The synthesis of new random poly(2,7‐fluorenylene‐vinylene)s was achieved by a Suzuki–Heck cascade polymerization reaction. The poly(fluorenylene‐vinylene) base structure was modified by the regio‐random incorporation of 1‐cyano‐2,5‐phenylene as electron withdrawing unit ( CN‐PFV1 ) and its properties were compared with terpolymers also embodying 1,4‐dioctyloxy‐2,5‐phenylene ( CN‐PFV2 ) or 3,6‐N‐octylcarbazole ( CN‐PFV3 ) as electron‐donating moieties. Thermal analysis revealed a high thermal stability (Td > 389 °C) and the absence of glass transitions for all polymers. Cyclic voltammetry indicated a high electron affinity of the materials (2.96–3.21 eV) attributed to the presence of the cyano‐containing comonomer. In dilute solutions, the copolymers showed a broad green fluorescence with quantum yields ranging from 0.42 to 0.79, while in the solid state, a relatively narrow emission centered at ~ 560 nm, governed by the low‐energy segments within the π‐conjugated backbone, was observed. The electroluminescence properties of the materials were tested in OLED devices of ITO/PEDOT‐PSS/ CN‐PFV1‐3 /Ca/Al or ITO/PEDOT‐PSS/ CN‐PFV1‐3 /Alq3/Ca/Al configurations, showing a bright green‐yellow emission that, in the case of CN‐PFV2 , reached 1403 cd/m2 with efficiencies as high as 0.13 cd/A. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 6051–6063, 2008 相似文献
20.
Catherine Bianchi Bruno Grassl Bernard Franois Christine Dagron‐Lartigau 《Journal of polymer science. Part A, Polymer chemistry》2005,43(19):4337-4350
Water‐soluble and photoluminescent block copolymers [poly(ethylene oxide)‐block‐poly(p‐phenylene vinylene) (PEO‐b‐PPV)] were synthesized, in two steps, by the addition of α‐halo‐α′‐alkylsulfinyl‐p‐xylene from activated poly(ethylene oxide) (PEO) chains in tetrahydrofuran at 25 °C. This copolymerization, which was derived from the Vanderzande poly(p‐phenylene vinylene) (PPV) synthesis, led to partly converted PEO‐b‐PPV block copolymers mixed with unreacted PEO chains. The yield, length, and composition of these added sequences depended on the experimental conditions, namely, the order of reagent addition, the nature of the monomers, and the addition of an extra base. The addition of lithium tert‐butoxide increased the length of the PPV precursor sequence and reduced spontaneous conversion. The conversion into PPV could be achieved in a second step by a thermal treatment. A spectral analysis of the reactive medium and the composition of the resulting polymers revealed new evidence for an anionic mechanism of the copolymerization process under our experimental conditions. Moreover, the photoluminescence yields were strongly dependant on the conjugation length and on the solvent, with a maximum (70%) in tetrahydrofuran and a minimum (<1%) in water. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 4337–4350, 2005 相似文献