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用电化学测量和表面分析方法研究了钇离子注入对304L奥氏体不锈钢耐水溶液腐蚀改性作用。结果表明,在适当的注入剂量下,注入试样在0.5mol/LH2SO4、0.6mol/LNaCl水溶液中的自腐蚀电位正移,自腐蚀电流密度下降至原来的1/4~1/6,击穿电位上升30~50mV。通过离于注入方式添加的钇以过饱和固溶形式均匀分布在不锈钢表面。试样表面层内Cr/Fe比值增加,含氧层厚度也增加。钇对不锈钢耐水溶液腐蚀改性主要是通过表面合金化和改变不锈钢表面层成分实现的。研究表明,注入剂量的变化对材料的改性效果具有一定的影响。 相似文献
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水溶性聚合物改性水泥的研究:Ⅱ.水溶性聚合物对水泥水化过程的 … 总被引:1,自引:0,他引:1
从聚合物改性水泥的水化速率,水化热及水化生成物三方面讨论了聚合物对水泥水化的影响。水泥溶液pH值和电导率及水泥凝结时间的研究结果表明,非离子聚合物聚丙烯酰胺,聚乙烯醇减慢水泥的初期水化,具有缓凝作用,而阴离子聚合物水解聚丙烯酰胺,聚丙烯酸,磺化聚丙烯酰胺及磺化聚苯乙烯则加速水泥的初期水化,具有促凝作用; 相似文献
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含环氧基的丙烯酸酯共聚物改性环氧树脂 总被引:10,自引:0,他引:10
合成了一系列含环氧基团的丙烯酸酯聚合物(HGMB),并对其改性环氧树脂/4,4‘-二氨基二苯基甲烷的抗冲性能,动态力学行为进行了考察,结果表明:当必性体系中加入质量分数为15%的HGMB(甲基丙烯酸缩水甘油酯、甲基丙烯酸羟乙基酯、甲基丙烯酸甲酯、丙烯酸丁酯的摩尔分数分别为4.3%、5%、25.7%、65%)时,与空白体系相比,改性体系的冲击强度提高50%,且玻璃化有所提高,模量没有降低。 相似文献
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制备了水解聚丙烯酰胺(HPAM)、磺甲基化聚丙烯酰胺(SPAM)及磺化聚苯乙烯(SPS)等几种水溶性聚合物。研究了水溶性聚合物的种类、阴离子度、分子量、表面活性、掺量、pH值等因素对水泥净浆流动性的影响。结果表明阴离子聚合物及适中的阴离子度、分子量、掺量、pH值有利于水泥的分数,从而改善水泥的流动性。聚合物的电荷保护作用是影响水溶性聚合物改性水泥分散的主要因素。提出了聚合物分散水泥粒子与分子链性质 相似文献
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水溶性聚合物和两亲聚合物:聚(丙烯酰胺-co-丙烯酸钠)-g-聚(β-胺基丙酸)接枝共聚物 总被引:2,自引:0,他引:2
合成了端丙烯酰胺基聚(β-胺基丙酸)大分子单体,用端基滴定法和1H-NMR法测定了大分子单体的分子量,用^1^3C-MNR和氢氧化钠水解法测定了支化度,在水溶液中用硫酸亚铁/异丙苯过氧化氢氧化还原引发体系引发丙烯酰胺,丙烯酸钠与聚(β-胺基丙酸)大分子单体的共聚反应,合成了聚(丙烯酰胺-co-丙烯酸钠)-g-聚(β-胺基丙酸)用1H-NMR和滴定法测定了接枝共聚物的组成。溶液性质的数据表明,与部分 相似文献
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Catalysis Conversion Methane into C2 Hydrocarbons via Electric Field Enhanced Plasma 总被引:3,自引:0,他引:3
BaoWeiWANG GenHuiXU 《中国化学快报》2003,14(12):1236-1238
In this paper the effect of catalyst and carrier in electric field enhanced plasma on methane conversion into C2 hydrocarbons was investigated. Methane coupling reaction was studied in the system of continuous flow reactor on Ni, MoO3, MnO2 catalysts and different ZSM-5 carriers. The per pass conversion of methane can be as high as 22%, the selectivity of ethylene can be as high as 23.8%, of acetylene 60.8%, of ethane 5.4% and of total C2 hydrocarbons was more than 90%. ZSM-5-25 was the better carrier and MnO2 was the better active component. The efficiency of energy was as high as 7.81%. 相似文献
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Labib Ghaoui Karen Pell Karen Chritz Robert N. Loomis 《Journal of separation science》1995,18(3):157-160
The use of 10%, 1%, and 0.1% ammonia in helium as carrier gas was investigated as a means of improving poor chromatographic peak shape often associated with low level determinations of amine compounds using thin film capillary columns. The 1% ammonia in helium was found suitable for improving the peak shape of sterically unhindered amine compounds, such as urethane and certain aliphatic primary amines, during gas chromatographic analysis on thin film columns. There was a negligible effect on the peak tailing arising on thick film columns. The 0.1% ammonia in helium was suitable, but not as efficient as the 1% ammonia in helium, in eliminating the peak tailing associated with low level analysis of amine compounds. The signal-to-noise (S/N) ratio improved from < 1 using helium carrier gas to 20–25 (for certain test amine compounds) using 1% ammonia in carrier gas. The 10% ammonia in helium carrier gas had an effect on the chromatographic performance similar to that of the 1% ammonia in helium, but the baseline level was very high and this mixture was not used in further studies. 相似文献
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柠檬醛及中间体的合成 总被引:1,自引:0,他引:1
以异戊烯醛和异戊烯醇为原料,经异戊烯酸催化缩醛化反应得到3-甲基-2-丁烯醛二异戊烯基缩醛,再经磷酸二氢铵催化消除反应得到顺/反-异戊二烯基-3-甲基丁二烯醚,并进一步热重排获得柠檬醛。研究了缩醛化反应条件和消除反应条件对转化率的影响。结果表明,以0.3%异戊烯酸为酸性催化剂,70~75℃共沸脱水反应8 h,异戊烯醛的单程转化率达到63%~64%,处理后可得含量为97.5%的3-甲基-2-丁烯醛二异戊烯基缩醛,收率96.8%;以0.2%~0.5%磷酸二氢铵为催化剂,100~130℃,2.66 kPa下反应并及时将反应产物蒸出,处理后得到含量为95.9%的顺/反-异戊二烯基-3-甲基丁二烯醚,收率97.0%。顺/反-异戊二烯基-3-甲基丁二烯醚在120~130℃重排反应1 h,其反应产物柠檬醛含量97.5%,收率90.2%。 相似文献
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This study examined the antiradical activity and chemical composition of essential oils of some plants grown in Mosul, Iraq. The essential oils of myrtle and parsley seed contained α-pinene (36.08% and 22.89%, respectively) as main constituents. Trans-Anethole was the major compound found in fennel and aniseed oils (66.98% and 93.51%, respectively). The dominant constituent of celery seed oil was limonene (76.63%). Diallyl disulphide was identified as the major component in garlic oil (36.51%). Antiradical activity was higher in garlic oil (76.63%) and lower in myrtle oil (39.23%). The results may suggest that some essential oils from Iraq possess compounds with antiradical activity, and these oils can be used as natural antioxidants in food applications. 相似文献
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Ultrasound-assisted synthesis of ethyl hexanoate was studied in a solvent-free system using Amberlyst-15 as a heterogeneous catalyst. The effect of reaction parameters was evaluated by employing Box Behnken Design. Maximum conversion was obtained as 83.9% experimentally with operating temperature 60 °C, ethanol to hexanoic acid molar ratio as 3, 60% duty cycle, 11% catalyst loading, 10% molecular sieves, and 80 W input power which were optimized through one parameter at a time. The optimal conditions for maximum 86.66% conversion obtained by Box Behnken Design operated in Response Surface Methodology were 62.8 °C temperature, 3.31 ethanol to hexanoic acid molar ratio, and 51.58% duty cycle. The absence of external mass transfer resistances was proved by evaluating Mear's criterion. Thiele modulus and effectiveness factor were determined to study the influence of internal mass transfer resistance qualitatively. The kinetics of the heterogeneous reaction was modeled using Langmuir-Hinshelwood model. The activation energy was calculated as 24.61 kJ/mol. 相似文献
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含亚砜基功能高分子可用作高分子药物载体,高分子螯合剂,高分子催化剂及气体分离膜材料等,近年来已引起各国学者的兴 相似文献
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I. El Mannoubi S. Barrek T. Skanji H. Casabianca H. Zarrouk 《Chemistry of Natural Compounds》2009,45(5):616-620
The lipid fraction of Opuntia ficus indica seeds was extracted and analyzed for its chemical and physical properties such as acid value, free fatty acid percentage
(% FFA), iodine index, peroxide value, and saponification value as well as refractive index and density. The yield of seed
oil was calculated as 11.75%. The acid and free fatty acid values indicated that the oil has a fairly low acidity. The triacylglycerols,
fatty acids, sterols, and tocopherols were identified and their concentrations determined. The main TAGs were LLL (25.60%),
OLL (21.53%), PLL (15.53%), and POL + SLL (12.73%). Linoleic acid (60.69%) was the dominant fatty acid, followed by oleic
(21.42%) and palmitic (12.76%) acids, respectively. A high level of sterols making up 16.06 g/kg seed oil was present. The
sterol marker, β-sitosterol, accounted for 71.60% of the total sterol content in the seed oil. Among the tocopherols present
in the oil, γ-tocopherol (421.08 mg/kg) was the main constituent. 相似文献