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1.
《Composite Interfaces》2013,20(4):197-211
The experimental technique of single-fiber electromechanical pull-out testing was introduced and used to study the interface between steel fiber and cement. The technique involves measuring both the contact electrical resistivity between fiber and matrix and the shear bond strength in a fiber-matrix interface sample. Samples that are identically prepared differ in contact resistivity and bond strength, which correlate. The correlation allows determination of even small differences in bond strength due to differences in sample preparation conditions, such as fiber surface treatment, cement curing age and admixtures to the cement paste. It also gives information on the structure of the interface and allows the bond strength to be non-destructively determined by measuring the contact resistivity.  相似文献   

2.
水和乙醇对纳米管结构聚苯胺电阻率的影响   总被引:2,自引:0,他引:2       下载免费PDF全文
研究了水和无水乙醇对萘磺酸掺杂的纳米管结构聚苯胺的电阻率-温度依赖关系的影响(测量温区为80—300K).实验结果表明,水分子和乙醇分子的进入均使样品的电导率升高.利用电荷能量限制隧道模型结合纳米管粉末压片的结构特点,认为样品电阻主要来源于纳米管间接触电阻.水或乙醇分子在纳米管聚苯胺中通过与分子链的相互作用,增加了链间与链上非局域化载流子的数量,增大管间接触界面,降低了载流子的隧穿势垒,进而提高了导电能力.但水和乙醇对样品导电性质影响程度是不同的,主要是因为水分子和乙醇分子在结构和物理化学性质上的不同. 关键词: 聚苯胺 纳米管 电阻率  相似文献   

3.
《Composite Interfaces》2013,20(5):453-458
Moisture was found to have a reversible effect on the interlaminar interface of a continuous carbon fiber epoxy–matrix composite. An increase in humidity increased the resistivity. The reversibility was essentially complete after the first cycle of humidity variation. The effect is attributed to expansion of the matrix at the interlaminar interface due to moisture uptake. It allows use of the composite for humidity sensing.  相似文献   

4.
《Composite Interfaces》2013,20(6):497-505
The interlaminar interface in carbon fiber (continuous) epoxy-matrix composites was studied by measuring the contact electrical resistivity of this interface. The contact resistivity was found to decrease with increasing curing pressure and to be higher for unidirectional than crossply composites. The lower the contact resistivity, the greater was the extent of direct contact between fibers of adjacent laminae. The activation energy for electrical conduction in the through-thickness direction was found to increase with increasing curing pressure and to be lower for unidirectional than crossply composites. The higher the activation energy, the greater the residual interlaminar stress.  相似文献   

5.
LaNiO3 thin film with perovskite structure was successfully prepared on Ag substrate via an amorphous heteronuclear complex LaNi(DTPA)·6H2O as a precursor. The influences of precursor concentration and PEG additive with different molecular weight on the texture of the film were carefully studied. The interface states of LaNiO3/Ag film were revealed by using AES analysis. The effect of annealing time on the interface diffusion of the LaNiO3/Ag film was shown by using AES depth profile spectrum. The relationship between the electric resistivity of the film and the environmental temperature was measured by using four-probe method. The results showed the film had good metallic conductivity from 300 down to 77 K.  相似文献   

6.
Present work explored a room temperature, simple and low cost chemical route for the preparation of hydrophilic cobalt oxide films from alkaline cobalt chloride (CoCl2:6H2O) and double distilled water precursor solutions. As-deposited cobalt oxide films showed amorphous nature, which is one of the prime requirements for supercapacitor, as confirmed from X-ray diffraction studies. Changes in direct band gap energy and electrical resistivity of as-deposited cobalt oxide films were confirmed after annealing. Spherical grains of about 40-50 nm diameters were uniformly distributed over the substrate surface. Surface wettability studied in contact with liquid interface, showed hydrophilic nature as water contact angle was <90°. Finally, presence of cobalt-oxygen covalent bond was observed from Raman shift experiment.  相似文献   

7.
周骏  邸明东  孙铁囤  孙永堂  汪昊 《物理学报》2010,59(12):8870-8876
在异质结前界面缺陷态密度Dit1和异质结背界面缺陷态密度Dit2均取不同值时,对p型单晶硅(c-Si(p))为衬底的硅异质结太阳电池的衬底电阻率ρ与电池性能的关系进行了数值研究.结果表明:衬底电阻率的最优值ρop取决于前界面缺陷态密度Dit1,且ρop随着Dit1的增大而增大;当ρρop时,背界面缺陷态密度Dit2对衬底电阻率的可取值范围具有较大影响,Dit2越大衬底电阻率的可取值范围越小.  相似文献   

8.
In order to simultaneously improve the conductivity and stabilize the contact resistance of electrically conductive adhesives (ECAs) containing silver flakes, different types of aminoaldehydes as multifunctional additives, N, N-dimethyl-4-aminobenzaldehyde (DABA), benzaldehyde (BA) as a comparison, and formamide (FA), were introduced into ECAs formulations. The results showed that when the optimal levels of FA, BA, and DABA were individually added into ECAs, the decrease in the resistivities of the ECAs were 34.8%, 67.2%, and 41.7%, respectively, compared to the control sample. This is because, during the curing process, the aldehyde acts as a reducing agent and reduces the oxidized silver flakes. Furthermore, the ECAs with FA or DABA had better contact resistance stability than that of the control sample under the condition of 85°C/85% relative humidity, but ECAs with BA could not stabilize the contact resistance on tin finish, The results indicate that FA and DABA can be adsorbed onto the tin surface and inhibit the occurrence of the galvanic corrosion on the interface between ECA and tin finish. The rheological results showed the processability of ECAs with FA, BA, and DABA were better than that of the control sample. However, the shear strength of ECAs with BA and DABA slightly declined.  相似文献   

9.
The in-plane electrical resistivity and thermoelectric power have been measured on single crystals of La2-xBaxCuO4 at around x=0.125. The room temperature resistivity and thermopower have their maximum values at x=0.125, indicating that the carrier concentration is the minimum and the carriers are most strongly localized at x=0.125. The observed semiconductor-like behaviour can be well described by the weak-localized quasi-two-dimensional state. The steep rise in electric resistivity of the sample at x=0.125 below 70K is attributed to the formation of static stripe-order of holes and spins, which are pinned by the low-temperature tetragonal (LTT) structure, as discovered in La1.48Nd0.4Sr0.12CuO4. The temperature dependence of electric resistivity below 70K is still well described by the formula ρ∝ lnT. A definite change in the slope of thermopower is observed at the low-temperature orthorhombic-LTT structural phase transition temperature. The origin of the 1/8 anomaly is discussed in the text.  相似文献   

10.
MgB2和Mg0.93Li0.07B2的电阻率与霍尔效应研究   总被引:5,自引:0,他引:5       下载免费PDF全文
测量了MgB2和Mg0.93Li0.07B2的电阻率ρ(T)与霍尔系数RH(T)的温度依赖关系.电阻率的测量结果表明,MgB2和Mg0.93Li0.07B2的正常态电阻率与温度有平方的依赖关系.MgB2和Mg0.93Li0.07B2关键词: 电阻率 霍尔效应  相似文献   

11.
 利用在金刚石压砧上集成的微电路,原位测量了CdSe多晶粉末在温度为300~450 K、压力达到23 GPa时电阻率随温度和压力的变化关系。实验结果表明:在加压过程中,电阻率在2.6 GPa压力时出现的异常改变,对应着CdSe从纤锌矿向岩盐矿结构的转变,而在6.0、9.8、17.0 GPa等压力处出现的电阻率异常,则是由CdSe中的电子结构的变化所引起的;在卸压过程中,只在约14.0和3.0 GPa压力下观察到了两个电阻率异常点。通过对电阻率随压力变化曲线的模拟,得出了CdSe高压相的带隙随压力的变化关系,据此预测CdSe金属化的压力应在70~100 GPa之间。变温实验结果表明,在实验的温度和压力范围内,CdSe的电阻率均随温度的增加而升高。  相似文献   

12.
P Singh  S Prakash 《Pramana》1994,42(5):405-420
The electronic structure of substitutional non-magnetic impurities Cu, Ag, Cd, Mg, Zn, Ga, In, Ge, Si and Sn in Al is studied using density functional theory. A simple physical model is proposed to calculate the effective charges on impurities in trivalent metal Al. A linear relation is found between the effective charges on impurities and impurity vacancy capture radii. The spherical solid model (SSM) is used to account for discrete nature of the host. The impurity-induced change in charge density, scattering phase shifts, host-impurity potential, residual resistivity and impurity self-energy are calculated. Higher order scattering phase shifts are found significant and the host-impurity potential is found proportional to effective charge on impurity in its vicinity. The self-consistently calculated potential is used to calculate the electric field gradients (EFGs) at the first and second nearest neighbours (1NNs, 2NNs) of impurity. The calculated values are in agreement with the experimental results.  相似文献   

13.
Over the past four decades xerography, the dry ink marking process developed by the photocopy industry, has grown from nothing into a $170 billion industry worldwide. This amazing commercial success is due to the fact that during this period, xerographic technology experienced constant and often-dramatic improvement created by sustained industrywide research and development. Indeed, the development of the xerographic copying and printing industry is one of the great applied surface science successes of all time. In this article we outline the story of the advances in xerographic technology during the past four decades, describe the profound dependence on these advances of the control of surface and interface properties of increasingly sophisticated multi-component materials systems, and indicate the potential impact on the industry of the continuing development of the surface and interface science of the multi-component materials packages used in xerographic technology.  相似文献   

14.
本文研究了对Y1-xCaxBa2Cu3O7-δ进行Ca掺杂后样品的输运特性.实验中发现:随Ca含量增加,样品正常态电阻随之下降.出现反常电阻现象原因可能是Ca替代Y位,导致体系载流子浓度发生变化,从而使得晶界附近的电子能带结构发生改变.另外;低温下的样品伏安特性在外磁场下出现反常,动态电阻dV/dI随磁场增加而下降.有关该现象的物理机制有待于进一步研究.  相似文献   

15.
砂泥岩薄互层电阻率准确测量是提高泥质砂岩储层计算的一项重要工作。为了解决薄互层电阻率准确测量问题,该文提出一种三维感应成像测井仪的设计与实现方法。首先,基于感应电磁测量方法,设计由1个三轴发射器、4个单轴接收阵列和3个三轴的接收阵列组成的三维探测器。在此基础上,通过三维线圈系参数与结构创新设计、多频循环发射、高精度多道同步采集、高性能发射接收一体化集成等技术实现,在每一个深度点可获取78个电导率测量值。最后,利用数据校正与处理技术来消除各种环境影响,经过理论模型和实际资料的处理结果均证实,该仪器处理得到5条不同径向探测深度的水平电阻率与垂向电阻率、地层倾角等曲线,实现了对薄互层电阻率的准确测量。  相似文献   

16.
近来,关于无序涡旋物质凝聚体的著名的涡旋玻璃理论受到了来自某些新实验的严重质疑.我们重新审查了高温超导体的临界标度,发现超导混合态的直流伏安特性具有扩展幂律的一般形式.由该扩展幂律型非线性方程模拟的等温线和Strachan等人得到的实验数据[Phys.Rev.Lett.87(2001),067007]符合得很好.文中还讨论了长期以来围绕纵向电阻率和霍尔电阻率的临界指数的某些争议.  相似文献   

17.
叙述微通道板玻璃的电阻率和其氢原处理后的表面电阻率以及表面电阻率的影响因素。按照玻璃钢络结构观点并就微通道板制造工艺中出现的电阻率差异进行了分析。最后,给出了改进措施。  相似文献   

18.
Electrical resistivity measurements have been performed on Ni2Mn(Sn1?xInx) Heusler alloys, where x = 0, 0.02, 0.05, 0.10 and 0.15, in the temperature range of 4–300 K. The experimental data clearly show the existence of two distinct kinds of resistivity behaviour, both described by an aTn law, for 7 ? T ? 20 K. Between 170 and 300 K the data are well described by an AT + BT2 phenomenological fit, and the results obtained are in good agreement with an interpretation based on electron-phonon and spin-disorder scattering.  相似文献   

19.
本文介绍了半导体硅的Seebeck系数和电阻率的测量,与Hall系数和电阻率测量实验相对应,从另一个方面了解半导体导电性能的一些特征.由Seebeck系数的正负号确定载流子的类型是P型还是N型.半导体内有两种导电机制:杂质导电和本征导电.在杂质导电区,可以确定晶格散射因子;在本征导电区,可以确定硅的禁带宽度.  相似文献   

20.
本文考察了由于温度各向异性分布产生的电磁波不稳定性所联系的反常电阻率问题,讨论了这一现象与地球磁场磁尾区中“磁再联”现象的关系。  相似文献   

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