Saturated Compressible and Incompressible Porous Solids: Macro- and Micromechanical Approaches

In this paper two complementary approaches are used to describe the mechanical behavior of saturated compressible and incompressible porous solids. The macroscopic investigation is based on the mixture theory, restricted by the volume fraction concept. In the micromechanical approach, a hierarchy of conditionally ensemble averaged fluid and solid phase momentum balance equations are derived for a simple model of quasi-static liquid saturated porous media. The ensemble averaged equations for both the phases agree remarkably well with the macroscopic results. A micromechanical basis for Terzhagi's effective stress concept is presented. In addition, an expression for additional partial solid stress modifying the effective stress principle, to account for deformability of solid materials, is also derived.     

A theory for species migration in a finitely strained solid with application to polymer network swelling

We present a theory for the behavior of a solid undergoing two interdependent processes, a macroscopic or mechanical process due to the deformation of the solid and a microscopic or chemical process due to the migration of a chemical species through the solid. The principle of virtual power is invoked to deduce the basic balances of the theory, namely the mechanical force balance and the transport balance for the chemical species. In combination with thermodynamically consistent constitutive relations, these balances generate the basic equations of the theory. Keeping in mind applications involving the swelling of polymer networks by liquids, a specialization of the theory is presented and applied to study the influences of mechanical and chemical interactions on equilibrium states and diffusive dynamical processes. It is shown that the possibility of a mechanically induced phase transition is governed by two parameters: the Flory interaction parameter and a parameter given by the product between the number of cross-linked units per unit reference volume and the molecular volume of the liquid molecule. As for diffusion, it is shown that the theory is able to describe the pressure-induced diffusion in swollen membranes.     

Homogenization in finite thermoelasticity

A homogenization framework is developed for the finite thermoelasticity analysis of heterogeneous media. The approach is based on the appropriate identifications of the macroscopic density, internal energy, entropy and thermal dissipation. Thermodynamical consistency that ensures standard thermoelasticity relationships among various macroscopic quantities is enforced through the explicit enforcement of the macroscopic temperature for all evaluations of temperature dependent microscale functionals. This enforcement induces a theoretical split of the accompanying micromechanical boundary value problem into two phases where a mechanical phase imposes the macroscopic deformation and temperature on a test sample while a subsequent purely thermal phase on the resulting deformed configuration imposes the macroscopic temperature gradient. In addition to consistently recovering standard scale transition criteria within this framework, a supplementary dissipation criterion is proposed based on alternative identifications for the macroscopic temperature gradient and heat flux. In order to complete the macroscale implementation of the overall homogenization methodology, methods of determining the constitutive tangents associated with the primary macroscopic variables are discussed. Aspects of the developed framework are demonstrated by numerical investigations on model microstructures.     

Détermination du comportement macroscopique d'un milieu à fissures frottantesDetermination of the macroscopic behavior of a medium with frictional cracks

A micromechanical modeling of closed cracks as flat ellipsoidal inhomogeneities has been recently proposed in [Deudé et al., C. R. Mecanique 330 (2002) 589–599]. The present Note extends this approach to the case of a frictional contact between the crack lips. For von Mises friction, a linear hardening is obtained at the macroscopic scale, the state equation in terms of stress and strain rates being identical to that derived for unfrictional cracks. For Drucker–Prager friction, the micromechanical approach predicts a macroscopic dilatant behavior. To cite this article: J.-F. Barthélémy et al., C. R. Mecanique 331 (2003).     

A homogenized microstructural approach to creep fracture

A two-dimensional nonlocal continuum model is proposed in this paper for creep damage in polycrystalline materials. Starting from previous micromechanical modeling, a heuristic homogenization approach is adopted to derive a theory for the macroscopic response. The model accounts for the main damage mechanisms (grain boundary sliding, nucleation, growth and coalescence of cavities along the grain boundaries) responsible for the creep fracture process. The resulting constitutive law takes into account the nonlocalities expressed through the gradients of the stresses and the damage variables.     

A micromechanical study of drying and carbonation effects in cement-based materials

This paper is devoted to a micromechanical study of mechanical properties of cement-based materials by taking into account effects of water saturation degree and carbonation process. To this end, the cement-based materials are considered as a composite material constituted with a cement matrix and aggregates (inclusions). Further, the cement matrix is seen as a porous medium with a solid phase (CSH) and pores. Using a two-step homogenization procedure, a closed-form micromechanical model is first formulated to describe the basic mechanical behavior of materials. This model is then extended to partially saturated materials in order to account for the effects of water saturation degree on the mechanical properties. Finally, considering the solid phase change and porosity variation related to the carbonation process, the micromechanical model is coupled with the chemical reaction and is able to describe the consequences of carbonation on the macroscopic mechanical properties of material. Some comparisons between numerical results and experimental data are presented.     

利用结构基因法研究非线性周期性板结构的等效力学性能

非线性周期性板结构是一类在智能复合材料领域具有巨大应用潜力的结构,因其构成材料的非线性特性,以及结构中经常包含增强纤维、肋板和空洞等复杂微结构导致的材料几何非线性,利用常规的有限元方法进行建模和分析较为困难.本文提出了一种结构基因法,通过提取非线性周期性板结构的最小模型单元作为其结构基因,将异质周期性板结构等效为均质板结构,便捷地求解了非线性周期性板结构的微观力学性能和整体等效力学性能.算例表明,结构基因方法可用来分析复杂非线性复合材料结构问题,计算结果精度足够,为复合材料微观力学研究提供了有价值的参考.     

A Multiscale Theory of Swelling Porous Media: II. Dual Porosity Models for Consolidation of Clays Incorporating Physicochemical Effects

A three-scale theory of swelling clay soils is developed which incorporates physico-chemical effects and delayed adsorbed water flow during secondary consolidation. Following earlier work, at the microscale the clay platelets and adsorbed water (water between the platelets) are considered as distinct nonoverlaying continua. At the intermediate (meso) scale the clay platelets and the adsorbed water are homogenized in the spirit of hybrid mixture theory, so that, at the mesoscale they may be thought of as two overlaying continua, each having a well defined mass density. Within this framework the swelling pressure is defined thermodynamically and it is shown to govern the effect of physico-chemical forces in a modified Terzaghi's effective stress principle. A homogenization procedure is used to upscale the mesoscale mixture of clay particles and bulk water (water next to the swelling mesoscale particles) to the macroscale. The resultant model is of dual porosity type where the clay particles act as sources/sinks of water to the macroscale bulk phase flow. The dual porosity model can be reduced to a single porosity model with long term memory by using Green's functions. The resultant theory provides a rational basis for some viscoelastic models of secondary consolidation.     

材料细观结构与构件宏观响应间直接关联分析

本文探讨一种用于材料细观结构与构件宏观响应之间的直接关联分析方法。该方法应用宏现计算,给出细观力学量,并可反映材料细观结构特征,适用于具有细观结构材料制成构件的力学分析。     

Micromechanics, macromechanics and constitutive modeling of the elasto-viscoplastic deformation of rubber-toughened glassy polymers

Under certain conditions, such as sufficiently low temperatures, high loading rates and/or highly triaxial stress states, glassy polymers display an unfavorable characteristic—brittleness. A technique used for reducing the brittleness (increasing the fracture toughness) of these materials is rubber toughening. While there is significant qualitative understanding of the mechanical behavior of rubber-toughened polymers, quantitative modeling tools for the large-strain deformation of rubber-toughened glassy polymers are largely lacking.In this paper, we develop a suite of numerical tools to investigate the mechanical behavior of rubber-toughened glassy polymers, with emphasis on rubber-toughened polycarbonate. The rubber particles are modeled as voids in view of their deformation-induced cavitation early during deformation. A three-dimensional micromechanical model of the heterogeneous microstructure is developed to study the effects of initial rubber particle (void) volume fraction on the underlying elasto-viscoplastic deformation mechanisms in the material, and how these mechanisms influence the macroscopic response of the material. A continuum-level constitutive model is developed for the large-strain elasto-viscoplastic deformation of porous glassy polymers, and it is calibrated against micromechanical modeling results for porous polycarbonate. The constitutive model can be used to study various boundary value problems involving rubber-toughened (porous) glassy polymers. As an example, the case of an axisymmetric notched bar is simulated for the case of polycarbonate with varying levels of initial porosity. The quality of the constitutive model calibration is assessed using a multi-scale modeling approach.     

Analysis of Differential Equations Modelling the Reactive Flow through a Deformable System of Cells

A system of model equations coupling fluid flow, deformation of solid structure and chemical reactions is formulated starting from processes in biological tissue. The main aim of this paper is to analyse this non-standard system, where the elasticity modules are functionals of a concentration and the diffusion coefficients of the chemical substances are functions of their concentrations. A new approach and new methods are required and adapted to these nonlinearities and the transmission conditions on the interface solid–fluid. Strong solutions for the initial and boundary value problem are constructed under suitable regularity assumptions on the data, and stability estimates of the solutions with respect to the initial and boundary values are proved. These estimates imply uniqueness directly. The approach of the paper can be used in more general problems modeling reactive flow and transport and its interaction with elastic cell structures. In a forthcoming paper the approach of this paper is used for getting the upscaled system modeling reactive flow through biological tissue on the macroscopic scale, starting from a system on the cell level.     

A micromechanical model for porous materials with a reinforced matrix

In this study a micromechanical model is proposed for ductile porous material whose matrix is reinforced by small inclusions. The solid phase is described by a pressure sensitive plastic model. Based on works of Maghous et al. [6], a macroscopic plastic criterion is firstly obtained by using a two-step homogenization procedure. The effect of porosity at the mesoscale and the influence of inclusions at the microscale are taken into account simultaneously by this criterion. With a non-associated plastic flow rule, the micro-macro model is applied to modeling of mechanical behavior of a cement paste. In particular, we have considered at the microscopic scale the formation of calcite grains by carbonation process in the solid matrix. The studied cement paste is then seen as a reinforced matrix–pore system. Comparisons between numerical results and experimental data show that the proposed model is able to capture the main features of the mechanical behavior of the studied material.     

A MODEL CONSIDERING HYDROSTATIC STRESS OF POROUS NITI SHAPE MEMORY ALLOY

Based on the micromechanical method and thermodynamic theory,a constitutive model for the macroscopic mechanical behavior of porous NiTi shape memory alloy is presented.The hydrostatic stress is considered for porous NiTi according to the transformation function of dense NiTi.The present model takes account of the tensile-compressive asymmetry of NiTi,and can degenerate to model dense material.Numerical calculations,which only need material parameters of dense NiTi,are conducted to investigate the nonlinear and hysteretic strain of porous NiTi,and the predicted results are in good agreement with the corresponding experiments.     

A New Coal-Permeability Model: Internal Swelling Stress and Fracture–Matrix Interaction

We have developed a new coal-permeability model for uniaxial strain and constant confining-stress conditions. The model is unique in that it explicitly considers fracture–matrix interaction during coal-deformation processes and is based on a newly proposed internal swelling stress concept. This concept is used to account for the impact of matrix swelling (or shrinkage) on fracture-aperture changes resulting from partial separation of matrix blocks by fractures that do not completely cut through the whole matrix. The proposed permeability model is evaluated using data from three Valencia Canyon coalbed wells in the San Juan Basin, where increased permeability has been observed during CH₄ gas production, as well as using published data from laboratory tests. Model results are generally in good agreement with observed permeability changes. The importance of fracture–matrix interaction in determining coal permeability, demonstrated in this study using relatively simple stress conditions, underscores the need for a dual-continuum (fracture and matrix) mechanical approach to rigorously capture coal-deformation processes under complex stress conditions, as well as the coupled flow and transport processes in coal seams.     

PLASTIC LIMIT ANALYSIS OF DUCTILE COMPOSITE STRUCTURES FROM MICRO-TO MACRO-MECHANICAL ANALYSIS

The load-bearing capacity of ductile composite structures comprised of periodic composites is studied by a combined micro/macromechanicai approach. Firstly, on the microscopic level, a representative volume element （RVE） is selected to reflect the microstructures of the composite materials and the constituents are assumed to be elastic perfectly-plastic. Based on the homogenization theory and the static limit theorem, an optimization formulation to directly calculate the macroscopic strength domain of the RVE is obtained. The finite element modeling of the static limit analysis is formulated as a nonlinear mathematical programming and solved by the sequential quadratic programming method, where the temperature parameter method is used to construct the self-stress field. Secondly, Hill＇s yield criterion is adopted to connect the micromechanicai and macromechanical analyses. And the limit loads of composite structures are worked out on the macroscopic scale. Finally, some examples and comparisons are shown.     

Macroscale Thermodynamics and the Chemical Potential for Swelling Porous Media

The thermodynamical relations for a two-phase, N-constituent, swelling porous medium are derived using a hybridization of averaging and the mixture-theoretic approach of Bowen. Examples of such media include 2-1 lattice clays and lyophilic polymers. A novel, scalar definition for the macroscale chemical potential for porous media is introduced, and it is shown how the properties of this chemical potential can be derived by slightly expanding the usual Coleman and Noll approach for exploiting the entropy inequality to obtain near-equilibrium results. The relationship between this novel scalar chemical potential and the tensorial chemical potential of Bowen is discussed. The tensorial chemical potential may be discontinuous between the solid and fluid phases at equilibrium; a result in clear contrast to Gibbsian theories. It is shown that the macroscopic scalar chemical potential is completely analogous with the Gibbsian chemical potential. The relation between the two potentials is illustrated in three examples.     

Macroscopic Flow Potentials in Swelling Porous Media

In swelling porous media, the potential for flow is much more than pressure, and derivations for flow equations have yielded a variety of equations. In this article, we show that the macroscopic flow potentials are the electro-chemical potentials of the components of the fluid and that other forms of flow equations, such as those derived through mixture theory or homogenization, are a result of particular forms of the chemical potentials of the species. It is also shown that depending upon whether one is considering the pressure of a liquid in a reservoir in electro-chemical equilibrium with the swelling porous media, or the pressure of the vicinal liquid within the swelling porous media, a critical pressure gradient threshold exists or does not.     

基于新修正偶应力理论的Mindlin层合板热稳定性分析

以新修正偶应力理论为基础,首次提出了机械载荷与热载荷共同作用下的微尺度Mindlin层合板热稳定性模型,该模型只引入一个材料尺度参数,通过虚功原理推导出了控制方程和边界条件,以四边简支方板为例,进行了热稳定性分析,应用纳维叶解法得到解析解。结果表明,所建模型可以捕捉到尺度效应。材料尺度参数值越大,屈曲临界温度越高;当跨厚比增大时,屈曲临界温度下降;随着板几何参数的增大,模型将退化为宏观模型;温度变化量越大,考虑热载荷作用下的屈曲临界载荷越大,尺度效应体现越显著。     

Micromechanical analysis of the behavior of stiff clay

Cementations formed in geological timescale are observed in various stiff clays.A micromechanical stress strain model is developed for modeling the effect of cementation on the deformation behavior of stiff clay.The proposed approach considers explicitly cementations at intercluster contacts,which is different from conventional model.The concept of inter-cluster bonding is introduced to account for an additional cohesion in shear sliding and a higher yield stress in normal compression.A damage law for inter-cluster bonding is proposed at cluster contacts for the debonding process during mechanical loading.The model is used to simulate numerous stress-path tests on Vallericca stiff clay.The applicability of the present model is evaluated through comparisons between the predicted and the measured results.In order to explain the stress-induced anisotropy arising from externally applied load,the evolution of local stresses and local strains at inter-cluster planes are discussed.