Quantum–Classical Correspondence Principle for Heat Distribution in Quantum Brownian Motion

Quantum Brownian motion, described by the Caldeira–Leggett model, brings insights to the understanding of phenomena and essence of quantum thermodynamics, especially the quantum work and heat associated with their classical counterparts. By employing the phase-space formulation approach, we study the heat distribution of a relaxation process in the quantum Brownian motion model. The analytical result of the characteristic function of heat is obtained at any relaxation time with an arbitrary friction coefficient. By taking the classical limit, such a result approaches the heat distribution of the classical Brownian motion described by the Langevin equation, indicating the quantum–classical correspondence principle for heat distribution. We also demonstrate that the fluctuating heat at any relaxation time satisfies the exchange fluctuation theorem of heat and its long-time limit reflects the complete thermalization of the system. Our research study justifies the definition of the quantum fluctuating heat via two-point measurements.     

Quantum corrections for Boltzmann equation

We present the lowest order quantum correction to the semiclassical Boltzmann distribution function, and the equation satisfied by this correction is given. Our equation for the quantum correction is obtained from the conventional quantum Boltzmann equation by explicitly expressing the Planck constant in the gradient approximation, and the quantum Wigner distribution function is expanded in powers of Planck constant, too. The negative quantum correlation in the Wigner distribution function which is just the quantum correction terms is naturally singled out, thus obviating the need for the Husimi’s coarse grain averaging that is usually done to remove the negative quantum part of the Wigner distribution function. We also discuss the classical limit of quantum thermodynamic entropy in the above framework. Supported by the National Natural Science Foundation of China (Grant No. 10404037) and the Scientific Research Fund of GUCAS (Grant No. 055101BM03)     

Towards Nonlinear Quantum Fokker-Planck Equations

It is demonstrated how the equilibrium semiclassical approach of Coffey et al. can be improved to describe more correctly the evolution. As a result a new semiclassical Klein-Kramers equation for the Wigner function is derived, which remains quantum for a free quantum Brownian particle as well. It is transformed to a semiclassical Smoluchowski equation, which leads to our semiclassical generalization of the classical Einstein law of Brownian motion derived before. A possibility is discussed how to extend these semiclassical equations to nonlinear quantum Fokker-Planck equations based on the Fisher information.     

The second law of thermodynamics under unitary evolution and external operations

The von Neumann entropy cannot represent the thermodynamic entropy of equilibrium pure states in isolated quantum systems. The diagonal entropy, which is the Shannon entropy in the energy eigenbasis at each instant of time, is a natural generalization of the von Neumann entropy and applicable to equilibrium pure states. We show that the diagonal entropy is consistent with the second law of thermodynamics upon arbitrary external unitary operations. In terms of the diagonal entropy, thermodynamic irreversibility follows from the facts that quantum trajectories under unitary evolution are restricted by the Hamiltonian dynamics and that the external operation is performed without reference to the microscopic state of the system.     

On the quantum-mechanical Fokker-Planck and Kramers-Chandrasekhar equation

In the classical theory of Brownian motion we can consider the Langevin equation as an infinitesimal transformation between the coordinates and momenta of a Brownian particle, given probabilistically, since the impulse appearing is characterized by a Gaussian random process. This probabilistic infinitesimal transformation generates a streaming on the distribution function, expressed by the classical Fokker-Planck and Kramers-Chandrasekhar equations. If the laws obeyed by the Brownian particle are quantum mechanical, we can reinterpret the Langevin equation as an operator relation expressing an infinitesimal transformation of these operators. Since the impulses are independent of the coordinates and momenta we can think of them as c numbers described by a Gaussian random process. The so resulting infinitesimal operator transformation induces a streaming on the density matrix. We may associate, according to Weyl functions with operators. The function associated with the density matrix is the Wigner function. Expressing, then, these operator relations in terms of these functions we can express the streaming as a continuity equation of the Wigner function. We find that in this parametrization the extra terms which appear are the same as in the classical theory, augmenting the usual Wigner equation.     

从离散Wigner函数的角度探讨量子相干性度量

量子相干性是量子信息处理的基本要素,在量子计算中扮演着重要的角色.为了便于讨论量子相干性在量子计算中的作用,本文从离散Wigner函数角度对量子相干性进行了探讨.首先对奇素数维量子系统的离散Wigner函数进行了分析,分离出表征相干性的部分,提出了一种可能的基于离散Wigner函数的量子相干性度量方法,并对其进行了量子相干性度量规范的分析;同时也比较了该度量与l_1范数相干性度量之间的关系.重要的是,这种度量方法能够明确给出量子相干性程度与衡量量子态量子计算加速能力的负性和之间不等式关系,由此可以解析地解释量子相干性仅是量子计算加速的必要条件.     

A Semiclassical Theory of a Dissipative Henon—Heiles System

A semiclassical theory of a dissipative Henon—Heiles system is proposed. Based on -scaling of an equation for the evolution of the Wigner quasiprobability distribution function in the presence of dissipation and thermal diffusion, we derive a semiclassical equation for quantum fluctuations, governed by the dissipation and the curvature of the classical potential. We show how the initial quantum noise gets amplified by classical chaotic diffusion, which is expressible in terms of a correlation of stochastic fluctuations of the curvature of the potential due to classical chaos, and ultimately settles down to equilibrium under the influence of dissipation. We also establish that there exists a critical limit to the expansion of phase space. The limit is set by chaotic diffusion and dissipation. Our semiclassical analysis is corroborated by numerical simulation of a quantum operator master equation.     

Topological Entanglement Entropy from the Holographic Partition Function

We study the entropy of chiral 2+01-dimensional topological phases, where there are both gapped bulk excitations and gapless edge modes. We show how the entanglement entropy of both types of excitations can be encoded in a single partition function. This partition function is holographic because it can be expressed entirely in terms of the conformal field theory describing the edge modes. We give a general expression for the holographic partition function, and discuss several examples in depth, including abelian and non-abelian fractional quantum Hall states, and $p+ip$ superconductors. We extend these results to include a point contact allowing tunneling between two points on the edge, which causes thermodynamic entropy associated with the point contact to be lost with decreasing temperature. Such a perturbation effectively breaks the system in two, and we can identify the thermodynamic entropy loss with the loss of the edge entanglement entropy. From these results, we obtain a simple interpretation of the non-integer ‘ground state degeneracy’ which is obtained in 1+1-dimensional quantum impurity problems: its logarithm is a 2+1-dimensional topological entanglement entropy.     

The diffusion in the quantum Smoluchowski equation

A novel quantum Smoluchowski dynamics in an external, nonlinear potential has been derived recently. In its original form, this overdamped quantum dynamics is not compatible with the second law of thermodynamics if applied to periodic, but asymmetric ratchet potentials. An improved version of the quantum Smoluchowski equation with a modified diffusion function has been put forward in L. Machura et al. (Phys. Rev. E 70 (2004) 031107) and applied to study quantum Brownian motors in overdamped, arbitrarily shaped ratchet potentials. With this work we prove that the proposed diffusion function, which is assumed to depend (in the limit of strong friction) on the second-order derivative of the potential, is uniquely determined from the validity of the second law of thermodynamics in thermal, undriven equilibrium. Put differently, no approximation-induced quantum Maxwell demon is operating in thermal equilibrium. Furthermore, the leading quantum corrections correctly render the dissipative quantum equilibrium state, which distinctly differs from the corresponding Gibbs state that characterizes the weak (vanishing) coupling limit.     

Covariant Relativistic Statistical Mechanics of Many Particles

In this paper the quantum covariant relativistic dynamics of many bodies is reconsidered. It is emphasized that this is an event dynamics. The events are quantum statistically correlated by the global parameter τ. The derivation of an event Boltzmann equation emphasizes this. It is shown that this Boltzmann equation may be viewed as exact in a dilute event limit ignoring three event correlations. A quantum entropy principle is obtained for the marginal Wigner distribution function. By means of event linking (concatenations) particle properties such as the equation of state may be obtained. We further reconsider the generalized quantum equilibrium ensemble theory and the free event case of the Fermi-Dirac and Bose-Einstein distributions, and some consequences. The ultra-relativistic limit differs from the non-covariant theory and is a test of this point of view.     

The Second Law of Thermodynamics in a Quantum Heat Engine Model

The second law of thermodynamics has been proven by many facts in classical world. Is there any new property of it in quantum world? In this paper, we calculate the change of entropy in T.D. Kieu's model for quantum heat engine (QHE) and prove the broad validity of the second law of thermodynamics. It is shown that the entropy of the quantum heat engine neither decreases in a whole cycle, nor decreases in either stage of the cycle. The second law of thermodynamics still holds in this QHE model. Moreover, although the modified quantum heat engine is capable of extracting more work, its efficiency does not improve at all. It is neither beyond the efficiency of T.D. Kieu's initial model, nor greater than the reversible Carnot efficiency.     

Quantum Moment Hydrodynamics and the Entropy Principle

This paper presents how a non-commutative version of the entropy extremalization principle allows to construct new quantum hydrodynamic models. Our starting point is the moment method, which consists in integrating the quantum Liouville equation with respect to momentum p against a given vector of monomials of p. Like in the classical case, the so-obtained moment system is not closed. Inspired from Levermore's procedure in the classical case,⁽²⁶⁾ we propose to close the moment system by a quantum (Wigner) distribution function which minimizes the entropy subject to the constraint that its moments are given. In contrast to the classical case, the quantum entropy is defined globally (and not locally) as the trace of an operator. Therefore, the relation between the moments and the Lagrange multipliers of the constrained entropy minimization problem becomes nonlocal and the resulting moment system involves nonlocal operators (instead of purely local ones in the classical case). In the present paper, we discuss some practical aspects and consequences of this nonlocal feature.     

Quantum Game with Restricted Matrix Strategies

We study a quantum game played by two players with restricted multiple strategies. It is found that in this restricted quantum game Nash equilibrium does not always exist when the initial state is entangled. At the same time,we find that when Nash equilibrium exists the payoff function is usually different from that in the classical counterpart except in some special cases. This presents an explicit example showing quantum game and classical game may differ.When designing a quantum game with limited strategies, the allowed strategy should be carefully chosen according to the type of initial state.     

Bohmian Trajectories Post-Decoherence

The role of the environment in producing the correct classical limit in the Bohm interpretation of quantum mechanics is investigated, in the context of a model of quantum Brownian motion. One of the effects of the interaction is to produce a rapid approximate diagonalisation of the reduced density matrix in the position representation. This effect is, by itself, insufficient to produce generically quasi-classical behaviour of the Bohmian trajectory. However, it is shown that, if the system particle is initially in an approximate energy eigenstate, then there is a tendency for the Bohmian trajectory to become approximately classical on a longer time-scale. The relationship between this phenomenon and the behaviour of the Wigner function post-decoherence is discussed.     

Quantum Game with Restricted Matrix Strategies

We study a quantum game played by two players with restricted multiple strategies. It is found that in this restricted quantum game Nash equilibrium does not always exist when the initial state is entangled. At the same time,we find that when Nasli equilibrium exists the payoff function is usually different from that in the classical counterpart except in some special cases. This presents an explicit example showing quantum game and classical game may differ.When designing a quantum game with limited strategies, the allowed strategy should be carefully chosen according to the type of initial state.     

量子扩散通道中Wigner算符的演化规律

众所周知,量子态的演化可用与其相应的Wigner函数演化来代替.因为量子态的Wigner函数和量子态的密度矩阵一样,都包含了概率分布和相位等信息,因此对量子态的Wigner函数进行研究,可以更加快速有效地获取量子态在演化过程的重要信息.本文从经典扩散方程出发,利用密度算符的P表示,导出了量子态密度算符的扩散方程.进一步通过引入量子算符的Weyl编序记号,给出了其对应的Weyl量子化方案.另外,借助于密度算符的另一相空间表示-Wigner函数,建立了Wigner算符在扩散通道中演化方程,并给出了其Wigner算符解的形式.本文推导出了Wigner算符在量子扩散通道中的演化规律,即演化过程中任意时刻Wigner算符的形式.在此结论的基础上,讨论了相干态经过量子扩散通道的演化情况.     

Quantum coherent versus classical coherent light

The paper shows that the Wigner distribution function of quantum optical coherent states, or of a superposition of such states, can be produced and measured with a classical optical set-up using classical coherent light fields. This measurement cannot be done directly in quantum optics since the quantum phase space variables correspond to non-commuting operators. As an example, the Wigner distribution function of Schrödinger cat states of light has been measured. It is also shown that the possibility of measuring the Wigner distribution function of quantum coherent states with classical coherent fields is unique in the sense that it cannot be extended to other quantum states, not even to the incoherent limit of the superposition of coherent states.     

Exact master equation for a noncommutative Brownian particle

We derive the Hu-Paz-Zhang master equation for a Brownian particle linearly coupled to a bath of harmonic oscillators on the plane with spatial noncommutativity. The results obtained are exact to all orders in the noncommutative parameter. As a by-product we derive some miscellaneous results such as the equilibrium Wigner distribution for the reservoir of noncommutative oscillators, the weak coupling limit of the master equation and a set of sufficient conditions for strict purity decrease of the Brownian particle. Finally, we consider a high-temperature Ohmic model and obtain an estimate for the time scale of the transition from noncommutative to ordinary quantum mechanics. This scale is considerably smaller than the decoherence scale.     

Microscopic Features of Bosonic Quantum Transport and Entropy Production

The microscopic features of bosonic quantum transport in a nonequilibrium steady state, which breaks time reversal invariance spontaneously, are investigated. The analysis is based on the probability distributions, generated by the correlation functions of the particle current and the entropy production operator. The general approach is applied to an exactly solvable model with a point‐like interaction driving the system away from equilibrium. The quantum fluctuations of the particle current and the entropy production are explicitly evaluated in the zero frequency limit. It is shown that all moments of the entropy production distribution are non‐negative, which provides a microscopic version of the second law of thermodynamics. On this basis a concept of efficiency, taking into account all quantum fluctuations, is proposed and analyzed. The role of the quantum statistics in this context is also discussed.