量子点调制的一维量子波导中声学声子输运和热导

利用散射矩阵方法,比较了被一维凸形量子点、凹形量子点调制的量子线中膨胀模的声子输运和热导性质. 研究结果表明: 声子的输运概率与热导受制于量子点几何结构,具有凸形量子点结构的量子线中声子输运概率与热导K_CV大于具有凹形量子点结构的量子线中声子输运概率与热导K_CC. 两者热导之比K_CV/K_CC依赖于一维量子点的具体结构,且随着温度及主量子线与量子点横截面的边长差Δ_SL的增加而增加. 两种具有不同散射结构的一维量子线中热输运性质的区别在于凸形量子点结构中膨胀模数量总是大于凹形量子点结构中膨胀模数量的缘故. 关键词： 声学声子输运 热导 量子结构     

Spin polarized Kondo transport through a quantum dot connected to ferromagnetic leads

We study the spin dependent transport through a quantum dot connected to ferromagnetic leads. Using the non-equilibrium generalization of the non-crossing approximation for finite Coulomb repulsion U, we compute the spin polarized conductance, the local average occupancies and the local densities of states in the Kondo regime. We show that transport properties are strongly affected if we allow double occupancy by using a finite value for U. In the framework of our model, we have successfully reproduced the recent experimental finding of an electrically controlled magnetic moment on a carbon nanotube quantum dot coupled to ferromagnetic nickel leads [3]. Besides, in addition to the well known splitting of the Kondo peak in the density of states due to the presence of ferromagnetic leads, we find that the additional splitting due to non-zero bias voltage leads to an unexpected increase of the total conductance, which has also been observed by Hauptmann et al.     

Quantum dot light emitting diodes using size-controlled ZnO NPs

The particle size and trap energy level of ZnO were adjusted by varying the concentration of precursors using a sol–gel process, and the energy transport properties of the electron transport layer in quantum dot light-emitting diodes (QD-LEDs) were analyzed. Thus far, no study has considered the efficient electron transport properties of quantum dot light-emitting devices with respect to trap energy levels owing to the oxygen vacancies of ZnO. The particle size and trap energy levels of ZnO were analyzed based on optical properties such as photoluminescence and absorbance. The optimized device showed excellent performance, with a maximum luminance of 50,120 cd/m², a high efficiency of 5.85 cd/A, and a threshold voltage of 2.5 V. The Y-ZnO (yellow photoluminescence ZnO)-based QD-LEDs not only enhanced the injection efficiency of electrons into the emitting layer but also confined the holes in the emitting layer due to the shallow trap level of Y-ZnO, in contrast to the deep trap levels of G-ZnO (green photoluminescence ZnO) and B-ZnO (blue photoluminescence ZnO). Here, we present the first attempt to analyze the electron transport behavior of the electron transport layer of the resulting device.     

Electronic transport through a Majorana bound state coupled to a T-shaped quantum-dot system with Coulomb interaction

Using the Green’s function technique, we respectively investigate the electron transport properties of two spin components through the system of a T-shaped double quantum dot structure coupled to a Majorana bound state, in which only one quantum dot is connected with two metallic leads. We explore the interplay between the Fano effect and the MBSs for different dot-MBS coupling strength λ, dot-dot coupling strength t, and MBS-MBS coupling strength ε_M in the noninteracting case. Then the Coulomb interaction and magnetic field effect on the conductance spectra are investigated. Our results indicate that G_↓(ω) is not affected by the Majorana bound states, but a “0.5” conductance signature occurs in the vicinities of Fermi level of G_↑(ω). This robust property persists for a wide range of dot-dot coupling strength and dot-MBS coupling strength, but it can be destroyed by Coulomb interaction in quantum dots. By adjusting the size and direction of magnetic field around the quantum dots, the “0.5” conductance signature damaged by U can be restored. At last, the spin magnetic moments of two dots by applying external magnetic field are also predicted.     

Transport through a double barrier for interacting quasi one-dimensional electrons in a quantum wire in the presence of a transverse magnetic field

We discuss the Luttinger liquid behaviour of a semiconducting quantum wire. We show that the measured value of the bulk critical exponent, α_bulk, for the tunneling density of states can be easily calculated. Then, the problem of the transport through a quantum dot formed by two quantum point contacts along the quantum wire, weakly coupled to spinless Tomonaga-Luttinger liquids is studied, including the action of a strong transverse magnetic field B. The known magnetic dependent peaks of the conductance, G(B), in the ballistic regime at a very low temperature, T, have to be reflected also in the transport at higher T and in different regimes. The temperature dependence of the maximum G_max of the conductance peak, according to the Correlated Sequential Tunneling theory, yields the power law G_max∝T^{2α end-1}, with the critical exponent, α_end, strongly reduced by B. This behaviour suggests the use of a similar device as a magnetic field modulated transistor.     

Ammonia modification of activated carbon to enhance carbon dioxide adsorption: Effect of pre-oxidation

A commercial granular activated carbon (GAC) was subjected to thermal treatment with ammonia for obtaining an efficient carbon dioxide (CO₂) adsorbent. In general, CO₂ adsorption capacity of activated carbon can be increased by introduction of basic nitrogen functionalities onto the carbon surface. In this work, the effect of oxygen surface groups before introduction of basic nitrogen functionalities to the carbon surface on CO₂ adsorption capacity was investigated. For this purpose two different approaches of ammonia treatment without preliminary oxidation and amination of oxidized samples were studied. Modified carbons were characterized by elemental analysis and Fourier Transform Infrared spectroscopy (FT-IR) to study the impact of changes in surface chemistry and formation of specific surface groups on adsorption properties. The texture of the samples was characterized by conducting N₂ adsorption/desorption at −196 °C. CO₂ capture performance of the samples was investigated using a thermogravimetric analysis (TGA). It was found that in both modification techniques, the presence of nitrogen functionalities on carbon surface generally increased the CO₂ adsorption capacity. The results indicated that oxidation followed by high temperature ammonia treatment (800 °C) considerably enhanced the CO₂ uptake at higher temperatures.     

Transport properties of carbon atomic wire in the environment of H2O molecules: An ab initio study

The transport properties of carbon atomic wire in the environment of H₂O molecules are studied by the non-equilibrium Green function method based on density functional theory. In particular, the carbon wire with seven atoms sandwiched between the Al(1 0 0) electrodes is considered. It is found that the transport properties are sensitive to the variation of the number and the position of the H₂O molecule adsorbed on the carbon wire. To our surprise, with different positions of a single H₂O molecule on the carbon wire, the equilibrium conductance shows an evident odd–even oscillatory behavior. For example, the equilibrium conductance of the carbon wire becomes bigger when the H₂O is adsorbed on the odd-numbered carbon atoms; an opposite conclusion is obtained for the H₂O adsorbed on the even-numbered carbon atoms. For the cases of two H₂O molecules, the equilibrium conductance varies largely and the contribution of the third eigenchannel becomes larger in some special configurations. The calculated current–voltage curves show different behavior with the variation of the positions of the H₂O molecules. In certain cases, large negative differential resistance (NDR) is shown, while in other cases, it only slightly deviates from the linear behavior. The above behavior is analyzed via the charge transfer and the density of states (DOS) and reasonable explanations are presented.     

Transport properties of a double quantum dot molecule in the presence of impurity effects

In this Letter, we studied the electronic transport through a parallel-coupled double quantum dot (DQD) molecule including impurity effects at zero temperature. The linear conductance can be calculated by using the Green's function method. An obvious Fano resonance arising from the impurity state in the quantum dot is observed for the symmetric dot-lead coupling structure in the absence of the magnetic flux through the quantum device. When the magnetic flux is presented, two groups of conductance peaks appear in the linear conductance spectra. Each group is decomposed into one Breit-Wigner and one Fano resonances. Tuning the system parameters, we can control effectively the shapes of these conductance peaks. The Aharonov-Bohm (AB) oscillation for the magnetic flux is also studied. The oscillation period of the linear conductance with π, 2π or 4π may be observed by tuning the interdot tunneling coupling or the dot-impurity coupling strengths.     

Ab initio study of transport properties of an all-carbon molecular switch based on C20 molecule

Choosing closed-ended armchair (5, 5) single-wall carbon nanotubes (CCNTs) as electrodes, we have investigated the electron transport properties across a carbon molecular junction consisting of a C₂₀ molecule sandwiched between two semi-infinite carbon nanotubes. It is shown that the Landauer conductance of this carbon hybrid system can be tuned within several orders of magnitude not only by varying the tube-C₂₀ distance, but more importantly by changing the orientation of the C₂₀ molecule and rotating the C₂₀ molecule or one of the tubes around the symmetry axis of the system at fixed distances. This fact could make this all-carbon molecular system a possible candidate for a nano-electronic switching device. Moreover, our study also reveals that molecular configuration selection and structural relaxation would play an important role in the design of such devices.      

Sulfur doped carbon nitride quantum dots with efficient fluorescent property and their application for bioimaging

Heteroatom doping can drastically alter electronic characteristics of carbon nitride quantum dots, thus resulting in unusual properties and related applications. Herein, we used sulfur as the doping element and investigated the influence of doping on the electronic distribution of carbon nitride and the corresponding fluorescent property. A simple synthetic strategy was applied to prepare sulfur-doped carbon nitride (S-g-C₃N₄) quantum dots through ultrasonic treatment of bulk S-g-C₃N₄. Characterization results demonstrated that the prepared S-g-C₃N₄ quantum dots with an average size of 2.0 nm were successfully prepared. Fluorescent properties indicated that S-g-C₃N₄ quantum dots have an emission peak at 460 nm and cover the emission spectra region up to 550 nm. Furthermore, the fluorescent intensity is greatly increased due to the sonication of bulk S-g-C₃N₄ into quantum dots. As a result, S-g-C₃N₄ quantum dots not only show a blue cell imaging, but have a bright green color. Therefore, S-g-C₃N₄ quantum dot is a promising candidate for bioimaging benefiting from the efficient fluorescent property, good biocompatibility, and low toxicity.     

Proximity effect of electron beam lithography on single-electron transistors

A simple method, based on the proximity effect of electron beam lithography, alleviated by exposing various shapes in the pattern of incident electron exposures with various intensities, was applied to fabricate silicon point-contact devices. The drain current (I _d) of the device oscillates against gate voltage. The electrical characteristics of the single-electron transistor were observed to be consistent with the expected behavior of electron transport through gated quantum dots, up to 150 K. The dependence of the electrical characteristics on the dot size reveals that the I _d oscillation follows from the Coulomb blockade by poly-Si grains in the poly-Si dot. The method of fabrication of this device is completely compatible with complementary metal-oxide-semiconductor technology, raising the possibility of manufacturing large-scale integrated nanoelectronic systems.     

Fano effect of a laterally coupled vertical triple quantum dot system

Using the nonequilibrium Green’s function technique,electron transport through a laterally coupled vertical triple quantum dot is investigated.The conductance as a function of electron energy is numerically calculated.The evolution of the conductance strongly depends on the configuration of dot levels and interdot coupling strengths.     

The equilibrium composition in GexSi1-x/Si self-assembled alloy quantum dot

<正>The equilibrium composition in strained quantum dot is the result of both elastic relaxation and chemical mixing effects,which have a direct relationship to the optical and electronic properties of the quantum-dot-based device.Using the method of moving asymptotes and finite element tools,an efficient technique has been developed to compute the composition profile by minimising the Gibbs free energy in self-assembled alloy quantum dot.In this paper,the composition of dome-shaped Ge_xSi_(1-x)/Si quantum dot is optimized,and the contribution of the different energy to equilibrium composition is discussed.The effect of composition on the critical size for shape transition of pyramid-shaped GeSi quantum dot is also studied.     

First-principles study for transport properties of defective carbon nanotubes with oxygen adsorption

Oxygen gas usually presents in carbon nanotube (CNT) based devices and can affect their transport properties. Here, we perform simulations for O₂ adsorption on a (5, 5) CNT with a double vacancy. We first use first-principles plane-wave calculation to optimize the structures and then use single-particle Green function method to study their transport properties. It is found that an O₂ can be either physisorbed or chemisorbed on the defective CNT. The physisorption has only minor effects on the transport while the chemisorption can improve it and the resulting conductance is affected by the orientation of the O₂ bonding.     

Non-Equilibrium Quantum Transport of Bosons through a Quantum Dot

The quantum dot coupled to reservoirs is known as a typical mesoscopic setup to manifest the quantum characteristics of particles in transport. In analogue to many efforts made on the study of electronic quantum dots in the past decades, we study the transport of bosons through such a device. We first generalize the formula which relates the current to the local properties of dot in the bosonic situation. Then, as an illustrative example, we calculate the local density of state and lesser Green function of the localized boson with a bosonic Fano-Anderson model. The current-voltage （I - V） behaviour at zero temperature is presented, and in the bosonic dot it is the I - V curve, in contrast to the differential conductance in the electronic dot, which is found to be proportional to the spectral function.     

Evidence for charging effects in an open dot at zero magnetic field

We have measured the low-temperature transport properties of an open quantum dot formed in a clean one-dimensional channel. At zero magnetic field, continuous and periodic oscillations superimposed upon ballistic conductance steps are observed when the conductance through the dot G exceeds 2e²/h. We ascribe the observed conductance oscillations to evidence for charging effects in an open dot. This is supported by the evolution of the oscillating features for G>2e²/h as a function of both temperature and barrier transparency.     

Transport in fullerene device coupled to Cu,Ag and Au electrodes

We present an ab initio approach of the electronic transport through a single molecular junction based on C₂₀ fullerene. The electronic properties of a single molecular junction constrained within two semi-infinite metallic electrodes are largely affected by the choice of electrode material. The two-probe device formed by the mechanically control break technique has been modelled with three distinct electrode materials from group IB of the periodic table, namely copper, silver and gold. The quantum characteristics of these mechanically stable devices are obtained by utilising first-principle density functional theory together with non-equilibrium green function method. We evaluate the quantum characteristics, namely density of states, transmission spectrum, energy levels, current and conductance, which essentially determine the behaviour of a molecule linked to different electrodes. Our investigation concludes that copper, silver and gold electrode configuration in conjunction with C₂₀ fullerene behaves as metallic, non-metallic and semi-metallic in nature, respectively.     

Transport through artificial single-molecule magnets: Spin-pair state sequential tunneling and Kondo effects

The transport properties of an artificial single-molecule magnet based on a CdTe quantum dot doped with a single Mn+2 ion(S=5/2) are investigated by the non-equilibrium Green function method.We consider a minimal model where the Mn-hole exchange coupling is strongly anisotropic so that spin-flip is suppressed and the impurity spin S and a hole spin s entering the quantum dot are coupled into spin pair states with(2S+1) sublevels.In the sequential tunneling regime,the differential conductance exhibits(2S+1) possible peaks,corresponding to resonance tunneling via(2S+1) sublevels.At low temperature,Kondo physics dominates transport and(2S+1) Kondo peaks occur in the local density of states and conductance.These peaks originate from the spin-singlet state formed by the holes in the leads and on the dot via higher-order processes and are related to the parallel and antiparallel spin pair states.     

A spin switch device based on a triple quantum dots superlattice using the Dicke effect

Spin-dependent transport in a triple quantum dots superlattice system with a bridge coupling to two leads is studied. There exists an odd-even parity oscillation of spin polarization at the central dot level εc = 0 due to the spin-dependent Fano and Dicke effects induced by the quantum interference and the Rashba spin-orbit interaction. In the case of even numbers of triple quantum dots, the device can be used as a spin switch by tuning the energy difference h between the energies of the central and the lateral dots. These results may be helpful to design and fabricate practical spintronic devices.     

Spin-flip effects in a parallel-coupled double quantum dot molecule

We investigate theoretically the electronic transport through a parallel-coupled double quantum dot (DQD) molecule attached to metallic electrodes, in which the spin-flip scattering on each quantum dot is considered. Special attention is paid to the effects of the intradot spin-flip processes on the linear conductance by using the equation of motion approach for Green’s functions. When a weak spin-flip scattering on each quantum dot is present, the single Fano peak splits into two Fano peaks, and the Breit–Wigner resonance may be suppressed slightly. When the spin-flip scattering strength on each quantum dot becomes strong, the linear conductance spectrum consists of two Breit–Wigner peaks and two Fano peaks due to the quantum interference effects. The positions and shapes of these resonant peaks can be controlled by using the magnetic flux through the quantum device.