Pump tuned wide tunable noncritically phase-matched ZnGeP2 narrow line width optical parametric oscillator

A line tunable singly resonant noncritically phase matched narrow band width ZnGeP₂ (ZGP) optical parametric oscillator pumped by the output idler radiation from a KTA OPO based on a 20 mm long KTA crystal pumped from a Q-switched Gaussian shaped Nd:YAG laser beam with a grating having grooves density 85 lines/mm has been demonstrated in the spectral ranges of 3–7 μm. The measured threshold of oscillation energy was 10 μJ. The conversion efficiency was 20.5% and slope efficiency of the ZGP OPO was 20% using a 23 mm long ZGP crystal at 26 mm cavity length. Line width of the generated infrared radiation from ZGP OPO was 37–60 nm.     

High-power eye-safe KTA-OPO driven by YVO4/Nd:YVO4 composite laser

We present a high-power 1.53 μm laser based on intracavity KTA-OPO driven by diode-end-pumped acousto-optical Q-switched YVO₄/Nd:YVO₄ composite. The composite crystal was utilized for reducing the thermal effect, and the mode mismatch compensating OPO cavity was designed for efficient OPO conversion. The output power of eye-safe laser at 1535 nm was up to 4.4 W with the pump power of 27 W, corresponding to a diode-to-signal conversion efficiency of 16.3%. To our knowledge, this is the highest output power in diode-end-pumped circumstances. In the experiment, the strong yellow light generated by Raman conversion and frequency doubling in the KTA crystal was observed.     

Diode-pumped actively Q-switched Nd:GGG laser operating at 938 nm

The stimulated emission cross-section of Nd:GGG crystal in 938 nm transition was measured by the amplifier approach. It is 2.3×10^?20 cm². A quasi-continuous-wave diode pumped, actively Q-switched Nd:GGG laser operating at 938 nm was demonstrated. Pumped by laser diodes with 900 W peak power and 300 μs pulse duration, it generated 168 mJ energy in long pulse mode. The slope efficiency was 36%. Q-switched by a KD?P Pockels cell, 41 mJ output pulse energy was obtained. The pulse duration and peak power were 120 ns and 340 kW, respectively. The optical to optical efficiency was 7%.     

60 W yellow laser at 561 nm by intracavity frequency doubling of a diode-pumped Q-switched Nd:YAG laser

A high-power yellow laser was achieved by intracavity frequency doubling of a diode-pumped Nd:YAG rod laser. A solid etalon was inserted into the resonator to implement efficient operation of the low-gain single line at 1123 nm transition. By using a LBO crystal inside the cavity as the frequency doubler, the maximum output power of the 561 nm yellow laser was obtained to be as high as 60.3 W with a pulse repetition frequency of 6 kHz, corresponding to an optical-to-optical conversion efficiency of about 6.1%. The output power fluctuation of the yellow laser was measured to be better than 3% in half an hour.     

Cr4+:YAG passively Q-switched c-cut Nd:YVO4 self-Raman laser at 1168.6 nm

We demonstrate the first Cr⁴⁺:YAG passively Q-switched c-cut Nd:YVO₄ self-Raman laser at 1168.6 nm based on the Stokes shift of 816 cm⁻¹. At the pump power of 4.7 W, the maximum output power of the Stokes line at 1168.6 nm is 270.5 mW, corresponding to an optical conversion efficiency of 5.8%. The pulse width, pulse repetition rate, pulse energy and peak power are 8.8 ns, 35.8 kHz, 7.6 μJ and 0.86 kW, respectively. At the pump of 5.0 W, the Stokes line at 1097.2 nm based on Raman shift of 259 cm⁻¹ also appears.     

Continuous-wave 560 nm light generated by intracavity SrWO4 Raman and KTP sum-frequency mixing

An LD end-pumped Nd:YAG/SrWO₄ continuous-wave 560 nm laser is presented based on intracavity sum-frequency mixing of the fundamental and first-Strokes light. The maximum output power of 330 mW at 559.6 nm was obtained for the diode pump power of 13.7 W and the conversion efficiency was about 2.5%. The intense blue emission was also observed in the SrWO₄ crystal when the Raman laser was operating above threshold. This blue emission is centered at 473 nm, which also happened to YVO₄.     

An eye-safe KTiAsO4 intracavity optical parametric oscillator driven by a diode pumped composite Nd:YAG/Cr4+:YAG laser

A mini eye-safe KTiAsO₄ intracavity optical parametric oscillator (IOPO) employing the shared cavity configuration and driven by a diode-end-pumped composite Nd:YAG/Cr⁴⁺:YAG laser is demonstrated in this paper. Under an incident laser diode power of 11 W, a maximum average output power of 424 mW at 1534 nm was obtained. The corresponding signal pulse width and repetition rate were 1.2 ns and 16.7 kHz, respectively. The fluctuation of the average signal output power over long-term operation was found to be ±3.0%. A theoretical model for the compact IOPO was also presented in this paper.     

YAG laser-induced β-BaB2O4 crystalline dot formation in Sm2O3–BaO–B2O3 glasses

A continuous-wave (CW) YAG laser (power: 0.75–0.9 J/s, irradiation time: 15 s–15 min) with a wavelength of 1064 nm is irradiated to 11.1Sm₂O₃·44.4BaO·44.4B₂O₃ glass, and the formation of β-BaB₂O₄ (β-BBO) crystalline dots with a diameter of 30–150 μm is confirmed from micro-Raman spectra. β-BBO crystals with around 200 μm length grow towards the interior of the glass. The incorporation of Sm³⁺ into β-BBO crystalline dots is suggested from micro-Raman and fluorescence spectra. The second harmonic generation is detected from the array (10×10=100 dots) of β-BBO crystalline dots, indicating that each crystalline dot formed by YAG laser irradiation is a nonlinear optical crystal. CW YAG laser irradiation to glass with Sm³⁺ ions is a nice technique for a spatially controlled crystal growth.     

Passively Q-switched a-cut Nd:GdVO4 self-Raman laser with Cr:YAG

A passively Q-switched a-cut Nd:GdVO₄ self-Raman solid-state laser with Cr:YAG saturable absorber was firstly demonstrated. The first Stokes at 1173 nm was successfully obtained. At the maximum incident pump power, the pulse width was about 1.8 ns and the repetition rate was 27.5 kHz. 586.5 nm yellow laser output was also realized by use of an LBO frequency doubling crystal.     

Growth and characterization of pure and doped bis thiourea zinc acetate: Semiorganic nonlinear optical single crystals

Metal–organic coordination complex single crystals bis thiourea zinc acetate (BTZA) and Cd²⁺ doped BTZA have been synthesized and grown successfully by slow-cooling technique from their aqueous solutions. Single crystals of pure and Cd²⁺ doped BTZA with dimensions of 35 × 4 × 2 mm³ and 10 × 5 × 6 mm³, respectively were obtained with well defined morphology. The as grown single crystals are characterized by single crystal XRD studies and melting point measurements which reveal the incorporation of metallic dopants has not changed the structure of the parent crystal. The powder X-ray diffractogram of the grown crystals has been recorded and the various planes of reflection identified shows shift in the peak positions. The metal coordination with thiourea through sulphur in pure and Cd²⁺ doped BTZA were ascertained by FTIR studies and optical absorption study to identify the UV cut-off range. The presence of metals in pure and Cd²⁺ doped BTZA crystal lattice were confirmed by atomic absorption spectroscopy (AAS). The thermal decomposition of pure and Cd²⁺ doped BTZA crystals were investigated by thermo gravimetric analyses (TGA) and differential thermal analysis (DTA) indicate that doped crystals are more stable than pure crystals. The dielectric response of the crystals were studied in the frequency range 100 Hz–5 MHz at different temperatures and the results are discussed. Second harmonic generation (SHG) measurement confirms that the pure and Cd²⁺ doped BTZA have nonlinear optical (NLO) property. Laser damage threshold value of 12.44 MW/cm² has been determined using Q-switched Nd:YAG laser operating at 1064 nm and with 8 ns pulses in single shot mode for pure BTZA single crystal is reported for the first time.     

Tunable single-longitudinal-mode operation of a sandwich-type YAG/Ho:YAG/YAG ceramic laser

We present a 2.09 μm single-longitudinal-mode sandwich-type YAG/Ho:YAG/YAG ceramic laser pumped by a Tm-doped fiber laser for the first time. A pair of F-P etalons was used to achieve tunable single-longitudinal-mode operation. The maximum single-longitudinal-mode output power of 530 mW at 2091.4 nm was obtained with an absorbed pump power of 8.06 W, corresponding to an optical conversion efficiency of 6.6% and a slope efficiency of 12.7%. Wavelength tunable was achieved by tuning the angle of etalons and the wavelength could be tuned from 2091.1 nm to 2092.1 nm, corresponding to a tuning frequency of 68 GHz. The M² factor was measured to be 1.23.     

High-peak-power,short-pulse-width,LD end-pumped,passively Q-switched Nd:YAG 946 nm laser

High-peak-power, short-pulse-width diode pumped 946 nm Nd:YAG laser in passively Q-switching operation with Cr⁴⁺:YAG is reported. The highest average output power reaches 3.4 W using the Cr⁴⁺:YAG with initial transmissivity T₀=95%. When the T₀=90% Cr⁴⁺:YAG is employed, the maximum peak power of 31.4 kW with a pulse width of 8.3 ns at 946 nm is generated.     

A method for rapid measurement of laser ablation rate of hard dental tissue

The aim of the study reported here is the development of a new method which allows rapid and accurate in-vitro measurements of three-dimensional (3D) shape of laser ablated craters in hard dental tissues and the determination of crater volume, ablation rate and speed. The method is based on the optical triangulation principle. A laser sheet projector illuminates the surface of a tooth, mounted on a linear translation stage. As the tooth is moved by the translation stage a fast digital video camera captures series of images of the illuminated surface. The images are analyzed to determine a 3D model of the surface. Custom software is employed to analyze the 3D model and to determine the volume of the ablated craters. Key characteristics of the method are discussed as well as some practical aspects pertinent to its use. The method has been employed in an in-vitro study to examine the ablation rates and speeds of the two main laser types currently employed in dentistry, Er:YAG and Er,Cr:YSGG. Ten samples of extracted human molar teeth were irradiated with laser pulse energies from 80 mJ to the maximum available energy (970 mJ with the Er:YAG, and 260 mJ with the Er,Cr:YSGG). About 2000 images of each ablated tooth surface have been acquired along a translation range of 10 mm, taking about 10 s and providing close to 1 million surface measurement points. Volumes of 170 ablated craters (half of them in dentine and the other half in enamel) were determined from this data and used to examine the ablated volume per pulse energy and ablation speed. The results show that, under the same conditions, the ablated volume per pulse energy achieved by the Er:YAG laser exceeds that of the Er,Cr:YSGG laser in almost all regimes for dentine and enamel. The maximum Er:YAG laser ablation speeds (1.2 mm³/s in dentine and 0.7 mm³/s in enamel) exceed those obtained by the Er,Cr:YSGG laser (0.39 mm³/s in dentine and 0.12 mm³/s in enamel). Since the presented method proves to be easy to use and allows quite rapid measurements it may become a valuable tool to study the influence of various laser parameters on the outcome of laser ablation of dental tissues.     

LD-end-pumped passively Q-switched Nd:YAG ceramic laser with single wall carbon nanotube saturable absorber

We report on a LD-end-pumped passively Q-switched Nd:YAG ceramic laser by using a novel single wall carbon nanotube saturable absorber (SWCNT-SA). The SWCNT wafer was fabricated by electric Arc discharge method on quartz substrate with absorption wavelength of 1064 nm. We firstly investigated the continuous wave (CW) laser performance and scattering properties of Nd:YAG ceramic sample. For the case of passively Q-switched operation, a maximum output power of 376 mW was obtained at an incident pump power of 8.68 W at 808 nm, corresponding to an optical–optical conversion efficiency of 4.3%. The repetition rate as the increase of pump power varied from 14 to 95 kHz. The minimum pulse duration of 1.2 μs and maximum pulse energy of 4.5 μJ was generated at a repetition rate of 31.8 kHz.     

Passively Q-switched diode-pumped Raman laser with third-order Stokes eye-safe oscillation

We demonstrate a passively Q-switched all-solid-state laser system with intracavity Raman frequency conversion to the eye-safe spectral region. Laser oscillation at the 1.064 μm wavelength with a pulse repetition rate of several kilohertz was provided by a Nd:YAG crystal and a Cr:YAG passive absorber. Third Stokes oscillations at the 1.599 and 1.494 μm wavelengths were obtained in Ba(NO₃)₂ and PbWO₄ crystals with output pulse energies of 5 μJ and 6 μJ, respectively. The results of the numerical simulation of the pulse dynamics are in good agreement with the experimental data.     

Growth,structural, optical and mechanical studies on acid mixed glycine metal salt (GABN) crystal as potential NLO material

Transparent crystals of α-glycine with ammonium nitrate and barium nitrate (GABN) have been grown from aqueous solution by slow evaporation technique at room temperature. Crystals of size 11 × 7 × 4 mm³ have been obtained in about 3–4 weeks time. The solubility of GABN has been determined in water. The grown crystal belongs to orthorhombic system with cell parameters a = 7.317 A.U, b = 12.154 A.U and c = 5.468 A.U with a unit cell volume 486.35 (A.U)³. The presence of chemical components/groups has been identified by CHN, EDAX and NMR analysis. Comparative IR and Raman studies indicate a molecule with a lack of centre of symmetry. A wide transparency window useful for optoelectronic applications is indicated by the UV Studies. Using a Nd-YAG laser (1064 nm), the optical second harmonic generation (SHG) conversion efficiency of GABN is found to be 1.406 times of that of standard KDP. On exposure to light the GABN crystals are found to exhibit negative photoconductivity. I–V characteristics, SEM studies, dielectrics studies, and Vickers micro hardness measurement have been carried out.     

Diode-pumped Nd:YAG ceramic laser at 946 nm passively Q-switched with a Cr4+:YAG saturable absorber

We demonstrate a diode-pumped Nd:YAG ceramic laser with emission at 946 nm that is passively Q-switched by single-crystal Cr⁴⁺:YAG saturable absorber. An average output power of 1.7 W is measured under 18.4 W of incident power using an output mirror with transmission T=4%. The corresponding optical-to-optical efficiency is 9.2%. The laser runs at a pulse repetition rate of 120 kHz and delivers pulses with energy of 14 μJ and duration of 80 ns, which corresponds to a peak power of 175 W.     

Improvement in solar-pumped Nd:YAG laser beam brightness

Solar-pumped solid-state lasers are promising for renewable extreme-temperature material processing. Here we report a large improvement in solar laser beam brightness by pumping a thin Nd:YAG single crystal rod. A fused silica light guide of 14 mm×22 mm rectangular cross-section is used to both transmit and homogenize the concentrated solar radiation from the focal zone of a 2.88 m² parabolic mirror to the entrance aperture of a modified 2D-CPC flooded pump cavity, within which a 4 mm diameter rod is efficiently pumped. 2.2% slope efficiency is reached. Laser beam brightness figure of merit B is three times higher than that of the most recent solar-pumped Nd:YAG laser by a Fresnel lens. The introduction of the rectangular cross-section light guide has also ensured a much more stable laser emission than previous pumping schemes.     

High-power sixth-harmonic generation of an Nd:YAG laser with KBe2BO3F2 prism-coupled devices

High-power sixth harmonic generation from an Nd:YAG laser (10 ns, 10 kHz) has been achieved with a KBe₂BO₃F₂ (KBBF) prism-coupled device (PCD) containing a 1.95 mm thick KBBF crystal. The highest output power reached 120.5 mW at 177.3 nm, and the highest conversion efficiency from 354.7 to 177.3 nm was 1.82%. Moreover, stable sixth harmonic output with an average power of 22.2 mW was produced by another KBBF-PCD, in which the thickness of the KBBF crystal was 1.51 mm. The highest and stable sixth harmonic output powers are improved by about three and six times compared with the previously published results, respectively.     

Investigation of different surface morphologies formed on AISI 304 stainless steel via millisecond Nd:YAG pulsed laser oxidation

Different surface morphologies on AISI 304 stainless steel have been obtained after millisecond Nd:YAG pulsed laser oxidation. The effects of laser processing parameters, especially pulse width and laser energy density on the surface morphologies of the stainless steel were emphatically investigated. The results showed that surface morphologies were significantly changed with increasing laser pulse widths and laser energy densities. When the pulse width was 0.2–1.0 ms and laser energy density was 4.30×10⁶–7.00×10⁶ J/m², the surface was obviously damaged and the morphologies varied gradually from craters to ripple structures. However, when the pulse width was longer than 1 ms and the laser energy density was increased from 1.90×10⁷ to 3.16×10⁷ J/m², the sizes of craters got smaller until disappeared and the surface became flatter and smoother. Nevertheless, the smooth surface was not obtained under overhigh laser energy densities. In addition, the schematic relationship was used to describe the formation process and mechanism of different surface morphologies.