Effect of impact breakup of solid and liquid particles on two-phase supersonic flow about solids

Experimental modeling of processes occurring when a supersonic gaseous suspension containing solid or liquid particles flows about a freely flying body is carried out. Considered is the situation when the particles reach the surface of the body intact and are not entrained by the flow. It is found that, after the particles break into pieces and disperse, exchange between the phases intensifies, causing a change in the position of the bow shock wave and the formation of a layer with an increased concentration of the particles. Collisions of solid and liquid particles with the solid surface are modeled. The observation of the particle dispersion pattern after impact breakup and measurement of the particle velocity shed light upon a mechanism behind the formation and movement of a finely dispersed particle cloud that arises when initial particles experience impact breakup. It is found that the postcollision dispersion of the particles generates two shock waves originating from the interaction zone.     

Behavior of aluminum near an ultimate theoretical strength in experiments with femtosecond laser pulses

The dynamics of the motion of the free surface of micron and submicron films under the action of a compression pulse excited in the process of femtosecond laser heating of the surface layer of a target has been investigated by femtosecond interferometric microscopy. The relation between the velocity of the shock wave and the particle velocity behind its front indicates the shock compression to 9–13 GPa is elastic in this duration range. This is also confirmed by the small (≤1 ps) time of an increase in the parameters in the shock wave. Shear stresses reached in this process are close to their estimated ultimate values for aluminum. The spall strength determined at a strain rate of 10⁹ s⁻¹ and a spall thickness of 250–300 nm is larger than half the ultimate strength of aluminum.     

炸药爆炸作用下液体破碎后颗粒尺寸分布的研究

 对液体抛撒的液滴尺寸进行研究在军事和民用上是很重要的,国内刚开始使用激光散射仪开展此项研究工作。利用R. A. Dobbins等人的液体颗粒测量技术,研制了一套既简单又实用的测量液体抛撒过程中液滴尺寸的实验装置——激光散射仪。对于激光与液体微粒的相互作用,当微粒的反射与折射和吸收效应可被忽略时,可导出液体微粒对激光散射的光强公式。只要测量激光被微粒散射的光强,就可推算出微粒的Sauter平均直径。在使用激光散射仪测量液体抛撒液滴尺寸的实验中,用水代替爆炸抛撒液体,测量结果表明：液体抛撒二次破碎中,在固定位置测量到的云雾区液滴Sauter平均直径随测量时间的增加呈现出减小的趋势;而云雾区的宽度则随着与抛撒中心距离的增大而呈现出增加的趋势;云雾区前沿的液滴Sauter平均直径随着与抛撒中心距离的增加而呈现出先逐渐增大然后迅速减小的趋势。为便于比较,对燃料抛撒二次破碎进行了回收法测量和数值模拟计算,其测量与计算结果与用激光散射仪测量的结果有较好的一致性。     

Growth fusion of submicron spherical boron carbide particles by repetitive pulsed laser irradiation in liquid media

We studied the fabrication of B₄C submicron particles by laser irradiation of boron nanoparticles dispersed in an organic solvent. The spherical shape of the formed particles suggests that instantaneous melt formation and solidification by quenching are involved in the particle-forming process. B₄C particles gradually became larger with irradiation time at relatively low laser fluence (1.5 J cm⁻² pulse⁻¹) by repetitive melting and fusion of the particles, and the B₄C yield increased with irradiation time to 90% for 600 min of irradiation. At higher laser fluences, the B₄C yield decreased due to the explosive ablation of boron or B₄C to form H₃BO₃, and thus only the larger B₄C particles were observed. The dielectric constant of the organic solvent also affected the generated B₄C particle size, probably due to the degree of particle aggregation. Thus, this technique can provide a new approach for fabricating spherical submicron particles of ceramic materials, such as carbides, with simple and safe processes.     

Heat release of carbon particle formation from hydrogen-free precursors behind shock waves

The process of heat release during carbon particle formation and growth after pyrolysis of carbon suboxide C₃O₂ behind shock waves was investigated. For this goal, temperature and optical density of gas-particle mixtures initially consisting of 3% C₃O₂ + 5% CO₂ in Ar were measured as a function of time. The temperature was determined by two-channel emission-absorption spectroscopy at λ = 2.7 ± 0.4 μm, corresponding to the CO₂ (1,0,1) vibrational band. In the range of initial temperatures behind the shock waves from 1600 up to 2200 K a significant heating of the mixture during particle formation and growth was observed that increased towards higher temperatures. The analysis of the obtained data in combination with previous results about the temperature dependence of the particle size shows a decrease of the heat release of condensation from ∼200 kJ/mol per atom for particles containing ∼1000 atoms to ∼50 kJ/mol per atom for particle containing ∼10⁶ atoms.     

Nanoparticle production by UV irradiation of combustion generated soot particles

Laser ablation of surfaces normally produce high temperature plasmas that are difficult to control. By irradiating small particles in the gas phase, we can better control the size and concentration of the resulting particles when different materials are photofragmented. Here, we irradiate soot with 193 nm light from an ArF excimer laser. Irradiating the original agglomerated particles at fluences ranging from 0.07 to 0.26 J/cm² with repetition rates of 20 and 100 Hz produces a large number of small, unagglomerated particles, and a smaller number of spherical agglomerated particles. Mean particle diameters from 20 to 50 nm are produced from soot originally having a mean electric mobility diameter of 265 nm. We use a non-dimensional parameter, called the photon–atom ratio (PAR), to aid in understanding the photofragmentation process. This parameter is the ratio of the number of photons striking the soot particles to the number of the carbon atoms contained in the soot particles, and is a better metric than the laser fluence for analyzing laser–particle interactions. These results suggest that UV photofragmentation can be effective in controlling particle size and morphology, and can be a useful diagnostic for studying elements of the laser ablation process.     

Particle agglomeration and properties of nanofluids

The present study demonstrates the importance of actual agglomerated particle size in the nanofluid and its effect on the fluid properties. The current work deals with 5 to 100 nm nanoparticles dispersed in fluids that resulted in 200 to 800 nm agglomerates. Particle size distributions for a range of nanofluids are measured by dynamic light scattering (DLS). Wet scanning electron microscopy method is used to visualize agglomerated particles in the dispersed state and to confirm particle size measurements by DLS. Our results show that a combination of base fluid chemistry and nanoparticle type is very important to create stable nanofluids. Several nanofluids resulted in stable state without any stabilizers, but in the long term had agglomerations of 250 % over a 2 month period. The effects of agglomeration on the thermal and rheological properties are presented for several types of nanoparticle and base fluid chemistries. Despite using nanodiamond particles with high thermal conductivity and a very sensitive laser flash thermal conductivity measurement technique, no anomalous increases of thermal conductivity was measured. The thermal conductivity increases of nanofluid with the particle concentration are as those predicted by Maxwell and Bruggeman models. The level of agglomeration of nanoparticles hardly influenced the thermal conductivity of the nanofluid. The viscosity of nanofluids increased strongly as the concentration of particle is increased; it displays shear thinning and is a strong function of the level of agglomeration. The viscosity increase is significantly above of that predicted by the Einstein model even for very small concentration of nanoparticles.     

Particle Size of Pneumatically Conveyed Powders Measured Using Impact Duration

CSIRO Minerals has developed a technique for measuring particle size in pneumatically conveyed powders [1] by measurement of the acoustic waves produced by particle impacts upon a specially designed transducer. Previous work has focused on using the peak acoustic wave amplitude to determine particle size. This produces a spectrum that is hard to determine the particle size from, as the peak amplitude is a non‐linear function of particle diameter, and is strongly affected by angle of incidence and velocity of the impacting particle. In this paper impact duration measurements are used to overcome these difficulties while retaining the advantages of being able to measure in high solids loadings of up to at least 0.5 kg/m³ of powder. In laboratory tests the impact size monitor's (ISM) results have been correlated with optical diffraction measurements of the mean (by number) powder size with a correlation coefficient of 0.985 and a relative error of 5.5 %. The ISM operated successfully in the laboratory at a loading of 0.5 kg/m³ of powder and measured particles down to 50 microns in size.     

Synthesis and properties of submicron range CaSO4:Eu particles

CaSO₄:Eu with particle size in submicron range was synthesized. Radiation induced Eu³⁺↔Eu²⁺ conversion as well as thermal conversion was studied. The samples showed thermal conversion above 400 °C. However, no radiation induced conversion in submicron range particles was observed. Particles heated above 400 °C coalesce and when heated at 925 °C bigger particles of 20 μm size were formed. Optical microscopy of these particles reveals red inclusion of about 5 μm inside CaSO₄ particle. It is speculated that the red inclusion is CaS:Eu²⁺.     

Acoustic emission monitoring during laser shock cleaning of silicon wafers

A laser shock cleaning is a new dry cleaning methodology for the effective removal of submicron sized particles from solid surfaces. This technique uses a plasma shock wave produced by laser-induced air breakdown, which has applied to remove nano-scale silica particles from silicon wafer surfaces in this work. In order to characterize the laser shock cleaning process, acoustic waves generated during the shock process are measured in real time by a wide-band microphone and analyzed in the change of process parameters such as laser power density and gas species. It was found that the acoustic intensity is closely correlated with the shock wave intensity. From acoustic analysis, it is seen that acoustic intensity became stronger as incident laser power density increased. In addition, Ar gas has been found to be more effective to enhance the acoustic intensity, which allows higher cleaning performance compared with air or N₂ gas.     

A Survey of Complementary Methods for the Characterization of Dense Colloidal Silica

The aim of this study is to enhance existing knowledge of different techniques developed for the characterization of stability and particle sizing of nanoparticles in dense dispersions subjected to interparticulate and hydrodynamic forces. Silica suspension, commercially known as Klebosol^® 30R50 and consisting of a particle size of 80 nm on average, was investigated in the study over a wide range of concentrations. The investigations were carried out using different optical and acoustic techniques such as laser diffraction, multiple light scattering, photon correlation spectroscopy and acoustic spectroscopy. The study details the capabilities and limitations of these modern techniques based on the different physical principles behind the characterization of the size distribution of particles in suspensions. The results are presented in terms of particle size ranges, solid concentration and technological aspects such as online and offline analysis. An important finding is that many of these modern techniques need to be improved for applications at higher concentrations since the standard models become practically invalid because of the complex interaction of acoustic and optical waves with particles in suspensions of silica.     

A Correlative Analysis of Gold Nanoparticles Internalized by A549 Cells

Fluorescently labeled nanoparticles are widely used to investigate nanoparticle cell interactions by fluorescence microscopy. Owing to limited lateral and axial resolution, nanostructures (<100 nm) cannot be resolved by conventional light micro­scopy techniques. Especially after uptake into cells, a common fate of the fluorescence label and the particle core cannot be taken for granted. In this study, a correlative approach is presented to image fluorescently labeled gold nanoparticles inside whole cells by correlative light and electron microscopy (CLEM). This approach allows for detection of the fluorescently labeled particle shell as well as for the gold core in one sample. In this setup, A549 cells are exposed to 8 nm Atto 647N‐labeled gold nanoparticles (3.3 × 10⁹ particles mL^?1, 0.02 μg Au mL^?1) for 5 h and are subsequently imaged by confocal laser scanning microscopy (CLSM) and transmission electron microscopy (TEM). Eight fluorescence signals located at different intracellular positions are further analyzed by TEM. Five of the eight fluorescence spots are correlated with isolated or agglomerated gold nanoparticles. Three fluorescence signals could not be related to the presence of gold, indicating a loss of the particle shell.     

An IH-QCL based gas sensor for simultaneous detection of methane and acetylene

Extended wavelength tuning of an IH-QCL (integrated heater quantum cascade laser) is exploited for simultaneous detection of methane and acetylene using direct absorption spectroscopy. The integrated heater, placed within few microns of the laser active region, enables wider wavelength tuning than would be possible with a conventional DFB (distributed feedback) QCL. In this work, the laser current and heater resistor current are modulated simultaneously at 25?kHz to tune the laser over 1279.6–1280.1 cm^?1, covering absorption transitions of methane and acetylene. The laser is characterized extensively to understand the dependence of wavelength tuning on modulation frequency, modulation amplitude and phase difference between laser/heater modulation. Thereafter, the designed sensor is validated in both room-temperature static cell experiments and non-reactive high-temperature-measurements in methane-acetylene-argon gas mixtures in the shock tube. Finally, the sensor is applied for simultaneous detection of methane and acetylene during the high-temperature pyrolysis of iso-octane behind reflected shock waves.     

Bimodal Nanoparticle Size Distributions Produced by Laser Ablation of Microparticles in Aerosols

Silver nanoparticles were produced by laser ablation of a continuously flowing aerosol of microparticles in nitrogen at varying laser fluences. Transmission electron micrographs were analyzed to determine the effect of laser fluence on the nanoparticle size distribution. These distributions exhibited bimodality with a large number of particles in a mode at small sizes (3–6-nm) and a second, less populated mode at larger sizes (11–16-nm). Both modes shifted to larger sizes with increasing laser fluence, with the small size mode shifting by 35% and the larger size mode by 25% over a fluence range of 0.3–4.2-J/cm². Size histograms for each mode were found to be well represented by log-normal distributions. The distribution of mass displayed a striking shift from the large to the small size mode with increasing laser fluence. These results are discussed in terms of a model of nanoparticle formation from two distinct laser–solid interactions. Initially, laser vaporization of material from the surface leads to condensation of nanoparticles in the ambient gas. Material evaporation occurs until the plasma breakdown threshold of the microparticles is reached, generating a shock wave that propagates through the remaining material. Rapid condensation of the vapor in the low-pressure region occurs behind the traveling shock wave. Measurement of particle size distributions versus gas pressure in the ablation region, as well as, versus microparticle feedstock size confirmed the assignment of the larger size mode to surface-vaporization and the smaller size mode to shock-formed nanoparticles.     

Self-organized nanostructure formation on the graphite surface induced by helium ion irradiation

The effects of helium ion irradiation on the graphite surface are studied by employing a plasma focus device. The device emits helium ion pulse having energies in the range of a few keV to a few MeV and flux on the order of 10²⁵ m^?2?s^?1 at 60 mm axial position from the anode tip. The field emission scanning electron microscopy confirms the formation of multi-modal spherical and elongated agglomerated structures on irradiated samples surface with increase in agglomerate size with increasing number of irradiation shots. The transient annealing in each irradiation was not enough to cause the Oswald ripening or sintering of particles into bigger particle or crystal size but only resulted in clustering. The atomic force micrographs reveal an increase in average surface roughness with increasing ion irradiation. The Raman study demonstrates increase in disordered D peak along with reduced crystallite size ($L_a$) with increasing number of irradiation shots.     

Numerical study of the synergistic effect of cavitation and micro-abrasive particles

In ultrasonic-assisted machining, the synergistic effect of the cavitation effect and micro-abrasive particles plays a crucial role. Studies have focused on the investigation of the micro-abrasive particles, cavitation micro-jets, and cavitation shock waves either individually or in pairs. To investigate the synergy of shock waves and micro-jets generated by cavitation with micro-abrasive particles in ultrasonic-assisted machining, the continuous control equations of a cavitation bubble, shock wave, micro-jet, and micro-abrasive particle influenced by the dimensionless amount (R/R₀), a particle size-velocity–pressure model of the micro-abrasive particle was established. The effects of ultrasonic frequency, sound pressure amplitude, and changes in particle size on micro-abrasive particle velocity and pressure were numerically simulated. At an ultrasonic frequency of 20 kHz and ultrasonic sound pressure of 0.1125 MPa, a smooth spherical SiO₂ micro-abrasive particle (size = 5 µm) was obtained, with a maximum velocity of 190.3–209.4 m/s and pressure of 79.69–89.41 MPa. The results show that in the range of 5–50 μm, smaller particle sizes of the micro-abrasive particles led to greater velocity and pressure. The shock waves, micro-jets, and micro-abrasive particles were all positively affected by the dimensionless amount (R/R₀) of cavitation bubble collapse, the larger the dimensionless quantity, the faster their velocity and the higher their pressure.     

Particle drift in a resonance tube--a numerical study

The paper considers longitudinal drift of small particles in a resonance tube, caused by periodic shock waves, and its effect on particle agglomeration. It is found that depending on particle size, drift is caused by shock waves and/or gas acceleration and compression. It is also shown that the drift velocity and direction can be controlled by the frequency of the piston that causes gas oscillations in the resonance tube. The obtained numerical solutions indicate that particle drift in a resonance tube enhances aerosol agglomeration. An agglomeration kernel is derived for this case, accounting for particle drift, leading to an estimate of agglomeration time. The time predicted by present model is of the same order of magnitude as that obtained from experiments in the literature.     

Influence of electron-atom cross section uncertainties on shock wave structure

The exact value of the electron-atom collisional ionization cross section for argon is not accurately known. The purpose of the present research is to determine numerically the effect of varying the magnitude of the electron-atom cross section on nonequilibrium shock-wave structure. Mach 18 shock waves propagating into an argon-like gas at 1 cm-Hg and 300°K have been analyzed. Thermal, ionizational, and excitational non-equilibrium are considered in the relaxation region behind the shock wave. Electrons in the relaxation region are formed by a two-step collisional process, wherein the atom is first excited and then it is ionized. The precursor is formed by ground and excited state continuum radiation and line radiation which is emitted, but not reabsorbed, in the region behind the shock wave. When the electron-atom ionization cross section is varied from 1·86 × 10^?4to 1·86 × 10^?2cm²/erg, the results show that (1) it influences the coupling between the precursor and relaxation region through the radiative source functions, (2) it does not influence the distance necessary to attain equilibrium behind the shock wave, (3) it inversely influences the magnitude of the precursor ionization, and excitation, and (4) it inversely influences both the free electron and excited state population in the relaxation layer.     

Size dependence of complex refractive index function of growing nanoparticles

The evidence of the change of the complex refractive index function E(m) of carbon and iron nanoparticles as a function of their size was found from two-color time-resolved laser-induced incandescence (TiRe-LII) measurements. Growing carbon particles were observed from acetylene pyrolysis behind a shock wave and iron particles were synthesized by pulse Kr–F excimer laser photo-dissociation of Fe(CO)₅. The magnitudes of refractive index function were found through the fitting of two independently measured values of particle heat up temperature, determined by two-color pyrometry and from the known energy of the laser pulse and the E(m) variation. Small carbon particles of about 1–14 nm in diameter had a low value of E(m)∼0.05–0.07, which tends to increase up to a value of 0.2–0.25 during particle growth up to 20 nm. Similar behavior for iron particles resulted in E(m) rise from ∼0.1 for particles 1–3 nm in diameter up to ∼0.2 for particles >12 nm in diameter.     

飞秒激光在铝膜中驱动冲击波的特性

为探索研究飞秒激光在材料中驱动冲击波的相关特性,采用激光脉冲频域干涉测试技术对脉冲宽度35fs、脉冲能量0.7mJ、功率密度1014W/cm2量级的飞秒激光脉冲在200nm厚铝膜中驱动冲击波的过程进行了实验测量。通过测量冲击波在铝膜中的渡越时间,获得激光脉冲在铝材料中驱动的冲击波平均速度约为6km/s;通过对不同时刻铝膜自由面频域干涉场测量结果的分析,获得铝材料自由表面速度达1km/s,根据平面冲击波的关系,推算其冲击压强达到9GPa。