共查询到20条相似文献,搜索用时 203 毫秒
1.
E. Czuchaj M. Kronicki J. Czub 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2001,13(3):345-353
Excitation spectra arising from A
3
0
+
←
X
1
0
+
and B
3
1 ←
X
1
0
+
electronic transitions in the Cd-rare gas (RG) van der Waals molecules are calculated using newly obtained theoretical potential
curves for these species. In the molecular structure calculations, Cd20+ and RG8+ cores are simulated by energy-consistent pseudopotentials which also account for scalar-relativistic effects and spin-orbit
(SO) interaction within the valence shell. Potential energies in the Λ
S coupling scheme have been obtained by means of ab initio complete-active-space multiconfiguration self consistent-field (CASSCF)/complete-active-space multireference second-order
perturbation theory (CASPT2) calculations with a total 28 correlated electrons, while the SO matrix has been computed in a
reduced CI space restricted to the CASSCF level. The final Ω potential curves are obtained by diagonalization of the modified SO matrix (its diagonal elements before diagonalization
substituted for the corresponding CASPT2 eigen-energies). The spectroscopic parameters for the ground and several excited
states of the Cd-RG complexes deduced from the calculated potential curves are in quite reasonable agreement with available
experimental data. In addition, the radial Schr?dinger equation for nuclear motion was solved numerically with the calculated
potentials to evaluate the corresponding vibrational levels and radial wavefunctions. The latter have been used in the calculation
of the appropriate Franck-Condon factors to yield information on relative intensities of the vibrational bands of the Cd-RG
complexes. The theoretical vibrational progressions are discussed in the context of experimental spectra.
Received 10 August 2000 and Received in final form 7 November 2000 相似文献
2.
U. Galster P. Kaminski M. Beckert H. Helm U. Müller 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2001,17(3):307-318
We have performed kinematically complete investigations of molecular photodissociation of triatomic hydrogen in a fast beam
translational spectrometer recently built in Freiburg. The apparatus allows us to investigate laser-induced dissociation of
neutral molecules into two, three, or more neutral products. The fragments are detected in coincidence and their vectorial
momenta in the center-of-mass frame are determined. We demonstrate the potential of the method at the fragmentation of the
3 s
2
A
1
′
(
N
= 1,
K
= 0) state of triatomic hydrogen. In this state, three-body decay into ground state hydrogen atoms H+H+H, two-body predissociation
into H+H
2
(v
,
J), and photoemission to the H
3
ground state surface with subsequent two-body decay are competing channels. In the case of two-body predissociation, we determine
the rovibrational population in the H
2
(v
,
J) fragment. The vibrational distribution of H
2
is compared with approximate theoretical predictions. For three-body decay, we measure the six-fold differential photodissociation
cross-section. To determine accurate final state distributions, the geometric collection efficiency of the apparatus is calculated
by a Monte Carlo simulation, and the raw data are corrected for apparatus efficiency. The final state momentum distribution
shows pronounced correlation patterns which are characteristic for the dissociation mechanism. For a three-body decay process
with a discrete kinetic energy release we have developed a novel data reduction procedure based on the detection of two fragments.
The final state distribution determined by this independent method agrees extremely well with that observed in the triple-coincidence
data. In addition, this method allows us to fully explore the phase space of the final state and to determine the branching
ratios between the two- and three-body decay processes.
Received 29 March 2001 相似文献
3.
R. Akers G. Alexander J. Allison K. Ametewee K. J. Anderson S. Arcelli S. Asai D. Axen G. Azuelos A. H. Ball et al. 《Zeitschrift fur Physik C Particles and Fields》1995,67(1):45-55
The properties of hadronic Z0 decays with final state photons, measured with OPAL at LEP, have been compared with predictions from two different matrix element calculations ofO(
s
). Two calculations, GNJETS and EEPRAD, have been investigated which use different schemes to restrict the phase space around the poles of the cross section. Assuming the E0-JADE jet definition, both calculations describe the data well in large regions of phase space fory
cut
values around 0.06. For very large and very small jet-photon masses some deviations from the predictions have been found, indicating the importance of higher order corrections. Significant differences between the calculations are only apparent in the predicted rate of 1-jet plus photon events. The rate is higher in GNJETS which reproduces the data better than EEPRAD. 相似文献
4.
W. Zhong W. Chen H.Y. Jiang X.S. Liu C.T. Au Y.W. Du 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,30(3):331-337
Polycrystalline two-layered perovskite La2.5-xK0.5+xMn2O
7 + δ
(0 <
x
< 0.5) samples have been prepared by a modified sol-gel method and their magnetoresistance and magnetocaloric effects have been
studied. A large deviation between the metal-insulator (MI) transition temperature (T
ρ
) and the magnetic transition temperature (TC) is observed. Large magnetoresistance (MR) effects with Δρ/ρ
of ∼40% at 12 kOe are obtained in wide temperature ranges. The maximum of the magnetic entropy change peaks at its Curie temperature
(TC), far above its MI transition temperature (T
ρ
). The large magnetic entropy change (∼1.4 J/kg.K) is obtained in the sample La2.5-xK0.5+xMn2O
7 + δ
(x
= 0.35) upon 10 kOe applied magnetic field.
Received 2 May 2002 / Received in final form 1st October 2002 Published online 19 December 2002
RID="a"
ID="a"e-mail: wzhong@ufp.nju.edu.cn 相似文献
5.
Influence of relaxation effects on probabilities of the 2s2p35S2-2s22p2 3P1,2 intercombination transitions in NII 下载免费PDF全文
Transition probabilities of the 2s2p^3 {}^5S_2-2s^22p^2 {}^3P_{1,2} intercombination transitions in NII have been calculated by using a large-scale multiconfiguration Dirac-Fock method. In the calculation the most important effects of relativity, correlation, and relaxation are considered. From the calculated transition probabilities, the lifetime of the 2s2p^3 {}^5S_2 metastable state is derived. The result is in excellent agreement with the latest experimental result. In the meantime the influence of anomalously strong relaxation effects on probabilities of the 2s2p^3 {}^5S_2-2s^22p^2 {}^3P_{1,2} lines in NII have been found. 相似文献
6.
Mireya Castillo 《International Journal of Infrared and Millimeter Waves》1992,13(6):909-922
A FT-IR spectroscopic study was carried out in the region 4000–400 cm–1 for ZnSeNi and ZnSNi at room temperature. The data obtained were examined on the basis of the energy states calculations of the (3d)n configuration, based on the defect molecule approach. The present investigation reveals the transition from the ground state to the first two excited states namely3T1–3A2 and3T1–3T2 of Ni+2 (d8). 相似文献
7.
8.
The low-energy level structure and electromagnetic transitions of ^48.50Cr nuclei have been studied using the interacting boson model with isospin (IBM-3). A sequence of isospin excitation bands with isospin T = Tz, Tz 1and Tz 2 has been assigned, and compared with available data. According to this study, the 2^3 and 2^2 states are the lowest mixed symmetry states in ^48Cr and ^50Cr, respectively. In particular, the present calculations suggest that a combination of isospin and F-spin excitation can explain the structure in these nuclei. The transition probabilities between the levels are analysed in terms of isoscalar and isovector decompositions which reveal the detailed nature of the energy levels. The results obtained are in good agreement with recent experimental data. 相似文献
9.
本文使用多组态Dirac-Hartree-Fock方法计算了29Si的3s23p2 3P2,1D2→3s3p3D30跃迁能量和3P2,3D30超精细结构A常数以及Si同位素29Si,30Si和31Si相对于28Si在3s23p2 3P2→3s3p3 3D30跃迁的同位素移动.通过尝试双电子激发(SD)和三电子激发(SDT),分别考虑VV相关,CV相关和CC相关产生各种不同的扩展组态波函数得到的计算结果和实验值的比较,推测了对于中性硅原子这两个组态,内壳层2p2s,1s电子活动到外壳层的概率较小,而3s3p壳层中的电子都比较活跃,但主要是在n=3,4的壳层内活动,活动到更高n壳层的概率则比较小. 相似文献
10.
Relativistic calculations of 3s2 1S0-3s3p 1P1 and 3s2 1S0-3s3p 3P1,2 transition probabilities in the Mg isoelectronic sequence 下载免费PDF全文
Using the multi-configuration Dirac-Fock self-consistent field method and the relativistic configuration-interaction method,calculations of transition energies,oscillator strengths and rates are performed for the 3s 2 1 S 0-3s3p 1 P 1 spinallowed transition,3s 2 1 S 0-3s3p 3 P 1,2 intercombination and magnetic quadrupole transition in the Mg isoelectronic sequence(Mg I,Al II,Si III,P IV and S V).Electron correlations are treated adequately,including intravalence electron correlations.The influence of the Breit interaction on oscillator strengths and transition energies are investigated.Quantum electrodynamics corrections are added as corrections.The calculation results are found to be in good agreement with the experimental data and other theoretical calculations. 相似文献
11.
使用Gaussian 03程序包中的“对称性匹配簇-组态相互作用”方法、在0.13—2.0nm的核间距范围内利用6-311+〖KG-*3〗+G(d,p)基组对7Li2(23Πu)分子的势能曲线进行了计算, 同时使用最小二乘法将计算结果拟合成了解析势能函数. 利用拟合出的解析势能函数并结合Rydberg-Klein-Rees方法, 计算了该态的谐振频率, 进而计算了该态的其他光谱常数, 分别为T关键词:
解析势能函数
谐振频率
振动能级
转动惯量 相似文献
12.
13.
本文用X射线粉末法测定了Li2K(IO3)3与Li2NH4(IO3)3的晶体结构和原子参数。发现Li3K(IO3)3,Li2NH4(IO3)3与Li2Rb(IO3)3同晶型,属单斜晶系,空间群为P21/α,每个单胞含有四个化合式量。室温的点阵常数分别为α=11.198?,b=11.046?,c=8.254?,β=111.53°,及α=11.327?,b=11.078?,c=8.341?,β=111.87°。讨论了二元化合物的形成与离子半径的关系。
关键词: 相似文献
14.
在镱原子中,利用5d6s3D1→6s21S0跃迁探索宇称破缺效应已经得到了深入的研究.但是5d6s3D1态与基态6s21S0之间的M1跃迁和超精细诱导E2跃迁很大程度上影响了宇称破缺信号的探测.因此,很有必要精确计算5d6s3D1态与基态6s21S0之间的M1跃迁和超精细诱导E2跃迁的跃迁概率.本文利用多组态Dirac-Hartree-Fock理论精确计算了5d6s3D1→6s21S0 M1跃迁和超精细诱导5d6s3D1,3→6s21S0 E2跃... 相似文献
15.
16.
V. N. Bocharov A. P. Burtsev E. V. Dubrovskaya T. D. Kolomiitsova D. N. Shchepkin 《Optics and Spectroscopy》2010,108(4):533-543
IR spectra of the solution of SF6 molecules in liquid NF3 at 84 K have been recorded. In a solvent transmission window of 1500–1750 cm−1, two wide absorption bands with pronounced peaks in the high-frequency part are observed. The profile of these bands is explained
by the influence of the resonance dipole-dipole (RDD) interaction of the states of the simultaneous transition ν1(SF6) + ν3(NF3) and ν2(SF6) + ν3(NF3) with the states (ν1 + ν3) and (ν2 + ν3) of the SF6 molecules, respectively. The use of three isotopic modifications 32SF6, 33SF6, and 34SF6 has allowed us to vary the resonance detuning and thus to change the strength of the RDD interaction. With the liquid near
the melting point being represented as a close-packed cubic crystal, the profile was calculated and its spectral characteristics
were determined. The frequencies of the main peaks coincide with the experimental values accurate to the error. 相似文献
17.
18.
用脉冲直流放电产生Xe原子亚稳态5p56s[3/2]2和5p56s′[1/2]0.在单光子28000-42000cm-1能量范围内,结合飞行时间质谱技术获得Xe原子共振增强激发光谱.光谱分析表明,所有谱线来源于Xe原子5p56s[3/2]2和5p56s′[1/2]0两个亚稳态吸收单个光子向偶宇称np′、nf′自电离Rydberg态序列的跃迁.实验观测到许多新的自电离能级,并获得更精确和系统的能级位置和量子亏损值数据. 相似文献
19.
20.
使用Gaussian03程序包中的“对称性匹配簇/对称性匹配簇-组态相互作用”方法, 利用多个基组对7Li2分子23Σ+g态的平衡几何进行了优化计算. 同时, 在优化得到的平衡位置附近、于同一条件下通过精细的单点能扫描, 获得了相应基组下的平衡核间距. 发现两者的结果不一致,对不一致的原因进行了解释. 分析表明,由单点能扫描得到的平衡核间距应更为合理. 同时也得出了6-311++G(3df,3pd),6-311++G(2df,2pd) 及6-311++G(2df,pd)基组均为较优基组的结论.于2.5a0—37a0的范围内利用6-311++G(3df,3pd)基组进行单点能扫描并使用最小二乘法拟合出了该态的解析势能函数. 利用解析势能函数的物理意义并结合Rydberg-Klein-Rees方法, 计算出了其相应的谐振频率, 进而计算了其他光谱常数. 为便于比较和分析, 对基态也进行了相应的计算.利用得到的解析势能函数, 对23Σ+g态的振动能级及振动经典转折点也进行了计算.
关键词:
势能函数
谐振频率
振动能级
Murrell-Sorbie函数 相似文献