All fiber passively mode locked zirconium-based erbium-doped fiber laser

All passively mode locked erbium-doped fiber laser with a zirconium host is demonstrated. The fiber laser utilizes the Non-Linear Polarization Rotation (NPR) technique with an inexpensive fiber-based Polarization Beam Splitter (PBS) as the mode-locking element. A 2 m crystalline Zirconia–Yttria–Alumino-silicate fiber doped with erbium ions (Zr–Y–Al-EDF) acts as the gain medium and generates an Amplified Spontaneous Emission (ASE) spectrum from 1500 nm to 1650 nm. The generated mode-locked pulses have a spectrum ranging from 1548 nm to more than 1605 nm, as well as a 3-dB bandwidth of 12 nm. The mode-locked pulse train has an average output power level of 17 mW with a calculated peak power of 1.24 kW and energy per pulse of approximately 730 pJ. The spectrum also exhibits a Signal-to-Noise Ratio (SNR) of 50 dB as well as a repetition rate of 23.2 MHz. The system is very stable and shows little power fluctuation, in addition to being repeatable.     

Characterization of stimulated Brillouin scattering in small core microstructured chalcogenide fiber

We report a full modal characterization of the stimulated Brillouin scattering (SBS) properties in small core As₂Se₃-based chalcogenide photonic crystal fibers (PCFs). Our results include the calculation of Brillouin gain spectrum (BGS), Brillouin gain coefficient (g_B), Brillouin frequency shift (BFS) by taking into account the contribution of the higher-order acoustic modes. We show that for a highly nonlinear PCF having a 2-μm hole-to-hole pitch and a 0.5-μm hole diameter, a Brillouin gain coefficient g_B = 5.91 10^? 9 m.W^? 1 is obtained around the acoustic frequency of 8.19 GHz, which is more than 340 times larger than that of the same PCF made with silica glass. We demonstrate that the BGS of small core PCF structures show strong SBS and multipeaked behavior, with a presence of a second peak, when decreasing the core diameter which is to be attributed to the higher-order acoustic modes. We designed small core PCFs with tailored Brillouin response for a wide range of applications.     

Phase-matched generation of high-order continuous-wave coherent Raman sidebands

We demonstrate the generation of continuous-wave (cw) Raman sidebands through phase-matched four-wave mixing (FWM) in molecular hydrogen. The phase-matching conditions of the intracavity FWM driven in our dispersion-compensated high-finesse cavity are satisfied over a 52.8 THz-wide frequency range (763.9–883.6 nm). This leads to the generation of high-order anti-Stokes emission. The cw Raman sidebands have sufficient bandwidth to allow the synthesis of a train of optical pulses with a duration of 13 fs at a repetition rate of 17.6 THz under phase-locked conditions.     

The adsorption and reaction of 2-butanol on clean and oxygen-covered Pd(100)

The surface chemistry of 2-butanol is explored on clean Pd(100), c(2 × 2)-O/Pd(100) and p(2 × 2)-O/Pd(100) surfaces by means of temperature-programmed desorption, reflection–absorption infrared and X-ray photoelectron spectroscopies. 2-Butanol adsorbs molecularly on clean and oxygen-covered Pd(100) below ～ 190 K, but then appears to react to form 2-butoxide species at ～ 200 K. Both 2-butanone and 2-butanol desorb from the clean surface at ～ 226 K, by β-hydride elimination from the 2-butoxide species and rehydrogenation of the 2-butoxide, respectively. In contrast, almost exclusively 2-butanone is formed on oxygen-covered surfaces. Butanone desorbs at ～ 195 K and ～ 260 K from c(2 × 2)-O/Pd(100) with the 195 K peak being the most intense. However, on p(2 × 2)-O/Pd(100), 2-butanone desorbs at ～ 195 K and ～ 295 K, and the latter peak is the most intense. The ～ 195 K, 2-butanone state is proposed to occur due to abstraction by adsorbed atomic oxygen and the change in relative intensity of these features is ascribed to the lower ability of surface hydroxyl groups to facilitate β-hydride elimination on oxygen-covered surfaces. Further heating results in the formation of hydrogen and carbon monoxide and leaves a small amount of carbon deposited on the surface.     

Performance comparison between 160 Gb/s WDM and TDM systems

The performances of 160 Gb/s time-division multiplexing (TDM) and 4 × 40 Gb/s wavelength-division multiplexing (WDM) signals are comparatively studied in the nonzero-dispersion shifted fibers (NZDSFs). TDM format is superior to WDM, and with the increase of distance, this advantage is enhanced. In the case of adopting the dispersion managed soliton transmission and dispersion flattened fibers (DFFs) technique, the Q values of both formats change little when the channel space varies. So, TDM technique is applicable to the dense and very long haul transmissions. Only by utilizing the conventional loss and dispersion compensation schemes (NZDSFs + DCFs + EDFAs), the available transmission distance of dense WDM signals reaches 1000 km, and for TDM format, it even extends to 2000 km. Both systems have the analogue characteristics: a higher pulse power benefits system's working; ASE noise is the dominant impact factor of system performance; both format's system performances are improved for the case of less channel number; the channel space and duty cycle of return zero pulse have little effect on Q; the impact of duty cycle relates to the filter bandwidths, XPM induced sidebands and pulse broadening effect; the influence of channel space is determined by the walk-off effect.     

Structural and photoluminescence investigation on the hot-wire assisted plasma enhanced chemical vapor deposition growth silicon nanowires

High density of silicon nanowires (SiNWs) were synthesized by a hot-wire assisted plasma enhanced chemical vapor deposition technique. The structural and optical properties of the as-grown SiNWs prepared at different rf power of 40 and 80 W were analyzed in this study. The SiNWs prepared at rf power of 40 W exhibited highly crystalline structure with a high crystal volume fraction, X_C of ～82% and are surrounded by a thin layer of SiO_x. The NWs show high absorption in the high energy region (E>1.8 eV) and strong photoluminescence at 1.73 to 2.05 eV (red–orange region) with a weak shoulder at 1.65 to 1.73 eV (near IR region). An increase in rf power to 80 W reduced the X_C to ～65% and led to the formation of nanocrystalline Si structures with a crystallite size of <4 nm within the SiNWs. These NWs are covered by a mixture of uncatalyzed amorphous Si layer. The SiNWs prepared at 80 W exhibited a high optical absorption ability above 99% in the broadband range between 220 and ～1500 nm and red emission between 1.65 and 1.95 eV. The interesting light absorption and photoluminescence properties from both SiNWs are discussed in the text.     

A novel tunable optical oscillator for broadband signals

A tunable optical oscillator that generates signals at the micro- to millimeter-wave band for wireless communication applications is suggested. It uses directly modulated semiconductor lasers, in which sideband modes and four-wave mixing (FWM) conjugate modes are injection locked by the simple control of the applied modulation power. The signals at 15 GHz with phase noise of below ?95 dBc/Hz at an offset frequency of 100 kHz were experimentally obtained. The frequency of the generated signal is tunable, and the maximum achievable signal frequency is limited mainly by the bandwidth of the receiver.     

2 μm passive Q-switched mode-locked Tm3+:YAP laser with single-walled carbon nanotube absorber

We report the first demonstration, to our knowledge, of passive Q-switched mode-locking in a Tm³⁺:YAP laser, operating in the 2 μm broadly spectral region formed with a compact Z-flod cavity. A transmission-type single-walled carbon nanotube saturable absorber (SWCNT–SA) is used for the initiation of the pulse generation. The repetition rate of the Q-switched envelope was 60 kHz at the pump power of 8.6 W. The mode-locked pulses inside the Q-switched pulse envelope had a repetition rate of ～92 MHz. A maximum average output power of 761 mW was obtained. The dependence of the operational parameters on the pump power was also investigated experimentally.     

Color filters featuring high transmission efficiency and broad bandwidth based on resonant waveguide-metallic grating

A one-dimensional transmission color filter based on a resonant waveguide-metallic subwavelength grating was numerically investigated by employing rigorous coupled-wave analysis (RCWA) and genetic algorithm (GA). The hybrid numerical method is used to determine the optimal parameters (the grating period, filling factor, grating thickness, and waveguide thickness) of two waveguide-grating structures, namely a double-layer resonant waveguide-metallic grating and a triple-layer resonant waveguide-metallic grating. The optical responses of these structures are evaluated and compared in terms of the ideal transmission efficiency aiming at the central wavelengths of 645 nm, 546 nm, and 455 nm of red (R), green (G), and blue (B) lights, respectively, over the visible region (380–780 nm). The results show that the optical performance of the double-layer with silver grating achieves the highest transmission efficiency of 82% (R), 81% (G), and 66% (B); and the largest bandwidth of about 125 nm (R), 118 nm (G), and 85 nm (B). Compared with existing color filters, the proposed device not only obtains a higher transmission and broader bandwidth, but it also suppresses redundant spectral peaks and transmission sidebands.     

Growth-morphology-luminescence correlation in ZnO-containing nanostructures synthesized in different media

Zinc hydroxide particles were prepared by a two-step process employing zinc nitrate hexahydrate, urea, ethylene glycol, water and p-toluene-sulfonic acid monohydrate (p-TSA). We used different concentrations of the reactants as well as different volume ratios of the solvents. ZnO particles were obtained by thermal treatment of the reaction products at two different temperatures: 350 °C and 500 °C. The samples were characterized by scanning field emission electron microscopy (SEM), X-ray diffraction (XRD) spectroscopy, BET analysis, thermogravimetry (TG) analysis and photoluminescence (PL) spectroscopy. It was found that after the thermal treatment particles become smaller, with the p-TSA concentration strongly affecting the morphology of the particles. Luminescence properties of the samples probed by PL at 8 K and room temperature exhibited a remarkable correlation with specimens′ nanomorphology. Luminescent features at ～2.0–2.2 eV, ～2.4–2.5 eV, ～2.65 eV, ～2.9 eV, ～3.0–3.1 eV and ～3.3 eV were observed in most specimens, although their relative intensity and temperature dependence were specific to an individual group of samples vis-à-vis their growth history and morphology.     

Efficient cw violet-light generation in a ring cavity with a periodically poled KTP

In this work, we experimentally demonstrate an efficient cw second harmonic generation (SHG) at 780 nm wavelength with a first-order type-I phase matching periodically poled KTP (PPKTP) crystal in a ring cavity, the wavelength corresponds to the D₂ line of Rb atom transition. The fundamental laser used is a grating-stabilized external cavity diode laser and its frequency is precisely locked to Rb atom transition frequency using the saturated absorption technique. About maximal 6.9 mW UV radiation of 390 nm with a net conversion of 9.5% at an input mode-matched power of 73 mW is generated with one crystal, and about maximal 8.8 mW with the net conversion of 12% is obtained with another crystal; the powers in stable operation are about 1.7 mW and 3.4 mW, respectively. This is, to our best knowledge, the first SHG experiment at 780 nm wavelength with the PPKTP in a ring cavity.     

Spectroscopic characterizations of individual single-crystalline GaN nanowires in visible/ultra-violet regime

Spectroscopic investigations of individual single-crystalline GaN nanowires with a lateral dimensions of ～30–90 nm were performed using the spatially resolved technique of electron energy-loss spectroscopy in conjunction with scanning transmission electron microscope showing a 2-Å electron probe. Positioning the electron probe upon transmission impact and at aloof setup with respect to the nanomaterials, we explored two types of surface modes intrinsic to GaN, surface exciton polaritons at ～8.3 eV (～150 nm) and surface guided modes at 3.88 eV (～320 nm), which are in visible/ultra-violet spectral regime above GaN bandgap of ～3.3 eV (～375 nm) and difficult to access by conventional optical spectroscopies. The explorations of these electromagnetic resonances might expand the current technical interests in GaN nanomaterials from the visible/UV range below ～3.5 eV to the spectral regime further beyond.     

Beam dynamics of 20 MeV MIRRORCLE-type tabletop storage ring

An experimental study on beam dynamics in MIRRORCLE-20, a tabletop storage ring of 15 cm orbit radius, was performed. Measurement of the infrared (IR) synchrotron light is the tool of this study. The IR emission is enhanced by a circular optics, named photon storage ring (PhSR), placed around the electron orbit, and is collected by a magic mirror associated with two plane mirrors in the storage ring. The measured average IR power in mid-IR region (λ < 50 μm) is ～59 mW. The observed stored beam current is about 1.2 A at maximum, which represents a record for a storage ring. The observed beam size is about 74 × 3 mm². We conclude that this very long beam size is due to the large betatron oscillation of 2/3 resonance injection.     

Photocatalytic degradation of ciprofloxacin drug in water using ZnO nanoparticles

We report the synthesis of nanostructure ZnO semiconductor with ～2.1 nm diameter using a chemical precipitation method. The resulting nanoparticles were characterized by X-ray diffraction analysis (XRD), Fourier-transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The optical properties were investigated by UV–vis and fluorescence techniques. The absorption spectra exhibit a sharp absorption edge at ～334 nm corresponding to band gap of ～3.7 eV. The fluorescence spectra displayed a near-band-edge ultraviolet excitonic emission at ～410 nm and a green emission peak at ～525 nm, due to a transition of a photo-generated electron from the conduction band to a deeply trapped hole. The photocatalytic activity of the prepared ZnO nanoparticles has been investigated for the degradation of ciprofloxacin drug under UV light irradiation in aqueous solutions of different pH values. The results showed that the photocatalytic degradation process is effective at pH 7 and 10, but it is rather slow at pH 4. Higher degradation efficiency (～50%) of the drug was observed at pH 10 after 60 min. Photodegradation of the drug follows a pseudo-first-order kinetics.     

Fabrication of single-mode Y-branch waveguides in photosensitive polymer with reduced Y-junction residue

Single-mode small-core (～2 μm × 2 μm) Y-branch waveguide structures in photosensitive polymer have been fabricated. Y-branch waveguides are designed by the beam propagation method and Y-branch waveguides are obtained on development after a cross-linkable negative tone epoxy SU-8 2002 polymer is exposed to UV through a photomask. Optical Adhesive NOA 61 is used as under- and over-clad. The fabrication process is optimized to avoid polymer residue at the Y-junction. The average insertion loss obtained for a 7.2 mm 1 × 2 device at chip-level is ～13 dB at 1550 nm.     

Dependence of sonochemical parameters on the platinization of rutile titania – An observation of a pronounced increase in photocatalytic efficiencies

Using a standing wave sonochemical reactor (SWSR), the influences of parameters of ultrasonic power input, sonication time, sonication temperature and the amount of propanol (which generates the reducing radicals) were systemically investigated to ascertain and optimize the best conditions for the sonochemical reduction of Pt from its precursor hexachloroplatinic acid and then its deposition on rutile TiO₂ (platinization of rutile titania) catalysts. Catalytic activity of the prepared platinized catalysts was tested in the reaction of methyl orange degradation. The results of photocatalytic activity study in the degradation of methyl orange further demonstrate that sonochemically as-prepared Pt/TiO₂ catalysts show a pronounced increase (～2 times) in photodegradation, even with a deposition of small amounts of platinum (1.4 wt.%), as compared to the unsupported or naked rutile titania. Although there are various parameters that influence the sonochemical platinization of rutile titania, the present optimization results clearly indicate that the best photocatalytic degradation of methyl orange can be obtained when the experimental conditions of the preparation were with an input power of 50 W, an initial hexachloroplatinic acid volume of 70 ml (which results into 1.4 wt.% Pt on TiO₂), sonication time of 90 min, 0.18 g of propanol and a temperature of 10 °C were adopted. The method of ultrasound application to prepare metal supported semiconductors has many advantages such as convenience, safety and high efficiency. Furthermore, it is hopeful that this optimization study can also be extended to the generation of similar metal supported semiconductors.     

Manganite heterojunction photodetectors for femtosecond pulse laser measurements

We report a sensitive photodetector, based on a manganite junction La_2/3Ca_1/3MnO₃/Si, for femtosecond (fs) pulse laser energy per pulse and average power measurements. The La_2/3Ca_1/3MnO₃/Si photodetector exhibits D^? (normalized detectivity) greater than 5.229×10⁹ cm Hz^1/2 W^?1. The open-circuit photovoltage and short-circuit photocurrent responsivities reach ～268 V/mJ and ～275 A/mJ for single pulse irradiation, respectively, and the open-circuit photovoltage responsivity reaches ～1.7 V/W for average power illumination. The experimental results make the manganite junction a promising fs laser measurement detector and reference standard for calibrating fs lasers.     

Improvement of polarization extinction in silicon waveguide devices

The SOI based waveguide devices are found to be highly polarization sensitive. Unwanted polarization excitations can be attenuated by integrating a TE- or TM-pass polarizer. A large attenuation of TM-polarized light has been observed when a thin film of metal is coated on the top of silicon rib waveguide, while TE-polarized light remains almost unaffected. The attenuation of TM-polarized light is attributed to the plasmonic absorption of the evanescent field in the metal cladding. Typically, with an Al cladding of thickness ～ 100 nm and a length of 1 mm on top of a single-mode (λ ～ 1550 nm) SOI rib waveguide structure, TE vs TM extinction ratio of ～ 15 dB has been obtained. Integrating such waveguide polarizers in a directional coupler and MZI based DWDM channel interleaver, we have also achieved an improvement in polarization extinction by ～ 15 dB.     

Highly sensitive hydrogen detection by medium energy Ne+ impact

Hydrogen atoms on solid surfaces were measured directly by elastic recoil detection analysis (ERDA) using medium energy (100–150 keV) Ne⁺ ions with an excellent sensitivity of (～ 1 × 10¹² H/cm²) without any absorber foils and time-of-flight techniques. An electrostatic toroidal analyzer acquired H⁺ ions with energy around 11 keV recoiled from Si(111)-1 × 1-H surfaces. The H⁺ fraction strongly depends upon emerging angle and takes a value more than 50% at the angle below 70° and a saturated value of 17% at the angle above 80° with respect to surface normal. We detected H atoms on the reduced TiO₂(110) exposed to water molecules at room temperature (2 L) and estimated the absolute amount of H to be ～ 2.0 × 10¹⁴ H/cm² corresponding to ～ 38% (～ 0.38 ML) of the bridging oxygen atoms.     

Third-order photonic-crystal distributed-feedback quantum cascade lasers

We demonstrate room-temperature operation of broad-area edge-emitting photonic-crystal distributed-feedback quantum cascade lasers at λ ～ 4.6 μm. The lasers use a weak-index perturbed third-order photonic-crystal lattice to control the optical mode in the wafer plane. Utilizing this coupling mechanism, the near-diffraction-limited beam quality with a far-field profile normal to the facet can be obtained. Single-mode operation with a signal-to-noise ratio of about 20 dB is achieved in the temperature range of 85–290 K. The single-facet output power is above 1 W for a 55 μm × 2.5 mm laser bar at 85 K in pulsed mode.