制备条件对PANI/PATP/Au和TiO_2-PANI/PATP/Au膜光电化学性能的影响

应用电化学方法在不同条件下制备聚苯胺 (PANI)膜和TiO2 -PANI复合膜 ,并对其光电化学性能进行研究 .实验表明 ,制备条件是影响膜光电化学性能的重要因素 .对氨基硫酚 (PATP)的组装有利于改善PANI膜的附着力 ;部分氧化态PANI膜的光电化学响应明显优于还原态和氧化态PANI膜的光电化学响应 ;部分氧化态PANI膜的厚度对其光电化学性能有一最佳值 ;热处理虽然有利于改善TiO2 的光电化学性能 ,但温度太高 ,将破坏PANI膜的表面结构 ,对于TiO2 -PANI复合膜有一最佳的热处理温度 .优化制备条件大可改善TiO2 -PANI复合膜和PANI膜的光电化学性能     

过渡金属氧化物在光电化学传感器中的应用研究进展

近年来,光电化学传感器的研究已经成为人们关注的热点。光敏材料作为光电化学传感器的关键部分,其性能对传感器的灵敏度、选择性和稳定性等特征起着决定性的作用。该文简要介绍了光电化学传感器的原理和光电材料的分类,阐述了在光电化学传感器中常见过渡金属氧化物及其复合物的光电材料的制备方法与应用,对光电化学传感器及光电化学材料的发展前景进行了展望(引用文献67篇)。     

光电化学方法在铜缓蚀剂作用机理研究中的应用

本文综述了笔者实验室采用光电化学方法在铜缓蚀剂作用机理研究中的应用情况，采用此方法不仅可对铜缓蚀剂的缓蚀性能进行评定，而且还可对缓蚀剂的作用机理级缓蚀协同效应与作用机理进行研究，可以得到其它一些常规电化学方法及表面分析所不能得到的一些信息，此方法不失为一种研究缓蚀剂作用机进的好方法。     

Exploitation of a photoelectrochemical sensing platform for bisphenol A quantitative determination using Cu/graphitic carbon nitride nanocomposites

The photoelectrochemical sensor basedon Cu/g-CN composites modified electrodeis firstly used to monitor bisphenol Awith high sensitivity. This work opens theway for the application of Cu/g-CN composites in photoelectrochemical field, and simultaneously contributed to broadening the application of graphitic carbon nitride-based materials. In addition, it can provide a convenient and rapid analysis method for the detection of other organic compounds in the future.     

3D Tungsten Trioxide Nanosheets as Optoelectronic Materials for On-chip Quantification of Global Antioxidant Capacity

The photoelectrochemical properties of semiconductors mainly depend on the size and shape of the corresponding nanoparticles. Herein, 3D WO₃ nanosheets were controllably synthesized with the aid of polyethyleneimine, which presents enhanced photocurrent responses. Based on this excellent photoelectrochemical property, a photoelectrochemical chip was prepared by lithography technology for the smart monitoring of the antioxidant capacity(AC) in red wine and exhibits a series of advantages inclu-ding rapid response time, high sensitivity, and long-lasting stability. The mechanism of the present photoelectrochemical sensing was explored and shows a single electron transfer reaction. Furthermore, only 200 μL of samples are required for one testing, which demonstrates that the present photoelectrochemical chip can be potentially integrated with a portable commercial device(such as a mobile phone) for further research and development of food and drug supervision.     

低背景信号的高级生物分析方法：光电化学生物分析

光电化学传感是近年来兴起并发展迅速的一种生物分析技术,其检测的主要原理是生物识别原件识别靶标物质而引起光电活性材料的光电性能变化,最终导致光电流值发生变化,从而达到检测的目的。由于光电化学生物分析中输入信号是光,输出信号是电,这赋予了此种检测方法背景信号低、灵敏度高的天然优势,这种优势所展现出来的潜力使光电化学分析在检测领域受到了越来越多的关注。本文介绍了光电化学生物传感的基本原理、光电活性材料的分类以及光电化学生物传感的传感模式,最后对其未来的发展进行了展望。     

Progress in the studies of photoelectrochemical sensors

Photoelectrochemical sensor is a new kind of developing analytical device based on the photoelectrochemical properties of materials. Because of its remarkable sensitivity, inherent miniaturization, portability and easy integration, photoelectrochemical analysis is becoming a promising analytical technique. This review focuses on the basic principles, classification, characteristics, and research progress of photoelectrochemical sensors with 94 references. The prospect of the development of photoelectrochemical sensors is also evaluated and discussed.     

多晶光电化学电极的内部短路电流

本文提出多晶光电化学电极中存在暗区短路电流的概念及其测试方法,并用模拟电极体系及实际多晶电极加以验证。实验结果表明:暗区短路电流的大小随电极的制造工艺而不同。由此可见,存在暗区短路电流是多晶光电化学电极开路电压和输出电流较单晶为低的原因之一,因此,制备多晶电极时应注意使电极致密、孔隙度小。     

电沉积二氧化钛纳米微粒膜的光电化学性能和表面形貌研究

采用光电流谱、透射光谱和扫描微探针显微镜技术对电沉积法制备的二氧化钛纳米微粒膜的光电化学性能和表面形貌进行了研究.结果表明,不同制备条件下的二氧化钛纳米微粒膜具有与紧密的半导体电极不同的光电化学性质,并探讨了其光电化学性能与表面形貌的关系.     

Structure and photoelectrochemical properties of phthalocyanine and perylene diimide composite clusters deposited electrophoretically on nanostructured SnO2 electrodes

Clusters of phthalocyanine and phthalocyanine-perylene diimide have been prepared and electrophoretically deposited on nanostructured SnO2 electrodes. The structure and photoelectrochemical properties of the clusters have been investigated by using UV-visible absorption, dynamic light scattering (DLS), atomic force microscopy (AFM), transmission electron microscopy (TEM), and photoelectrochemical and photodynamical measurements. Enhancement of the photocurrent generation efficiency in the composite system has been achieved relative to that in the phthalocyanine reference system without the perylene diimide. Such information will be valuable for the design of molecular photoelectrochemical devices that exhibit efficient photocurrent generation.     

Photoelectrochemical property of the BiOBr-BiOI/ZnO heterostructures with tunable bandgap

Layered BiOBr-BiOI composites with tunable bandgap were deposited onto ZnO nanowire arrays by spin-coating. The prepared BiOBr-BiOI/ZnO heterostructures were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, UV-visible absorption, and photoelectrochemical response. The bandgap of the BiOBr-BiOI can be tuned by varying the ratio of BiOBr/BiOI. The BiOBr-BiOI composites were proved to be n-type semiconductors, which serve as sensitizers in the BiOBr-BiOI/ZnO heterostructures. BiOBr-BiOI/ZnO heterostructures show much higher visible light photoelectrochemical activity than ZnO nanowire arrays because of the visible light absorption of BiOBr-BiOI and the formation of heterojunction between BiOBr-BiOI and ZnO, which reduces the recombination of photogenerated electrons and holes. In addition, the bandgap of BiOBr-BiOI directly affects the photoelectrochemical performance of the BiOBr-BiOI/ZnO heterojunctions. The smaller bandgap of the BiOBr-BiOI is, the more visible light is absorbed and the higher photoelectrochemical performance of the BiOBr-BiOI/ZnO heterojunctions achieves. The BiOBr-BiOI/ZnO heterostructures can be developed for application in water splitting and other optoelectrical devices.     

聚吡咯/TiO2纳米管阵列复合电极制备条件对其光电性能的影响

通过阳极氧化法制备TiO2纳米管阵列(TNTA),静态下采用电化学方法在TNTA表面修饰聚吡咯(PPy)。并用扫描电子显微镜(SEM)、红外透射光谱(FTIR)、紫外可见漫反射吸收光谱(UV-Vis)等表征手段对复合材料进行表征。结果显示,PPy和TiO2之间存在强烈的相互作用,PPy修饰的TNTA发生了红移,并且增强了其在整个可见光区的吸收。确定了影响PPy/TNTA复合电极光电性能的因素(聚合时间、聚合温度、聚合电位、电解质浓度等),通过测定连续瞬间电流-时间曲线的方法,考察了制备条件对复合材料光电性能的影响。初步探讨出PPy提高TNTA光电性能的机理。     

结合光电化学和瞬态吸收光谱技术研究光电化学分解水载流子动力学

半导体光电化学制氢是一种重要的、有前景的太阳能应用技术. 其产氢效率取决于光生载流子的产生、分离和传输效率. 深入理解光生载流子的动力学过程对于设计高效的太阳能产氢器件有重要的指导意义. 光电化学和瞬态吸收光谱技术是研究光催化反应微观动力学和机理的强有力手段. 本文介绍作者应用这些技术在半导体光电化学制氢方面所取得的部分最新研究结果, 并对存在的问题和今后研究重点提出了一些看法.     

纳米TiO2电极的特殊光电化学响应

应用涂膜法、电沉积法和溶胶-凝胶法制备纳米TiO2电极.实验发现,纳米TiO2具有特殊的光电化学响应,其光电流~电位变化出现光电流峰,这一特殊的光电化学性质乃与纳米半导体电极的纳米结构及其特殊的光诱导氧化还原反应机理密切相关.     

TiO2-MoO3复合纳米管阵列薄膜的制备及其可见光活性

通过阳极氧化的方法制备TiO₂纳米管薄膜, 在MoO₃存在的条件下对该薄膜进行热处理得到TiO₂-MoO₃复合纳米管阵列薄膜. 利用X射线衍射(XRD), 扫描电子显微镜(SEM), X射线光电子能谱(XPS), 电化学阻抗谱(EIS), Mott-Schottky 及光电化学方法对得到的薄膜进行了表征. XRD结果表明, TiO₂-MoO₃复合纳米管薄膜中的TiO₂主要为锐钛矿晶型. SEM实验证实了薄膜纳米管结构的存在, 样品中的MoO₃均匀地分散在TiO₂纳米管表面. 利用XPS方法分析了TiO₂-MoO₃复合纳米管薄膜元素的组成, 结果表明, MoO₃在TiO₂表面形成TiO₂-MoO₃复合纳米管薄膜. 研究了热处理温度以及热处理时间对样品的光电化学性能的影响, 相对于单纯TiO₂纳米管薄膜, 适量引入MoO₃提高了样品在可见光区的光电响应能力, 样品的平带电位负移. 在450 °C热处理60 min制得的TiO₂-MoO₃复合半导体纳米管阵列薄膜光电响应活性最高.     

Effect of light on the poly-3-phenylthiophene properties

The electrochemical and photoelectrochemical behavior of a conducting polymer, poly-3-phenylthiophene (P3PhT), is studied in acetonitrile containing salts of tetrabutylammonium (TBA) and lithium. Like other thiophene polymers, P3PhT may or may not be doped cathodically in the presence of salts of TBA or lithium, respectively. In general, the photoelectrochemical behavior of P3PhT resembles that of polybithiophene and poly-3-methylthiophehe. In particular, P3PhT is photoactivated when exposed to light at negative potentials. Depending on the system in which measurements are taken (in the presence of salts of lithium or TBA), P3PhT undergoes photoelectrochemical undoping or photoelectrochemical cathodic doping, respectively, which is confirmed by measuring electrochemical impedance. However, the photoelectrochemical processes on P3PhT (at least in solutions containing lithium salts) proceed much slower than those on other thiophene polymers we studied earlier. The concentration of doping ions in P3PhT in the presence of lithium salts is higher than that in the presence of TBA salts even in the undoped state. This is due to a specific interaction between Li⁺ and the phenyl group in P3PhT. Deceased.     

光电化学传感器的研究进展

光电化学传感器以光作为激发源,以光电流或光电压作为检测信号,具有响应快速、灵敏度高、设备简单等特点,目前已在环境、食品、医学等多个领域的分析测试中得到广泛应用。该文阐述了光电转换材料与光电化学传感器的制备方法,介绍了光电化学传感器的原理和分类。光电化学传感器包含光寻址电位型传感器和电流型光电化学传感器,其中,电流型光电化学传感器由于优良的光电性能、检出限低、所需材料低廉且易加工等优势而被广泛应用。文中着重介绍了电流型光电化学传感器在金属离子、有机污染物、核酸、蛋白质、细胞等方面的应用,并对光电化学传感器的发展前景进行了展望。     

二氧化钛纳米微粒膜光电化学行为的研究

利用不同的制备方法制备出二氧化钛纳米微粒膜，对二氧化钛纳米微粒膜的光电化学材为和产生的机理进行了研究．结果表明；二氧化钛纳米微粒膜除了具有传统半导体的光电化学性质外，还具有不同于传统半导体的光电化学性质这主要是出膜的微粒性引起的，可综合传统半导体和胶粒半导体两种模型来加以解释。     

The effect of various calcination treatments on the photocatalytic activity of a rod-type TiO<Subscript>2</Subscript> electrode for oxidation of ethanethiol

It was found that the photoelectrochemical performance and photocatalytic activity of rod-type TiO₂ electrodes were affected by various post-calcination treatments, for example, calcination in NH₃ or under vacuum. Post-calcination treatment in NH₃ at 773 K was particularly effective in increasing the photoelectrochemical performance and photocatalytic activity of rod-type TiO₂ electrodes. A unique photoelectrochemical circuit was constructed by connecting a rod-type TiO₂ electrode to a Pt electrode through a silicon solar cell in which the negative bias was applied on the rod-type TiO₂ electrode. It was found that the photoelectrochemical circuit can effectively oxidize ethanethiol in water into CO₂.     

不同取代基卟啉衍生物敏化纳米TiO2多孔膜电极的光电性质研究

采用含有不同取代基的卟啉衍生物四羟基苯基卟啉(THPP)和四羧基苯基卟啉(TCPP)分别对纳米TiO2多孔膜电极进行敏化.对两种敏化电极进行了UV-Vis光谱、FTIR光谱和X射线光电子能谱(XPS)测试.结果表明,TiO2与TCPP的作用比与THPP的作用强.在相同浸泡条件下,TiO2电极吸附TCPP的量大于吸附THPP的量.将两种敏化电极分别组装成光电化学电池,从正背两个方向照射光电池,研究它们在不同照射方向下的光电流响应.从光电化学电池的I-V曲线计算TCPP敏化的光电化学池的总光电转换效率(η)为0.13%,而THPP敏化的光电化学电池的η为0.06%.