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Luminescence Spectra of YGG:RE^3+, Bi^3+ (RE = Eu and Tb) and Energy Transfer from Bi^3+ to RE^3+
引用本文:朱南飞,李永祥,于晓峰.Luminescence Spectra of YGG:RE^3+, Bi^3+ (RE = Eu and Tb) and Energy Transfer from Bi^3+ to RE^3+[J].中国物理快报,2008,25(2):703-706.
作者姓名:朱南飞  李永祥  于晓峰
作者单位:[1]The State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai institute of Ceramics Chinese Academy of Sciences, Shanghai 200050; [2]Postgraduate School of the Chinese Academy of Sciences, Beijing 100049
基金项目:Supported by the Shanghai Science and Technology Committee under Grant No 03JC14075.
摘    要:We investigate the luminescence properties of Bi^3+ and RE^3+ (RE = Tb or Eu) in a Y3Ga5O12 (YGG) host system. The additional doping of Bi^3+ can enhance the luminescence of Th^3+ or Eu^3+ in this host. Energy transfer from Bi^3+ to Tb^3+ and Eu^3+ is observed and the mechanism of energy transfer is investigated. Mechanism of energy transfer can be explained as electric multipole interaction since the Bi^3+ emission band and Tb^3+ or Eu^3+ excitation band overlaps and the Bi^3+ emission intensity decreases while the intensity of Tb^3+ or Eu^3+ increases with the increase of Tb^3+ or Eu^3+ concentration. Therefore, Bi^3+ ion is a kind of efficient sensitizer to the Tb^3+ and Eu^3+ activators in the Y3Ga5O12 host.

关 键 词:发光光谱  发光特征  能量传递        稀土元素

Luminescence Spectra of YGG:RE3+,Bi3+ RE= Eu and Tb) and Energy Transfer from Bi3+ to RE3+
ZHU Nan-Fei,LI Yong-Xiang,YU Xiao-Feng.Luminescence Spectra of YGG:RE3+,Bi3+ RE= Eu and Tb) and Energy Transfer from Bi3+ to RE3+[J].Chinese Physics Letters,2008,25(2):703-706.
Authors:ZHU Nan-Fei  LI Yong-Xiang  YU Xiao-Feng
Affiliation:[1]The State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai institute of Ceramics Chinese Academy of Sciences, Shanghai 200050 [2]Postgraduate School of the Chinese Academy of Sciences, Beijing 100049
Abstract:We investigate the luminescence properties of Bi3+ and RE3+ (RE = Tb or Eu) in a Y3Ga5O12 (YGG) host system. The additional doping of Bi3+ can enhance the luminescence of Tb3+ or Eu3+ in this host. Energy transfer from Bi3+ to Tb3+ and Eu3+ is observed and the mechanism of energy transfer is investigated. Mechanism of energy transfer can be explained as electric multipole interaction since the Bi3+ emission band and Tb3+ or Eu3+ excitation band overlaps and the Bi3+ emission intensity decreases while the intensity of Tb3+ or Eu3+ increases with the increase of Tb3+ or Eu3+ concentration.Therefore, Bi3+ ion is a kind of efficient sensitizer to the Tb3+ and Eu3+ activators in the Y3Ga5O12 host.
Keywords:78  55  -m  33  50  Dq  34  70  +e
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