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1.
Theoretical study of (e,2e) triple differential cross sections of pyrimidine and tetrahydrofurfuryl alcohol molecules using multi-center distorted-wave method 下载免费PDF全文
We report theoretical studies of electron impact triple differential cross sections of two bio-molecules,pyrimidine and tetrahydrofurfuryl alcohol,in the coplanar asymmetric kinematic conditions with the impact energy of 250 eV and ejected electron energy of 20 eV at three scattering angles of-5°,-10°,and-15°.Present multi-center distorted-wave method well describes the experimental data,which was obtained by performing(e,2e)experiment.The calculations show that the secondary electron produced by the primary impact electron is strongly influenced by the molecular ionic multi-center potential,which must be considered when the low energy electron interacts with DNA analogues. 相似文献
2.
Dr. Rong-Lin Zhong Dr. Feng-Wei Gao Dr. Hong-Liang Xu Prof. Zhong-Min Su 《Chemphyschem》2019,20(14):1879-1884
The nature of the 2e/12c bond and its conversion to a carbon-carbon single bond in phenalenyl dimers have prompted a great deal of interests recently. In this work, we theoretically investigated a series of π-stacking phenalenyl derivatives with 2e/12c bonding character by density functional theory (DFT) calculations to elucidate origin of this unusual bond conversion. Results show that bond-conversion of the phenalenyl dimer easily occurs at room-temperature both dynamically and thermodynamically. However, bond-conversion of hetero π-stacking adducts, in which the two center carbon atoms were substituted by boron and nitrogen atoms, respectively, is much more difficult, because the 2e/12c bond is stabilized by its charge transfer character. Consequently, the bond-conversion is an endothermic process, albeit with a low conversion barrier. Interestingly, Lewis acid-base interactions would be induced by substitution of the center nitrogen atom to phosphorus atom. The 2e/12c bond is further stabilized by 5.9 kcal mol−1 and its conversion is also thermodynamically unfavorable. 相似文献
3.
4.
Exponential H∞ synchronization for discrete‐time chaotic neural networks with time delays and stochastic perturbations via output feedback control 下载免费PDF全文
《Mathematical Methods in the Applied Sciences》2018,41(9):3282-3293
This paper investigates the problem of exponential H∞ synchronization of discrete‐time chaotic neural networks with time delays and stochastic perturbations. First, by using the Lyapunov‐Krasovskii (Lyapunov) functional and output feedback controller, we establish the H∞ performance of exponential synchronization in the mean square of master‐slave systems, which is analyzed using a matrix inequality approach. Second, the parameters of a desired output feedback controller can be achieved by solving a linear matrix inequality. Finally, 2 simulated examples are presented to show the effectiveness of the theoretical results. 相似文献
5.
In this paper,the authors consider the asymptotic behavior of the monic polynomials orthogonal with respect to the weight function w(x) = |x|~(2α)e~(-(x~4+tx~2)),x ∈ R,where α is a constant larger than -1/2 and t is any real number. They consider this problem in three separate cases:(i) c -2,(ii) c =-2,and(iii) c -2,where c := t N~(-1/2) is a constant,N = n + α and n is the degree of the polynomial. In the first two cases,the support of the associated equilibrium measure μ_t is a single interval,whereas in the third case the support of μ_t consists of two intervals. In each case,globally uniform asymptotic expansions are obtained in several regions. These regions together cover the whole complex plane. The approach is based on a modified version of the steepest descent method for Riemann-Hilbert problems introduced by Deift and Zhou(1993). 相似文献
6.
Bin Yang Feng Hong Junsheng Chen Yuxuan Tang Li Yang Youbao Sang Xusheng Xia Jingwei Guo Haixiang He Songqiu Yang Weiqiao Deng Keli Han 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(8):2300-2305
A series of lead‐free double perovskite nanocrystals (NCs) Cs2AgSb1?yBiyX6 (X: Br, Cl; 0≤y≤1) is synthesized. In particular, the Cs2AgSbBr6 NCs is a new double perovskite material that has not been reported for the bulk form. Mixed Ag–Sb/Bi NCs exhibit enhanced stability in colloidal solution compared to Ag–Bi or Ag–Sb NCs. Femtosecond transient absorption studies indicate the presence of two prominent fast trapping processes in the charge‐carrier relaxation. The two fast trapping processes are dominated by intrinsic self‐trapping (ca. 1–2 ps) arising from giant exciton–phonon coupling and surface‐defect trapping (ca. 50–100 ps). Slow hot‐carrier relaxation is observed at high pump fluence, and the possible mechanisms for the slow hot‐carrier relaxation are also discussed. 相似文献
7.
《Arabian Journal of Chemistry》2020,13(11):8424-8457
Nowadays, increasing extortions regarding environmental problems and energy scarcity have stuck the development and endurance of human society. The issue of inorganic and organic pollutants that exist in water from agricultural, domestic, and industrial activities has directed the development of advanced technologies to address the challenges of water scarcity efficiently. To solve this major issue, various scientists and researchers are looking for novel and effective technologies that can efficiently remove pollutants from wastewater. Nanoscale metal oxide materials have been proposed due to their distinctive size, physical and chemical properties along with promising applications. Cupric Oxide (CuO) is one of the most commonly used benchmark photocatalysts in photodegradation owing to the fact that they are cost-effective, non-toxic, and more efficient in absorption across a significant fraction of solar spectrum. In this review, we have summarized synthetic strategies of CuO fabrication, modification methods with applications for water treatment purposes. Moreover, an elaborative discussion on feasible strategies includes; binary and ternary heterojunction formation, Z-scheme based photocatalytic system, incorporation of rare earth/transition metal ions as dopants, and carbonaceous materials serving as a support system. The mechanistic insight inferring photo-induced charge separation and transfer, the functional reactive radical species involved in a photocatalytic reaction, have been successfully featured and examined. Finally, a conclusive remark regarding current studies and unresolved challenges related to CuO are put forth for future perspectives. 相似文献
8.
In this article, a multiobjective problem with a feasible set defined by inequality, equality and set constraints is considered, where the objective and constraint functions are locally Lipschitz. Several constraint qualifications are given and the relations between them are analyzed. We establish Kuhn-Tucker and strong Kuhn-Tucker necessary optimality conditions for (weak) quasi e?ciency in terms of the Clarke subdifferential. By using two new classes of generalized convex functions, su?cient conditions for local (weak) quasi e?cient are also provided. Furthermore, we study the Mond-Weir type dual problem and establish weak, strong and converse duality results. 相似文献
9.
In this paper, the asymptotic behavior of the weak solution (u_t)_{t\ge0} to the non-local Cauchy problems as stated in (1) is considered. Only using lower bounds of jumping kernel J(x,y) for large |x-y|, it is obtained that \|u_t\|_p\le c(t)\|u_0\|_q with any 1\le q
相似文献
10.
The resilient dissipative dynamic output feedback control problem for a class of uncertain Markov jump Lur’e systems with piecewise homogeneous transition probabilities and time-varying delays in the discrete-time domain are examined in this study. The designed controller can tolerate additive uncertainties in the controller gain matrix, which result from controller implementations. The time-varying delays are also supposed to be mode-dependent with lower and upper bounds known a priori. By constructing a Lyapunov–Krasovskii functional candidate, the sufficient conditions regarding the existence of desired resilient dissipative controllers are obtained in terms of linear matrix inequalities, thereby ensuring that the resulting closed-loop system is stochastically stable and strictly dissipative. Two numerical examples were established to illustrate the effectiveness of the proposed theoretical results. 相似文献