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Mo Back Contact for Flexible Polyimide Substrate Cu(In,Ga)Se2 Thin-Film Solar Cells
引用本文:张力,何青,姜伟龙,刘芳芳,李长健,孙云.Mo Back Contact for Flexible Polyimide Substrate Cu(In,Ga)Se2 Thin-Film Solar Cells[J].中国物理快报,2008,25(9):3452-3454.
作者姓名:张力  何青  姜伟龙  刘芳芳  李长健  孙云
作者单位:The Tianjin Key Laboratory for Photoelectronic Thin Film Devices and Technology, Nankai University, Nankai University, Tianjin 300071
基金项目:Supported by the National High-Tech Research and Development Programme of China under Grant No 2004AA513020.
摘    要:A dc magnetic sputtering process is applied to growth of a Mo back. contact layer onto the flexible polyimide (PI) and rigid soda-lime glass (SLC) substrates. The structural and electrical properties of the Mo layer coated on the two kinds of substrates are investigated by x-ray diffraction (XRD) and Hall effect measurements. The results show that the Mo layer on SLG indicate more better crystal quality and lower resistivity than that on the PI sheets. In contrast to the SLG substrate, the resistivity of the Mo layer on PI is increased by the vacuum annealing process at the substrate temperature of 450℃ under Se atmosphere, which is attributed to the cracked Mo layer induced by the mismatch of the coefficient of thermal expansion between PI and Mo material. The Cu(In,Ga)Se2 (CIGS) solar cells based on the PI and SLO substrates show the best conversion efficiencies of 8.16% and 10.98% (active area, 0.2cm^2), respectively. The cell efficiency of flexible CIGS solar cells on PI is limited by its relatively lower fill factor caused by the Mo back contact.

关 键 词:薄膜太阳能电池  聚酰亚胺    静合接点  磁反应溅射法
收稿时间:2008-5-11

Mo Back Contact for Flexible Polyimide Substrate Cu(In, Ga)Se2 Thin-Film Solar Cells
ZHANG Li,HE Qing,JIANG Wei-long,LIU Fang-fang,LI Chang-Jian,SUN Yun.Mo Back Contact for Flexible Polyimide Substrate Cu(In, Ga)Se2 Thin-Film Solar Cells[J].Chinese Physics Letters,2008,25(9):3452-3454.
Authors:ZHANG Li  HE Qing  JIANG Wei-long  LIU Fang-fang  LI Chang-Jian  SUN Yun
Affiliation:The Tianjin Key Laboratory for Photoelectronic Thin Film Devices and Technology, Nankai University, Nankai University, Tianjin 300071
Abstract:A dc magnetic sputtering process is applied to growth of a Mo back contact layer onto the flexible polyimide (PI) and rigid soda-lime glass (SLG) substrates. The structural and electrical properties of the Mo layer coated on the two kinds of substrates are investigated by x-ray diffraction (XRD) and Hall effect measurements. The results show that the Mo layer on SLG indicate more better crystal quality and lower resistivity than that on the PI sheets. In contrast to the SLG substrate, the resistivity of the Mo layer on PI is increased by the vacuum annealing process at the substrate temperature of 450°C under Se atmosphere, which is attributed to the cracked Mo layer induced by the mismatch of the coefficient of thermal expansion between PI and Mo material. The Cu(In,Ga)Se2 (CIGS) solar cells based on the PI and SLG substrates show the best conversion efficiencies of 8.16% and 10.98% (active area, 0.2cm2), respectively. The cell efficiency of flexible CIGS solar cells on PI is limited by its relatively lower fill factor caused by the Mo back contact.
Keywords:81  05  Bx  68  55  Jk  81  15  Cd  84  60  Jt
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