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Adsorption of flexible polymers on small colloids: complexes and gels
Authors:S. Diez Orrite  J. Bonet Avalos  A. Johner  J.F. Joanny
Affiliation:1. Departament d'Enginyeria Quimica, ETSEQ, University Rovira i Virgili, Avinguda dels Països Catalans, 26, Campus Sesceslades, 43007, Tarragona, Spain;2. Institut Charles Sadron, 6 rue Boussingault 67083 Strasbourg, France
Abstract:We describe adsorption of neutral flexible polymer chains onto small colloids that can be covered by one chain. We discuss the structure of star-shaped complexes and their abundance in dilute solution. In semi-dilute solution similar complexes form crosslinks between chains and cause gelation.
Keywords:adsorption  colloids  gels
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