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1.
2.
[Na(18-C-6)]2[Cu(i-mnt)2]的合成与结构分析 总被引:2,自引:2,他引:0
研究了18-冠-6与Na2[Cu(i-mnt)2][i-mnt=异丁二腈烯二硫醇阴离子,S2CC(CN)2-2]的反应,得到的配合物[Na(18-C-6)]2[Cu(i-mnt)2](1)通过元素分析、红外光谱、X射线单晶衍射进行了结构分析.配合物为单斜晶系,空间群P2(1)/c.晶体学结构数据a=1.2819(11),b=1.1793(10),c=1.4928(13)nm,β=99.121(16)°,V=2.228(3)nm3,Z=2,Dcaled.=1.369g/cm3,F(000)=958,R1=0.0521,wR2=0.1003.1中的[Cu(i-mnt)2]基团通过配体i-mnt的氮原子与两个[Na(18-C-6)]基团中的钠原子成键,形成稳定的中性配合物. 相似文献
3.
On Best Approximations from RS-sets in Complex Banach Spaces 总被引:2,自引:0,他引:2
ChongLI 《数学学报(英文版)》2005,21(1):31-38
The concept of an RS-set in a complex Banach space is introduced and the problem of best approximation from an RS-set in a complex space is investigated. Results consisting of characterizations, uniqueness and strong uniqueness are established, 相似文献
4.
室温下,通过双核配合物[Cu(dppm)(NO3)]2(dppm=双二苯基膦甲烷)与四苯基硼钠在甲醇和二氯甲烷混合溶剂中反应制备了三核铜(I)配合物[Cu3(dppm)3(NO3)(OH)](NO3),经过红外光谱、热重分析、核磁和ES-MS等现代分析手段表征了配合物的物理化学性质,并进一步研究了配合物在室温下的荧光光谱特征。 相似文献
5.
6.
Nick Peatfield 《Archive for Mathematical Logic》2006,45(6):739-768
Following the introduction and preliminary investigations of analytic Zariski structures in Peatfield and Zilber (Ann pure Appl Logic 132:125–180, 2005) an example of an analytic Zariski structure extending an algebraically closed field is provided. The example is constructed using Hrushovski’s method of free amalgamation, and a topology is introduced in which we can verify the analytic Zariski axioms. 相似文献
7.
This article proves the existence of singular directions of value distribution theory for some transcendental holomorphic curves in the n-dimensional complex projective space Pn(C). An example is given to complement these results. 相似文献
8.
R. Percacci A. Vespignani 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,32(4):411-414
Measurements and data analysis have proved very effective in the study of the Internet's physical fabric and have shown heterogeneities
and statistical fluctuations extending over several orders of magnitude. Here we focus on the relationship between the Round-Trip-Time
(RTT) and the geographical distance. We define dimensionless variables that contain information on the quality of Internet
connections finding that their probability distributions are characterized by a slow power-law decay signalling the presence
of scale-free features. These results point out the extreme heterogeneity of Internet delay since the transmission speed between
different points of the network exhibits very large fluctuations. The associated scaling exponents appear to have fairly stable
values in different data sets and thus define an invariant characteristic of the Internet that might be used in the future
as a benchmark of the overall state of “health” of the Internet.
Received 25 January 2003 Published online 7 May 2003 相似文献
9.
Tris(tropolonato)neodimium( Ⅲ )has been prepared by the electrochemical oxidation of neodimium meral anode in acetonitrile solution of 2-hydroxy - 2,4,6 - cycloheptatrienone(tropolone). The unusual divalent neodimium complex was formed at the first step of electrosyn - thesis. The final product ,Nd (C7H6O2)3, has been characterized by microanalysis and the studies of IR and H, C3 NMR spectra. 相似文献
10.
This paper proposes a floating-point genetic algorithm (FPGA) to solve the unit commitment problem (UCP). Based on the characteristics of typical load demand, a floating-point chromosome representation and an encoding–decoding scheme are designed to reduce the complexities in handling the minimum up/down time limits. Strategic parameters of the FPGA are characterized in detail, i.e., the evaluation function and its constraints, population size, operation styles of selection, crossover operation and probability, mutation operation and probability. A dynamic combination scheme of genetic operators is formulated to explore and exploit the FPGA in the non-convex solution space and multimodal objective function. Experiment results show that the FPGA is a more effective technique among the various styles of genetic algorithms, which can be applied to the practical scheduling tasks in utility power systems. 相似文献