锡苯和铅苯二聚反应的理论研究

采用密度泛函理论B3LYP方法,研究了锡苯和铅苯的[2+2],[4+2]及[4+4]二聚反应的微观机理和势能剖面,考察了Sn(Pb)原子上的2,4,6-三甲基苯基(Mes)取代基对反应势能剖面的影响.研究结果表明,所有反应均为协同过程,且大多数情况下,2个C—Sn(Pb)键同步形成.[2+2]和[4+2]反应在热力学和动力学上均比相应的[4+4]反应容易进行,而[4+2]反应在动力学上比相应的[2+2]反应有利.Sn(Pb)原子上的Mes取代基在热力学和动力学上均不利于反应的进行.铅苯的动力学稳定性与锡苯相当,但其热力学稳定性高于锡苯.     

格点Chern-Simons理论的量子化

讨论了Chern-Simons理论的naive格点化,并就其中最简单的一种情形用Dirac约束体系量子化方法进行量子化.由此显示naive格点化的缺陷,找出了克服这一困难的办法.求出了anyon产生算符.     

玻璃陶瓷材料中Tm3+离子红外到蓝色上转换发光

系统研究了PbF2+GeO2+WO3ⅩⅣTmF3玻璃陶瓷材料中,在近红外光(1.06μm)激发下,Tm3+离子的发光特性.实验中观测到Tm3+离子的两组峰值位置分别在20920cm-1和22173cm-1的蓝色上转换发光,并证实这两组上转换发光分别与吸收三个和四个光子有关,同时建立了上转换发光的模型.为了选择最佳掺杂浓度,详细地测量了Tm3+离子峰值为20920cm-1的蓝色上转换发光强度与TmF3浓度的关系.     

凸域内单叶函数的导数

设函数f（w）为凸区域D内的单叶解析函数,对于2≤n≤8和所有w∈D,本文得到估计式|f（n）（w）/f＇（w）|的精确上界.这个结果推广了一些已知的结论.     

高考数学的一个新亮点——猜想题

猜想是对所要研究的问题依据已有材料、条件和知识，进行实验、观察、分析、比较、联想、类比、归纳、推理等，作出符合一定的经验与事实的推测性想象的思维方法．牛顿指出：“没有大胆的猜想，就做不出伟大的发现”。猜想是发现问题、解决问题的一种重要的思维方法，是创新思维的重要组成部分，猜想也是数学发展的动力，数学理论的重大突破往往起源于立意深邃的猜想，正是无数数学家们的猜想，数学科学才发展到当今的现代数学。由于猜想可让学生体验数学发现和创造的历程，培养和发展他们的创新思维和合情推理能力，更能体现高考的选拔功能，因此近几年猜想题倍受高考命题老师的亲睐，成为高考数学题的一个新亮点．本文试对这类题型及解法作一综述，供参考．     

Theoretical Research on a Kind of Quantum Left-handed Metamaterial

Recently, research on left-handed materials （LHMs） has attracted considerable attentions. The LHMs are a kind of metameterial which have negative permittivity and negative permeability, which lead to negative refractive index in a frequency range. The LHMs that have been available so far are in the microwave range and are usually composed of classical particles, such as split-ring resonators. Some quantum phenomena such as spontaneous emission of atoms in the LHMs which are considered to be ＇classical background＇ have also been investigated. Many potential applications of LHMs have been proposed, such as superlenses which, in principle, can achieve arbitrary subwavelength resolution.     

A Reliability Analysis of Calculated Results for Odd-Even and Odd-Odd Nuclei in Relativistic Mean-Field Theory

We calculate the binding energies of Ni, Cu, Xe, Cs, Pt, Au, Np, Pu isotope chains using two interaction parameter sets NL-3 and NL-Z, and compared the relative errors of the even-even nuclei with those of odd-even nuclei and odd-odd nuclei. We find that the errors of binding energy of odd-even and odd-odd nuclei are not bigger than the one of even-even nuclei. The result shows that comparing with even-even nuclei, there is no systematic error and approximation in the calculations of the binding energy of odd-even and odd-odd nuclei with relativistic mean-field theory. In addition, the result is explained theoretically.     

Advances in micro-perforated panel absorbers

Theoretical and experimental investigations on the performance of micro-perforated -panel absorbers are reviewed in this paper. By reviewing recent research work, this paper reveals a relationship between the maximum absorption coefficient and the limit of the absorption frequency bandwidth. It has been demonstrated that the absorption frequency bandwidth can be extended up to 3 or 4 octaves as the diameters of the micro-holes decrease. This has become possible with the development of the technologies for manufacturing micro-perforated panels, such as laser drilling, powder metallurgy, welded meshing and electro-etching to form micrometer order holes. In this paper, absorption characteristics of such absorbers in random fields and in high sound intensity are discussed both theoretically and experimentally. A new absorbing structure based on micro-perforated-panel absorbers demonstrate experimentally high sound absorption capability. This review shows that the micro-perforated-panel absorber has potentials to be one of ideal absorbing materials in the 21st century.     

珠算算理浅论

四、远古时代数学发展的可能性 （一）度量单位的发展用尺量长度实际早已有记载。1976年上海人民出版社出版《中国古代的发明创造》一书揭示，公元前2698年以后，已有尺，其尺折24.88厘米，该尺以九为进制，足见我国在4700年前对长度就有了研究。关于长度的研究是不是更远一些，有待进一步考证，若伏羲研究的矩有数量关系，那么可以把历史推进7000年。尺的出现不是小事。它说明数轴已经出现。黄帝时有尺，说明中国有了历史可载的“数”学，数学理性化已经开始，“隶首作数”决不是虚言。这个数学经过大禹时代可能因治水的需要，得到了很大的发展，到了商代周代数学已经达到理性化的一个顶峰。     

NA列加权乘积和的完全收敛性

本文讨论了NA和几类加权部分和及加权乘积和的完全收敛性，其中部分结果要优于iid列的已知结论。