Cr^4＋：YAG可饱和吸收特性测量

测量了Cr4+:YAG材料的可饱和吸收特性,用多种数据分析方法处理了实验结果,Cr4+:YAG的基态吸收截面σgs=11×10-19cm2,激发态吸收截面σes=1.2×10-19cm2。     

Output dynamics and stabilisation of a multi-mode double-clad Yb-doped silica fibre laser

The intensity dynamics of the double-clad Yb fibre laser have been characterised. Stabilisation of the fibre laser intensity by using uniform bi-directional pumping is demonstrated. For the single-end-pumped Yb fibre laser, the output becomes more stable for the shorter fibre length due to the higher threshold of stimulated Brillouin scattering, SBS, and Kerr effects and the reduction of saturated absorber effects caused by any unpumped fibre section. By additional pumping in a double-end-pumped configuration, the output power can be scaled higher before detecting high intensity pulses initiated by SBS in the Yb fibre laser due to the reduction of saturable absorption effect. It is confirmed that uniform pumping enhances the stability of the laser output.     

Diode-end-pumped Nd:YAGLaser with Cr4+:YAG as Passive Q-switch

A diode-end-pumped Nd:YAG laser is passively Q-switched by using Cr4+:YAG as saturable absorber. When CW pumped with a laser diode which the maximum power is 550 mW, the laser produces pulses of 24 ns duration at 1064 nm, with an energy of 26 μJ.     

Spectral Properties and Solubilization Location of 2'-Ethylhexyl 4-(N,N-Dimethylamino)benzoate in Micelles

Dual fluorescence and UV absorption of 2'-ethylhexyl 4-(N,N-dimethylamino)benzoate (EHDMAB) were investigated in cationic, non-ionic and anionic micelles. When EHDMAB was solubilized in different micelles, the UV absorption of EHDMAB was enhanced. Twisted intramolecular charge transfer (TICT) emission with longer wavelength was observed in ionic micelles, whereas TICT emission with shorter wavelength was obtained in non-ionic micelles. In particular, dual fluorescence of EHDMAB was significantly quenched by the positively charged pyridinium ions arranged in the Stern layer of cationic micelles. UV radiation absorbed mainly decays via TICT emission and radiationless deactivation. The dimethylamino group of EHDMAB experiences different polar environments in ionic and non-ionic micelles according to the polarity dependence of TICT emission of EHDMAB in organic solvents. In terms of the molecular structures and sizes of EHDMAB and surfactants, each individual EHDMAB molecule should be buried in micelles with its dimethylamino group toward the polar head groups of different micelles and with its 2'-ethylhexyl chain toward the hydrophobic micellar core. Dynamic fluorescence quenching measurements of EHDMAB provide further support for the location of EHDMAB in different micelles.     

超低频率全正色散半导体可饱和吸收镜被动锁模光纤激光器

通过延长激光器环形腔腔长,利用高浓度掺杂的单模掺镱光纤,搭建了超低重复频率、全正色散结构的半导体可饱和吸收镜被动锁模光纤激光器。激光器的中心波长、重复频率、平均功率及单脉冲能量分别为1 064 nm,281.5 kHz,11 mW和39 nJ。为了稳定中心波长,实现自启动,激光器腔体内接入了一个带通滤波器。该激光器运行稳定,无调Q不稳定现象,极大减小了半导体可饱和吸收镜被损坏的机会。     

Ultraviolet light absorber with low surface energy: synthesis and characterization

Novel fluorine-containing ultraviolet absorbers (FBPs) with low surface energy were successfully synthesized based on 2,4-dihydroxy benzophenone (BP-1), and their structures were characterized by ¹H NMR, ¹³C NMR, FTIR, and HRMS. UV absorption of FBPs was studied in 10⁻⁴ M dichloromethane (CH₂Cl₂), which demonstrated the superior UV absorption capability of FBPs (ca. ?=1.7×10⁴ to 2.2×10⁴ at λ_max) over the matrix (?=1.7×10⁴ at λ_max). Quantum chemistry calculation was performed to investigate the stable structure and UV electronic absorption bands of FBPs. The surface chemistry information of high-chlorinated polyethylene (HCPE) coating films embedded with ultraviolet absorbers (UVAs) was given by X-ray photoelectron spectroscopy (XPS) and contact angle measurement. The results show that the surface enrichment capability of FBPs is remarkably better than traditional UVAs (including BP-1, BP-3, BP-12) because of the low surface energy properties of FBPs.     

Beyond Perovskite Solar Cells: Tellurium Iodide as a Promising Light‐Absorbing Material for Solution‐Processed Photovoltaic Application

Searching new light‐absorbing materials to replace toxic lead halide in solar cells is very important and highly desirable. In this research, we firstly demonstrated that tellurium iodide (TeI₄) could be used as a light‐absorbing material in solar cells due to its suitable optical band gap and the active lone‐pair electron orbital in Te⁴⁺. The best power conversion efficiency (PCE=3.56%) was achieved with a concentration of 0.9 M TeI₄ in DMF:DMSO (4 : 1, v,v) without any heat treatment or antisolvent dripping. Our study indicates the promising potential of TeI₄ for photovoltaic and optoelectronic applications.     

Simulation of Organic Liquid Product Deoxygenation through Multistage Countercurrent Absorber/Stripping Using CO2 as Solvent with Aspen-HYSYS: Process Modeling and Simulation

In this work, the deoxygenation of organic liquid products (OLP) obtained through the thermal catalytic cracking of palm oil at 450 °C, 1.0 atmosphere, with 10% (wt.) Na₂CO₃ as a catalyst, in multistage countercurrent absorber columns using supercritical carbon dioxide (SC-CO₂) as a solvent, with an Aspen-HYSYS process simulator, was systematically investigated. In a previous study, the thermodynamic data basis and EOS modeling necessary to simulate the deoxygenation of OLP was presented. This work addresses a new flowsheet, consisting of 03 absorber columns, 10 expansions valves, 10 flash drums, 08 heat exchanges, 01 pressure pump, and 02 make-ups of CO₂, aiming to improve the deacidification of OLP. The simulation was performed at 333 K, 140 bar, and (S/F) = 17; 350 K, 140 bar, and (S/F) = 38; 333 K, 140 bar, and (S/F) = 25. The simulation shows that 81.49% of OLP could be recovered and that the concentrations of hydrocarbons in the extracts of absorber-01 and absorber-02 were 96.95 and 92.78% (wt.) on a solvent-free basis, while the bottom stream of absorber-03 was enriched in oxygenated compounds with concentrations of up to 32.66% (wt.) on a solvent-free basis, showing that the organic liquid products (OLP) were deacidified and SC-CO₂ was able to deacidify the OLP and obtain fractions with lower olefin contents. The best deacidifying condition was obtained at 333 K, 140 bar, and (S/F) = 17.     

Design of a tuned vibration absorber for a slender hollow cylindrical structure

Abstract

In this paper, details of the design work for a tuned vibration absorber to be used on a hollow cylindrical structure is presented. The vibration problem is of resonant type and the tuned vibration absorber is designed to suppress the displacement vibration response of the free end of the slender hollow structure dominated by the contribution of its lowest transverse vibration modes. The structure is modeled using a commercial finite element software. Finite element model of the structure is verified using experimentally obtained frequency response functions and modal parameters. Effective parameters of the tuned vibration absorber design are then determined based on finite element analysis simulations of the vibration suppression performance of the tuned vibration absorber as it is used on the structure. Details of the tuned vibration absorber design are determined and a prototype is fabricated. Prototype tuned vibration absorber is then characterized experimentally both as a standalone system and also as it is used on the main structure. Vibration reduction performance of the physical prototype of the tuned vibration absorber is also compared with its vibration reduction performance estimated from finite element analysis simulations so that the analysis based design process can be validated.

Communicated by Dumitru Caruntu.