全文获取类型
收费全文 | 40490篇 |
免费 | 7519篇 |
国内免费 | 6459篇 |
专业分类
化学 | 20029篇 |
晶体学 | 533篇 |
力学 | 1844篇 |
综合类 | 512篇 |
数学 | 3610篇 |
物理学 | 11713篇 |
无线电 | 16227篇 |
出版年
2024年 | 173篇 |
2023年 | 794篇 |
2022年 | 1390篇 |
2021年 | 1483篇 |
2020年 | 1549篇 |
2019年 | 1452篇 |
2018年 | 1302篇 |
2017年 | 1465篇 |
2016年 | 1609篇 |
2015年 | 1992篇 |
2014年 | 2415篇 |
2013年 | 3004篇 |
2012年 | 3491篇 |
2011年 | 3558篇 |
2010年 | 2970篇 |
2009年 | 3124篇 |
2008年 | 3201篇 |
2007年 | 2934篇 |
2006年 | 2771篇 |
2005年 | 2291篇 |
2004年 | 1721篇 |
2003年 | 1344篇 |
2002年 | 1297篇 |
2001年 | 1238篇 |
2000年 | 1053篇 |
1999年 | 821篇 |
1998年 | 530篇 |
1997年 | 548篇 |
1996年 | 474篇 |
1995年 | 388篇 |
1994年 | 375篇 |
1993年 | 285篇 |
1992年 | 215篇 |
1991年 | 208篇 |
1990年 | 192篇 |
1989年 | 142篇 |
1988年 | 132篇 |
1987年 | 105篇 |
1986年 | 77篇 |
1985年 | 55篇 |
1984年 | 60篇 |
1983年 | 53篇 |
1982年 | 46篇 |
1981年 | 32篇 |
1980年 | 25篇 |
1979年 | 16篇 |
1977年 | 7篇 |
1976年 | 9篇 |
1975年 | 9篇 |
1959年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
3.
Qianqian Fan Zirui Liu Feng Qiu Prof. Yong Mao Prof. Qingju Liu Prof. Longzhou Zhang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(63):e202202700
The artificially accurate design of nonmetal electrocatalysts’ active site has been a huge challenge because no pure active species with the specific structure could be strictly controlled by traditional synthetic methods. Species with a multiconfiguration in the catalyst hinder identification of the active site and the subsequent comprehension of the reaction mechanism. We have developed a novel electro-assisted molecular assembly strategy to obtain a pure pentagon ring on perfect graphene avoiding other reconstructed structures. More importantly, the active atom was confirmed by the subtle passivation process as the topmost carbon atom. Recognition of the carbon-defect electrocatalysis reaction mechanism was first downsized to the single-atom scale from the experimental perspective. It is expected that this innovative electro-assisted molecular assembly strategy could be extensively applied in the active structure-controlled synthesis of nonmetal electrocatalysts and verification of the exact active atom. 相似文献
4.
5G系统将移动通信服务从移动电话、移动宽带和大规模机器通信扩展到新的应用领域,即所谓对通信服务有特殊要求的垂直领域。对使能未来工厂的5G能力进行了全面的分析总结,包括弹性网络架构、灵活频谱、超可靠低时延通信、时间敏感网络、安全和定位,而弹性网络架构又包括对网络切片、非公共网络、5G局域网和边缘计算的支持。希望从广度到深度,对相关的理论及技术应用做透彻、全面的梳理,对其挑战做清晰的总结,从而为相关研究和工程技术人员提供借鉴。 相似文献
5.
Photoresponsive biomaterials are experiencing a transition from in vitro models to in vivo demonstrations that point toward clinical translation. Dynamic hydrogels for cell encapsulation, light-responsive carriers for controlled drug delivery, and nanomaterials containing photosensitizers for photodynamic therapy are relevant examples. Nonetheless, the step to the clinic largely depends on their combination with technologies to bring light into the body. This review highlights the challenge of photoactivation in vivo, and presents strategies for light management that can be adopted for this purpose. The authors’ focus is on technologies that are materials-driven, particularly upconversion nanoparticles that assist in “direct path” light delivery through tissue, and optical waveguides that “clear the path” between external light source and in vivo target. The authors’ intention is to assist the photoresponsive biomaterials community transition toward medical technologies by presenting light delivery concepts that can be integrated with the photoresponsive targets. The authors also aim to stimulate further innovation in materials-based light delivery platforms by highlighting needs and opportunities for in vivo photoactivation of biomaterials. 相似文献
6.
7.
Shuhai Liu Ming Han Xiaolong Feng Qiuhong Yu Long Gu Longfei Wang Yong Qin Zhong Lin Wang 《Advanced functional materials》2021,31(17):2010339
Utilizing inner-crystal piezoelectric polarization charges to control carrier transport across a metal-semiconductor or semiconductor–semiconductor interface, piezotronic effect has great potential applications in smart micro/nano-electromechanical system (MEMS/NEMS), human-machine interfacing, and nanorobotics. However, current research on piezotronics has mainly focused on systems with only one or rather limited interfaces. Here, the statistical piezotronic effect is reported in ZnO bulk composited of nanoplatelets, of which the strain/stress-induced piezo-potential at the crystals’ interfaces can effectively gate the electrical transport of ZnO bulk. It is a statistical phenomenon of piezotronic modification of large numbers of interfaces, and the crystal orientation of inner ZnO nanoplatelets strongly influence the transport property of ZnO bulk. With optimum preferred orientation of ZnO nanoplatelets, the bulk exhibits an increased conductivity with decreasing stress at a high pressure range of 200–400 MPa, which has not been observed previously in bulk. A maximum sensitivity of 1.149 µS m−1 MPa−1 and a corresponding gauge factor of 467–589 have been achieved. As a statistical phenomenon of many piezotronic interfaces modulation, the proposed statistical piezotronic effect extends the connotation of piezotronics and promotes its practical applications in intelligent sensing. 相似文献
8.
Recently, the successful synthesis of wafer-scale single-crystal graphene, hexagonal boron nitride (hBN), and MoS2 on transition metal surfaces with step edges boosted the research interests in synthesizing wafer-scale 2D single crystals on high-index substrate surfaces. Here, using hBN growth on high-index Cu surfaces as an example, a systematic theoretical study to understand the epitaxial growth of 2D materials on various high-index surfaces is performed. It is revealed that hBN orientation on a high-index surface is highly dependent on the alignment of the step edges of the surface as well as the surface roughness. On an ideal high-index surface, well-aligned hBN islands can be easily achieved, whereas curved step edges on a rough surface can lead to the alignment of hBN along with different directions. This study shows that high-index surfaces with a large step density are robust for templating the epitaxial growth of 2D single crystals due to their large tolerance for surface roughness and provides a general guideline for the epitaxial growth of various 2D single crystals. 相似文献
9.
在公交时间表下给定起始和目标站点,路径规划查询返回一组到达时间早和换乘次数少的帕雷托最优路径.现有的索引方法需要大量运行时内存.本文提出主存空间高效的索引方法(a-)PAINT.(a-)PAINT对每个站点v预计算一组标签,使得对于从站点s到站点d的查询可以通过匹配s和d相关的标签高效地生成查询结果的一条路径.PAINT对任意查询返回最优路径.a-PAINT只需要很小的预处理开销,但可能返回多一趟换乘的次优路径.用真实的公交时间表与模拟查询测试,PAINT具有合理的预处理开销.a-PAINT需要更少量的预处理开销,在大规模公交网络下准确率达90%. 相似文献