全文获取类型
收费全文 | 66972篇 |
免费 | 12780篇 |
国内免费 | 17304篇 |
专业分类
化学 | 48050篇 |
晶体学 | 2034篇 |
力学 | 4695篇 |
综合类 | 1681篇 |
数学 | 9419篇 |
物理学 | 31177篇 |
出版年
2024年 | 181篇 |
2023年 | 972篇 |
2022年 | 2393篇 |
2021年 | 2527篇 |
2020年 | 2604篇 |
2019年 | 2627篇 |
2018年 | 2357篇 |
2017年 | 2857篇 |
2016年 | 2840篇 |
2015年 | 3426篇 |
2014年 | 4220篇 |
2013年 | 5434篇 |
2012年 | 5774篇 |
2011年 | 6146篇 |
2010年 | 5278篇 |
2009年 | 5247篇 |
2008年 | 5882篇 |
2007年 | 5146篇 |
2006年 | 5061篇 |
2005年 | 4140篇 |
2004年 | 3259篇 |
2003年 | 2278篇 |
2002年 | 2384篇 |
2001年 | 2216篇 |
2000年 | 2324篇 |
1999年 | 1583篇 |
1998年 | 997篇 |
1997年 | 870篇 |
1996年 | 841篇 |
1995年 | 724篇 |
1994年 | 646篇 |
1993年 | 585篇 |
1992年 | 535篇 |
1991年 | 436篇 |
1990年 | 392篇 |
1989年 | 333篇 |
1988年 | 275篇 |
1987年 | 241篇 |
1986年 | 221篇 |
1985年 | 153篇 |
1984年 | 134篇 |
1983年 | 129篇 |
1982年 | 82篇 |
1981年 | 69篇 |
1980年 | 48篇 |
1979年 | 46篇 |
1978年 | 18篇 |
1971年 | 11篇 |
1965年 | 24篇 |
1959年 | 16篇 |
排序方式: 共有10000条查询结果,搜索用时 468 毫秒
1.
Zhihong Zhao Bin Wang Rui Tan Wenjing Liu Minghui Zhang 《Magnetic resonance in chemistry : MRC》2022,60(4):427-433
In this study, the transverse relaxation time (T2) of activated carbon (AC) in different relative environment humidity was detected firstly by low-field nuclear magnetic resonance (LFNMR). The pore size (diameter) of AC distributions was calculated by the relationship between T2 and surface relaxation rate (ρ), where ρ was obtained by the detection of nine porous materials with known pore size. The results showed that the pore size distributions of AC calculated by ρ < 0.19 nm/ms were in good agreement with that obtained by nitrogen adsorption method and proved that LFNMR as a new detection method was feasible for characterizing AC pore size distribution. 相似文献
2.
Zhang Bing Yang Jie-qin Liu Ying Hu Bin Yang Yang Zhao Li Lu Qiang 《Cellulose (London, England)》2022,29(12):6565-6578
Cellulose - Heating is essential in various biomass pre-treatments and thermal conversion processes. It is of practical significance to study the characteristics of cellulose-lignin and... 相似文献
3.
Dan Chen Kaixin Du Xiaochen Niu Hongwei Zhang Xue Zhang Yu Tang Jianchun Zhao 《Biomedical chromatography : BMC》2022,36(3):e5288
Amlexanox, an anti-inflammatory and anti-allergic agent, has been widely used clinically for the treatment of canker sores, asthma, and allergic rhinitis. Recently, amlexanox has received considerable attention in curing nonalcoholic fatty liver diseases and hepatitis virus infection. Herein, we first established a sensitive high-performance liquid chromatography-tandem mass spectrum (LC–MS/MS) method for the determination of amlexanox in rat plasma. Propranolol was used as the internal standard (IS). Using a simple protein precipitation method, the amlexanox and IS were separated with Capcell Pak C18 column (2.0 × 50 mm, 5 μm) and eluted with water and acetonitrile each containing 0.1% formic acid using gradient elution condition at a flow rate of 0.4 mL·min−1. Amlexanox and IS were detected by a triple quadrupole mass in multiple reactive monitoring (MRM) under the transitions of m/z 299.2 → 281.2 and m/z 259.9 → 116.1 with positive electrospray ionization, respectively. The calibration curves of amlexanox were established with the range of 50 to 2000 ng·mL−1 (r2 > 0.99). The validation method consisted of selectivity, accuracy, precision, carryover effect, matrix effect, recovery, dilution effect, and stability. The fully validated method was successfully applied to the pharmacokinetic study of amlexanox in Wistar rats. 相似文献
4.
Cellulose - In this research, the production of levoglucosan (LG) and levoglucosenone (LGO) was improved from acid-impregnated cellulose via fast pyrolysis. Thermogravimetric and kinetic analysis... 相似文献
6.
Edward G. Sheetz Zhao Zhang Alyssa Marogil Minwei Che Dr. Maren Pink Dr. Veronica Carta Prof. Dr. Krishnan Raghavachari Prof. Dr. Amar H. Flood 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(60):e202201584
The recognition of boron compounds is well developed as boronic acids but untapped as organotrifluoroborate anions (R−BF3−). We are exploring the development of these and other designer anions as anion-recognition motifs by considering them as substituted versions of the parent inorganic ion. To this end, we demonstrate strong and reliable binding of organic trifluoroborates, R−BF3−, by cyanostar macrocycles that are size-complementary to the inorganic BF4− progenitors. We find that recognition is modulated by the substituent's sterics and that the affinities are retained using the common K+ salts of R−BF3− anions. 相似文献
7.
Applied Mathematics and Mechanics - Spiral springs have a wide range of applications in various fields. As a result of the complexity of friction, few theoretical analyses of spring belts under... 相似文献
8.
Geometriae Dedicata - Inspired by a recent work of Grove and Petersen (Alexandrov spaces with maximal radius, 2018), where the authors studied positively curved Alexandrov spaces with largest... 相似文献
9.
10.
硒是动植物及人体生长必需的十五种微量元素之一,具有清除体内自由基、抗氧化、增强免疫力等功能,但其安全剂量的范围却很窄。利用扫描电子显微镜(SEM)和X射线衍射仪(XRD)对湿法球磨制备的硫铁矿形貌进行了表征。SEM观测发现加乙醇助磨后的硫铁矿为粒径大小较均匀的球形颗粒团聚体,粒径范围在17~200 nm之间,平均粒径138 nm。XRD衍射图谱中的特征峰与FeS2衍射图谱中各峰位置基本一致,因此判定硫铁矿中主要化学组分为FeS2,且图谱中基本没有杂峰,表明制备过程中并未混入杂质,样品纯度较高。实验结果表明,该法制备的硫铁矿具有颗粒粒径小、比表面积大、反应活性高等优点。研究中利用X射线光电子能谱仪(XPS)对硫铁矿去除水体中SeO2-3的机理进行了研究。研究结果表明, (1)在较为广泛的实验pH范围(pH 2.2~11.5),硫铁矿均能有效去除水体中SeO2-3,去除效率(除pH值7.8以外)均达到90%以上;(2)硫铁矿与SeO2-3发生反应后,其主要组成元素的XPS特征峰结合能有所减小,表明硫铁矿表面发生了一定化学变化;(3)酸碱环境下硫铁矿去除SeO2-3的机理不完全相同,酸性环境下,硫铁矿对SeO2-3的去除是单纯的氧化还原过程,即硫铁矿中被酸活化的S2-2将SeO2-3还原为单质Se(0),并且酸性越强,SeO2-3去除效果越好;碱性环境下,SeO2-3的去除过程中氧化还原与络合反应并存,硫铁矿表面有络合态Fe(OH)SeO3和单质Se(0)两种存在形态,且碱性越强,络合态Fe(OH)SeO3含量越高。以上研究结果为硫铁矿去除固定水体和土壤中以SeO2-3为代表的可变价金属阴离子提供重要理论依据和应用基础。 相似文献