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Employing radical bridges between anisotropic metal ions has been a viable route to achieve high-performance single-molecule magnets (SMMs). While the bridges have been mainly considered for their ability to promote exchange interactions, the crystal-field effect arising from them has not been taken into account explicitly. This lack of consideration may distort the understanding and limit the development of the entire family. To shed light on this aspect, herein we report a theoretical investigation of a series of N -radical-bridged diterbium complexes. It is found that while promoting strong exchange coupling between the terbium ions, the N -radical induces a crystal field that interferes destructively with that of the outer ligands, and thus reduces the overall SMM behavior. Based on the theoretical results, we conclude that the SMM behavior in this series could be further maximized if the crystal field of the outer ligands is designed to be collinear with that of the radical bridge. This conclusion can be generalized to all exchange-coupled SMMs.  相似文献   
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In this article, we construct and analyze a residual-based a posteriori error estimator for a quadratic finite volume method (FVM) for solving nonlinear elliptic partial differential equations with homogeneous Dirichlet boundary conditions. We shall prove that the a posteriori error estimator yields the global upper and local lower bounds for the norm error of the FVM. So that the a posteriori error estimator is equivalent to the true error in a certain sense. Numerical experiments are performed to illustrate the theoretical results.  相似文献   
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The present work reports new experimental and numerical results of the combustion properties of hydrogen based mixtures diluted by nitrogen and steam. Spherical expanding flames have been studied in a spherical bomb over a large domain of equivalence ratios, initial temperatures and dilutions at an initial pressure of 100 kPa (Tini = 296, 363, 413 K; N2/O2 = 3.76, 5.67, 9; %Steam = 0, 20, 30). From these experiments, the laminar flame speed SL0, the Markstein length L’, the activation energy Ea and the Zel'dovich β number have been determined. These parameters were also simulated using COSILAB® in order to verify the validity of the Mével et al. [1] detailed kinetic mechanism. Other parameters as the laminar flame thickness δ and the effective Lewis number Leeff were also simulated. These new results aim at providing an extended database that will be very useful in the hydrogen combustion hazard assessment for nuclear reactor power plant new design.  相似文献   
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The problem of the minimax testing of the Poisson process intensity \({\mathbf{s}}\) is considered. For a given intensity \({\mathbf{p}}\) and a set \(\mathcal{Q}\), the minimax testing of the simple hypothesis \(H_{0}: {\mathbf{s}} = {\mathbf{p}}\) against the composite alternative \(H_{1}: {\mathbf{s}} = {\mathbf{q}},\,{\mathbf{q}} \in \mathcal{Q}\) is investigated. The case, when the 1-st kind error probability \(\alpha \) is fixed and we are interested in the minimal possible 2-nd kind error probability \(\beta ({\mathbf{p}},\mathcal{Q})\), is considered. What is the maximal set \(\mathcal{Q}\), which can be replaced by an intensity \({\mathbf{q}} \in \mathcal{Q}\) without any loss of testing performance? In the asymptotic case (\(T\rightarrow \infty \)) that maximal set \(\mathcal{Q}\) is described.

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