首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   98257篇
  免费   5569篇
  国内免费   4656篇
化学   56051篇
晶体学   1309篇
力学   5534篇
综合类   328篇
数学   11861篇
物理学   33399篇
  2022年   1337篇
  2021年   1946篇
  2020年   2306篇
  2019年   2498篇
  2018年   2857篇
  2017年   2803篇
  2016年   3479篇
  2015年   2364篇
  2014年   3454篇
  2013年   4891篇
  2012年   5048篇
  2011年   5394篇
  2010年   4271篇
  2009年   4281篇
  2008年   4470篇
  2007年   4191篇
  2006年   3821篇
  2005年   3391篇
  2004年   3043篇
  2003年   2713篇
  2002年   2827篇
  2001年   2552篇
  2000年   1989篇
  1999年   1605篇
  1998年   1537篇
  1997年   1332篇
  1996年   1293篇
  1995年   1078篇
  1994年   1156篇
  1993年   1095篇
  1992年   1062篇
  1991年   1125篇
  1990年   1118篇
  1989年   1039篇
  1988年   917篇
  1987年   914篇
  1986年   882篇
  1985年   921篇
  1984年   915篇
  1983年   822篇
  1982年   800篇
  1979年   797篇
  1978年   809篇
  1977年   805篇
  1976年   917篇
  1975年   811篇
  1974年   839篇
  1973年   843篇
  1972年   751篇
  1971年   739篇
排序方式: 共有10000条查询结果,搜索用时 375 毫秒
1.
Bo  Luo  Gao  Wei  Yu  Yuguo  Chen  Xiaojun 《Nonlinear dynamics》2022,110(1):281-311
Nonlinear Dynamics - The perovskite solar cell (PSC) is one of the most promising photovoltaic candidates along with the highly increasing demand for green electricity. One of the main concerns...  相似文献   
2.
Lin  Yu  Wu  Yeyu  Tan  Xuecai  Wu  Jiawen  Huang  Kejing  Mi  Yan  Ou  Panpan  Wei  Fucun 《Journal of Solid State Electrochemistry》2022,26(4):959-971
Journal of Solid State Electrochemistry - An ultrasensitive “signal-off–on” electrochemiluminescence (ECL) biosensor is constructed based on f1-TiO2/g-C3N4/PDA for thrombin...  相似文献   
3.
Russian Journal of General Chemistry - Aminophosphabetaines, i.e., isobutyl {[alkyl(dimethyl)ammonio]methyl}phosphonates with higher alkyl substituents at the nitrogen atom, were obtained by a...  相似文献   
4.
Amlexanox, an anti-inflammatory and anti-allergic agent, has been widely used clinically for the treatment of canker sores, asthma, and allergic rhinitis. Recently, amlexanox has received considerable attention in curing nonalcoholic fatty liver diseases and hepatitis virus infection. Herein, we first established a sensitive high-performance liquid chromatography-tandem mass spectrum (LC–MS/MS) method for the determination of amlexanox in rat plasma. Propranolol was used as the internal standard (IS). Using a simple protein precipitation method, the amlexanox and IS were separated with Capcell Pak C18 column (2.0 × 50 mm, 5 μm) and eluted with water and acetonitrile each containing 0.1% formic acid using gradient elution condition at a flow rate of 0.4 mL·min−1. Amlexanox and IS were detected by a triple quadrupole mass in multiple reactive monitoring (MRM) under the transitions of m/z 299.2 → 281.2 and m/z 259.9 → 116.1 with positive electrospray ionization, respectively. The calibration curves of amlexanox were established with the range of 50 to 2000 ng·mL−1 (r2 > 0.99). The validation method consisted of selectivity, accuracy, precision, carryover effect, matrix effect, recovery, dilution effect, and stability. The fully validated method was successfully applied to the pharmacokinetic study of amlexanox in Wistar rats.  相似文献   
5.
Refractory wounds have always been an important issue to healthcare systems, whose healing process is always delayed by multiple factors, including bacterial infections, chronic inflammation, and excessive exudates, etc. Employing multifunctional wound dressings is recognized as an effective strategy to deal with refractory wounds, which has yielded promising outcomes in recent years. Among these advanced wound dressings, fibrous dressings have gained growing attention due to their unique merits. Such wound dressings have demonstrated great potential in delivering theranostic agents, such as antibacterial agents, anti-inflammatory drugs, growth factors, and diagnostic probes, etc., for the purposes of accelerating wound healing. This paper reviews the development of multifunctional fibrous dressings and their applications in treating refractory wounds. The construction approaches of novel fibrous dressing with capabilities of antibacterial, anti-inflammation, exudate management and diagnosis were also introduced. Furthermore, the existing problems and challenges are also discussed briefly.  相似文献   
6.
At present, the reactivity of cyclic alkanes is estimated by comparison with acyclic hydrocarbons. Due to the difference in the structure of cycloalkanes and acycloalkanes, the thermodynamic data obtained by analogy are not applicable. In this study, a molecular beam sampling vacuum ultraviolet photoionization time-of-flight mass spectrometer (MB-VUV-PI-TOFMS) was applied to study the low-temperature oxidation of cyclopentane (CPT) at a total pressure range from 1–3 atm and low-temperature range between 500 and 800 K. Low-temperature reaction products including cyclic olefins, cyclic ethers, and highly oxygenated intermediates (e. g., ketohydroperoxide KHP, keto-dihydroperoxide KDHP, olefinic hydroperoxides OHP and ketone structure products) were observed. Further investigation of the oxidation of CPT – electronic structure calculations – were carried out at the UCCSD(T)-F12a/aug-cc-pVDZ//B3LYP/6-31+ G(d,p) level to explore the reactivity of O2 molecules adding sequentially to cyclopentyl radicals. Experimental and theoretical observations showed that the dominant product channel in the reaction of CPT radicals with O2 is HO2 elimination yielding cyclopentene. The pathways of second and third O2 addition – the dissociation of hydroperoxide – were further confirmed. The results of this study will develop the low-temperature oxidation mechanism of CPT, which can be used for future research on accurately simulating the combustion process of CPT.  相似文献   
7.
8.
Russian Journal of Applied Chemistry - A method for the disposal of hydrolysis lignin waste based on its modification with ZnCl2 and FeCl3 and subsequent carbonization at 800°C was proposed....  相似文献   
9.
Russian Journal of General Chemistry - The review article traces the main trends of the synthetic approach to the solution of the problem of overcoming the resistance of pathogenic bacterial...  相似文献   
10.
Knyazev  Yu. V.  Kazak  N. V.  Gavrichkov  V. A.  Polukeev  S. I.  Ovchinnikov  S. G. 《JETP Letters》2022,116(8):567-573
JETP Letters - Changes in the magnetic properties of FeBO3 single crystals in the course of spin crossover occurring with increasing pressure up to 63 GPa are studied both experimentally and...  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号