全文获取类型
收费全文 | 570篇 |
免费 | 9篇 |
国内免费 | 13篇 |
专业分类
化学 | 347篇 |
晶体学 | 2篇 |
力学 | 9篇 |
数学 | 144篇 |
物理学 | 90篇 |
出版年
2022年 | 10篇 |
2020年 | 5篇 |
2019年 | 5篇 |
2017年 | 5篇 |
2016年 | 3篇 |
2015年 | 9篇 |
2014年 | 6篇 |
2013年 | 15篇 |
2012年 | 20篇 |
2011年 | 34篇 |
2010年 | 13篇 |
2009年 | 12篇 |
2008年 | 23篇 |
2007年 | 23篇 |
2006年 | 33篇 |
2005年 | 25篇 |
2004年 | 27篇 |
2003年 | 24篇 |
2002年 | 18篇 |
2001年 | 16篇 |
2000年 | 17篇 |
1999年 | 6篇 |
1998年 | 7篇 |
1997年 | 12篇 |
1996年 | 17篇 |
1995年 | 17篇 |
1994年 | 8篇 |
1993年 | 13篇 |
1992年 | 10篇 |
1991年 | 10篇 |
1990年 | 7篇 |
1989年 | 4篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1986年 | 5篇 |
1985年 | 4篇 |
1983年 | 8篇 |
1982年 | 7篇 |
1981年 | 17篇 |
1980年 | 3篇 |
1979年 | 5篇 |
1978年 | 9篇 |
1977年 | 4篇 |
1976年 | 6篇 |
1975年 | 3篇 |
1974年 | 6篇 |
1972年 | 3篇 |
1969年 | 3篇 |
1968年 | 4篇 |
1903年 | 5篇 |
排序方式: 共有592条查询结果,搜索用时 15 毫秒
1.
2.
Bjorn Fritzell 《Journal of voice》1992,6(2)
Inverse filtering is a noninvasive method of producing a glottogram thought to reflect the vibratory motions of the vocal fold. The flow glottogram provides information related to the type of phonation, the sound pressure level, the regularity of vocal fold vibrations, and to the presence or absence of vocal fold closure. Limited data, speech samples, filter tuning, and lack of unanimity on waveform display and interpretation have contributed to slow application of the techniques to the clinical population. The author argues the technique has utility in both diagnosis and treatment 相似文献
3.
Analysis of Static Simulated Annealing Algorithms 总被引:1,自引:0,他引:1
Generalized hill climbing (GHC) algorithms provide a framework for modeling local search algorithms to address intractable discrete optimization problems. This paper introduces a measure for determining the expected number of iterations to visit a predetermined objective function level, given that an inferior objective function level has been reached in a finite number of iterations. A variation of simulated annealing (SA), termed static simulated annealing (S2A), is analyzed using this measure. S2A uses a fixed cooling schedule during the algorithm execution. Though S2A is probably nonconvergent, its finite-time performance can be assessed using the finite-time performance measure defined in this paper. 相似文献
4.
S. Coffa D. C. Jacobson J. M. Poate F. Priolo 《Applied Physics A: Materials Science & Processing》1992,54(6):481-484
We have investigated ion-beam-enhanced diffusion of Au in undoped and B doped amorphous Si. The diffusion coefficients depend linearly on ion flux and exibit an Arrhenius-like temperature dependence with an activation energy of 0.37 eV in the temperature range 200–350° C. Moreover the diffusivity is enhanced by a factor of 5 by B-doping at a concentration of 1×1020 atoms/cm3. A similar enhancement is observed in thermal diffusion of Au which has an activation energy of 1.5 eV. On the basis of these results a model for the ion-beam-enhanced diffusion of Au is proposed where the high density of defects present in amorphous Si act as traps for the fast moving interstitial Au atoms. The effectiveness of this trapping process can be changed by the high concentration of mobile defects generated by the beam and also by a change in the charge state of the traps induced by the presence of B. 相似文献
5.
Guantao Chen Ronald J. Gould Michael S. Jacobson Richard H. Schelp 《Journal of Graph Theory》1994,18(7):663-672
For several years, the study of neighborhood unions of graphs has given rise to important structural consequences of graphs. In particular, neighborhood conditions that give rise to hamiltonian cycles have been considered in depth. In this paper we generalize these approaches to give a bound on the smallest number of cycles in G containing all the vertices of G. We show that if for all x, y ? V(G), |N(x) ∩ N(y)| ≧ 2n/5 + 1, then V(G) is coverable by at most two cycles. Several related results and extensions to t cycles are also given. 相似文献
6.
7.
Three new Ni(BDC)/2,2'-bipy compounds, Ni2(BDC)(HBDC)2(2,2'-bipy)2 (2), Ni3(BDC)3(2,2'-bipy)2 (3), and Ni(BDC)(2,2-bipy)2.2H2O (5), in addition to the previously reported Ni(BDC)(2,2'-bipy).0.75H2BDC (1) and Ni(BDC)(2,2'-bipy)(H2O) (4) [BDC = 1,4-benzenedicarboxylate; 2,2'-bipy = 2,2'-bipyridine], have been synthesized by hydrothermal reactions. A systematic investigation of the effect of the reaction temperature and pH resulted in a series of compounds with different compositions and dimensionality. The diverse product slate illustrates the marked sensitivity of the structural chemistry of polycarboxylate aromatic ligands to synthesis conditions. Compound 1, which has a channel structure containing guest H2BDC molecules, is formed at the lowest pH. The guest H2BDC molecules are connected by hydrogen bonds and form extended chains. At a slightly higher pH, a dimeric molecular compound 2 is formed with a lower number of protonated carboxylate groups per nickel atom and per BDC ligand. Reactions at higher temperature and the same pH lead to the transformation of 1 and 2 into the two-dimensional, layered trinuclear compound 3. As the pH is increased, a one-dimensional polymer 4 is formed with a water molecule coordinated to Ni2+. Bis-monodentate and bischelating BDC ligands alternate along the chain to give a crankshaft rather than a regular zigzag arrangement. A further increase of the pH leads to the one-dimensional chain compound 5, which has two chelating 2,2'-bipy ligands. Crystal data: 2, triclinic, space group P, a = 7.4896(9) angstroms, b = 9.912(1) angstroms, c = 13.508(2) angstroms, alpha = 86.390(2) degrees , beta = 75.825(2) degrees, gamma = 79.612(2) degrees, Z = 2; 3, orthorhombic, space group Pbca, a = 9.626(2) angstroms, b = 17.980(3) angstroms, c = 25.131(5) angstroms, Z = 4; 5, orthorhombic, space group Pbcn, a = 14.266(2) angstroms, b = 10.692(2) angstroms, c = 17.171(2) angstroms, Z = 8. 相似文献
8.
Mosley DW Sellmyer MA Daida EJ Jacobson JM 《Journal of the American Chemical Society》2003,125(35):10532-10533
Adlayers were formed on self-assembled monolayers (SAMs) formed by alkanethiols on gold. Base SAMs exposing amide functional groups at the SAM surface were formed with 12-mercaptododecanamide. Adlayers of diacetylene-containing monomers were then formed via amide hydrogen bonding in decalin and decalin/toluene mixtures. Grazing angle FTIR, contact angle measurements, and ellipsometry suggest that these adlayer films exhibit ordering and packing similar to that of SAMs on gold. Resonance Raman spectroscopy showed that these diacetylene adlayers could be readily polymerized by exposure to UV light. 相似文献
9.
The CD spectra of L-2-methylpyrrolidine, L-prolinol, and their N-methylated derivatives have been determined. As in the 2-substituted piperidines, N-methylation results in an inversion of the sign of the Cotton effects (CE). However, the sign of the long-wavelength CE does not follow the simple helicity rule found for 2-substituted piperidines, since the pyrrolidine ring is itself chiral and makes its own contributions to the observed CE's. The rotational contribution due to pyrrolidine ring chirality appears to be opposite in sign to and larger in magnitude than that due to the 2-substituent in both the secondary and the tertiary amines. 相似文献
10.
E. G. Coffman Jr. Bjorn Poonen Peter Winkler 《Probability Theory and Related Fields》1995,102(1):105-121
Summary Letn random intervalsI
1, ...,I
n be chosen by selecting endpoints independently from the uniform distribution on [0.1]. Apacking is a pairwise disjoint subset of the intervals; itswasted space is the Lebesgue measure of the points of [0,1] not covered by the packing. In any set of intervals the packing with least wasted space is computationally easy to find; but its expected wasted space in the random case is not obvious. We show that with high probability for largen, this best packing has wasted space
. It turns out that if the endpoints 0 and 1 are identified, so that the problem is now one of packing random arcs in a unit-circumference circle, then optimal wasted space is reduced toO(1/n). Interestingly, there is a striking difference between thesizes of the best packings: about logn intervals in the unit interval case, but usually only one or two arcs in the circle case. 相似文献