全文获取类型
收费全文 | 7403篇 |
免费 | 1384篇 |
国内免费 | 1280篇 |
专业分类
化学 | 5681篇 |
晶体学 | 150篇 |
力学 | 484篇 |
综合类 | 94篇 |
数学 | 788篇 |
物理学 | 2870篇 |
出版年
2024年 | 18篇 |
2023年 | 114篇 |
2022年 | 258篇 |
2021年 | 263篇 |
2020年 | 327篇 |
2019年 | 342篇 |
2018年 | 290篇 |
2017年 | 260篇 |
2016年 | 375篇 |
2015年 | 376篇 |
2014年 | 455篇 |
2013年 | 554篇 |
2012年 | 688篇 |
2011年 | 722篇 |
2010年 | 518篇 |
2009年 | 485篇 |
2008年 | 510篇 |
2007年 | 509篇 |
2006年 | 452篇 |
2005年 | 378篇 |
2004年 | 323篇 |
2003年 | 245篇 |
2002年 | 253篇 |
2001年 | 211篇 |
2000年 | 154篇 |
1999年 | 178篇 |
1998年 | 133篇 |
1997年 | 127篇 |
1996年 | 107篇 |
1995年 | 74篇 |
1994年 | 71篇 |
1993年 | 64篇 |
1992年 | 50篇 |
1991年 | 36篇 |
1990年 | 36篇 |
1989年 | 17篇 |
1988年 | 18篇 |
1987年 | 12篇 |
1986年 | 19篇 |
1985年 | 4篇 |
1984年 | 8篇 |
1983年 | 11篇 |
1982年 | 6篇 |
1981年 | 4篇 |
1980年 | 2篇 |
1973年 | 1篇 |
1970年 | 2篇 |
1959年 | 1篇 |
1957年 | 2篇 |
1909年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Zhang Bing Yang Jie-qin Liu Ying Hu Bin Yang Yang Zhao Li Lu Qiang 《Cellulose (London, England)》2022,29(12):6565-6578
Cellulose - Heating is essential in various biomass pre-treatments and thermal conversion processes. It is of practical significance to study the characteristics of cellulose-lignin and... 相似文献
2.
Dan Chen Kaixin Du Xiaochen Niu Hongwei Zhang Xue Zhang Yu Tang Jianchun Zhao 《Biomedical chromatography : BMC》2022,36(3):e5288
Amlexanox, an anti-inflammatory and anti-allergic agent, has been widely used clinically for the treatment of canker sores, asthma, and allergic rhinitis. Recently, amlexanox has received considerable attention in curing nonalcoholic fatty liver diseases and hepatitis virus infection. Herein, we first established a sensitive high-performance liquid chromatography-tandem mass spectrum (LC–MS/MS) method for the determination of amlexanox in rat plasma. Propranolol was used as the internal standard (IS). Using a simple protein precipitation method, the amlexanox and IS were separated with Capcell Pak C18 column (2.0 × 50 mm, 5 μm) and eluted with water and acetonitrile each containing 0.1% formic acid using gradient elution condition at a flow rate of 0.4 mL·min−1. Amlexanox and IS were detected by a triple quadrupole mass in multiple reactive monitoring (MRM) under the transitions of m/z 299.2 → 281.2 and m/z 259.9 → 116.1 with positive electrospray ionization, respectively. The calibration curves of amlexanox were established with the range of 50 to 2000 ng·mL−1 (r2 > 0.99). The validation method consisted of selectivity, accuracy, precision, carryover effect, matrix effect, recovery, dilution effect, and stability. The fully validated method was successfully applied to the pharmacokinetic study of amlexanox in Wistar rats. 相似文献
3.
Cavitation erosion is caused in solids exposed to strong pressure waves developing in an adjacent fluid field. The knowledge of the transient distribution of stresses in the solid is important to understand the cause of damaging by comparisons with breaking points of the material. The modeling of this problem requires the coupling of the models for the fluid and the solid. For this purpose, we use a strategy based on the solution of coupled Riemann problems that has been originally developed for the coupling of 2 fluids. This concept is exemplified for the coupling of a linear elastic structure with an ideal gas. The coupling procedure relies on the solution of a nonlinear equation. Existence and uniqueness of the solution is proven. The coupling conditions are validated by means of quasi‐1D problems for which an explicit solution can be determined. For a more realistic scenario, a 2D application is considered where in a compressible single fluid, a hot gas bubble at low pressure collapses in a cold gas at high pressure near an adjacent structure. 相似文献
4.
We investigate terahertz radiation(T-rays) from a pentacene organic diode at room temperature. The quantum chemistry calculation for frequency-related Huang–Rhys factor of pentacene is also carried out. The results demonstrate that the T-rays can come from a bending vibration of pentacene skeleton after the energy of pentacene exciton transferring to the vibrational excited state via electron–phonon coupling. Frequency and natural bond orbital analytics of pentacene and its derivatives are performed in order to explain the result and develop new materials to get higher emission. This work provides a new way to produce T-rays with a simple device at room temperature. 相似文献
5.
We report a spatially modulated polarimetry scheme by using a zero-order vortex half-wave retarder(ZVHR)and a spatial Fourier analysis method.A ZVHR is employed to analyze the input polarized light and convert it into a vectorial optical field,and an analyzer is set after the ZVHR to form an hourglass intensity pattern due to the spatial polarization modulation.Then,the input light’s Stokes parameters can be calculated by spatial Fourier analysis of the hourglass pattern with a single shot.The working principle of the polarimeter has been analyzed by the Stokes-Mueller formalism,and some quantitative measuring experiments of different polarization states have been demonstrated.The experimental results indicate that the proposed polarimeter is accurate,robust,and simple to use. 相似文献
6.
Chen Fenge Li Bing Peng Xingchun 《Methodology and Computing in Applied Probability》2022,24(2):635-659
Methodology and Computing in Applied Probability - This paper is devoted to the study of an optimal investment and risk control problem for an insurer. The risky asset process and the insurance... 相似文献
7.
Nonlinear Dynamics - This paper seeks to address the problem of finite-time stabilization for a class of uncertain Hamiltonian systems via sliding mode control approach. A novel sliding function in... 相似文献
8.
9.
Studies on metabolism of total glucosides of paeony from Paeoniae Radix Alba in rats by UPLC‐Q‐TOF‐MS/MS 下载免费PDF全文
Wenli Cao Xinguo Wang Haojie Li Xuliang Shi Wencheng Fan Shaohua Zhao Minyan Liu Liying Niu 《Biomedical chromatography : BMC》2015,29(11):1769-1779
Total glucosides of paeony are the active constituents of Paeoniae Radix Alba. In this study, a novel strategy was proposed to find more metabolites and the differences between paeoniflorin, albiflorin and total glucosides of paeony (TGP). This strategy was characterized as follows: firstly, the animals were divided into three groups (paeoniflorin, albiflorin and TGP) to identify the source of TGP metabolites from paeoniflorin or albiflorin; secondly, a generic information‐dependent acquisition scan for the low‐level metabolites was triggered by the multiple mass defect filter and dynamic background subtraction; thirdly, the metabolites were identified with a combination of data‐processing methods including mass defect filtering, neutral loss filtering and product ion filtering; finally, a comparative study was used in the metabolism of paeoniflorin, albiflorin and TGP. Based on the strategy, 18 metabolites of TGP, 10 metabolites of paeoniflorin and 13 metabolites of albiflorin were identified respectively. The results indicated that the hydrolysis, conjugation reaction and oxidization were the major metabolic pathways, and the metabolic sites were the glycosidic linkage, the ester bond and the benzene ring. This study is first to explore the metabolism of TGP, and these findings enhance our understanding of the metabolism and the interactions of paeoniflrin and albiflorin in TGP. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
10.
Nonlinear Dynamics - Nonlinear vibration isolation provides with an effective way for vibration reduction with broad band and high efficiency. This investigation focuses on the dynamic effects of a... 相似文献