首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   21906篇
  免费   2682篇
  国内免费   2876篇
化学   11170篇
晶体学   174篇
力学   1748篇
综合类   337篇
数学   5368篇
物理学   8667篇
  2024年   42篇
  2023年   556篇
  2022年   802篇
  2021年   788篇
  2020年   914篇
  2019年   612篇
  2018年   724篇
  2017年   857篇
  2016年   842篇
  2015年   940篇
  2014年   1305篇
  2013年   1508篇
  2012年   1697篇
  2011年   1704篇
  2010年   1412篇
  2009年   1382篇
  2008年   1223篇
  2007年   1521篇
  2006年   1381篇
  2005年   854篇
  2004年   637篇
  2003年   533篇
  2002年   492篇
  2001年   495篇
  2000年   404篇
  1999年   443篇
  1998年   353篇
  1997年   278篇
  1996年   205篇
  1995年   204篇
  1994年   145篇
  1993年   173篇
  1992年   181篇
  1991年   155篇
  1990年   147篇
  1989年   143篇
  1988年   326篇
  1987年   428篇
  1986年   400篇
  1985年   114篇
  1984年   47篇
  1983年   43篇
  1982年   18篇
  1981年   13篇
  1980年   5篇
  1979年   5篇
  1978年   2篇
  1958年   2篇
  1957年   3篇
  1936年   2篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
This paper is concerned with the Cauchy problem on the Boltzmann equation without angular cutoff assumption for hard potential in the whole space. When the initial data is a small perturbation of a global Maxwellian, the global existence of solution to this problem is proved in unweighted Sobolev spaces HN(Rx,v6) with N2. But if we want to obtain the optimal temporal decay estimates, we need to add the velocity weight function, in this case the global existence and the optimal temporal decay estimate of the Boltzmann equation are all established. Meanwhile, we further gain a more accurate energy estimate, which can guarantee the validity of the assumption in Chen et al. (0000).  相似文献   
2.
3.
4.
《中国物理 B》2021,30(7):74204-074204
We investigate the influence of the birefringence on the high-order harmonics in an a-cut Zn O crystal with midinfrared laser pulses. The high harmonics exhibit strong dependence on the alignment of the crystal with respect to the laser polarization. We introduce the Jones calculus to counteract the birefringent effect and obtain the harmonics with polarization corrections in Zn O. We show that the birefringent effect plays an important role in the orientation dependence of HHG.  相似文献   
5.
本文在不确定理论的框架下,研究一类带背景状态变量的最优控制模型.在乐观值准则下,利用不确定动态规划的方法,证明了不确定最优性原则,得到最优性方程.作为应用,求解一个固定缴费(DC)型养老金的最优投资策略问题,在乐观值准则下,以工资变量为背景状态变量,建立养老金模型.通过求解不确定最优性方程得到最优投资策略和最优支付率.  相似文献   
6.
7.
We consider the irreducibility of polynomial Ln(α)(x) where α is a negative integer. We observe that the constant term of Ln(α)(x) vanishes if and only if n|α|=?α. Therefore we assume that α=?n?s?1 where s is a non-negative integer. Let g(x)=(?1)nLn(?n?s?1)(x)=j=0najxjj! and more general polynomial, let G(x)=j=0najbjxjj! where bj with 0jn are integers such that |b0|=|bn|=1. Schur was the first to prove the irreducibility of g(x) for s=0. It has been proved that g(x) is irreducible for 0s60. In this paper, by a different method, we prove: Apart from finitely many explicitly given possibilities, either G(x) is irreducible or G(x) is linear factor times irreducible polynomial. This is a consequence of the estimate s>1.9k whenever G(x) has a factor of degree k2 and (n,k,s)(10,5,4). This sharpens earlier estimates of Shorey and Tijdeman and Nair and Shorey.  相似文献   
8.
Given their superior penetration depths, photosensitizers with longer absorption wavelengths present broader application prospects in photodynamic therapy (PDT). Herein, Ag2S quantum dots were discovered, for the first time, to be capable of killing tumor cells through the photodynamic route by near-infrared light irradiation, which means relatively less excitation of the probe compared with traditional photosensitizers absorbing short wavelengths. On modification with polydopamine (PDA), PDA-Ag2S was obtained, which showed outstanding capacity for inducing reactive oxygen species (increased by 1.69 times). With the addition of PDA, Ag2S had more opportunities to react with surrounding O2, which was demonstrated by typical triplet electron spin resonance (ESR) analysis. Furthermore, the PDT effects of Ag2S and PDA-Ag2S achieved at longer wavelengths were almost identical to the effects produced at 660 nm, which was proved by studies in vitro. PDA-Ag2S showed distinctly better therapeutic effects than Ag2S in experiments in vivo, which further validated the enhanced regulatory effect of PDA. Altogether, a new photosensitizer with longer absorption wavelength was developed by using the hitherto-unexplored photodynamic function of Ag2S quantum dots, which extended and enhanced the regulatory effect originating from PDA.  相似文献   
9.
The accumulation of material degradation under contact with aggressive aqueous environments could lead to reduced structural reliability. In terms of hydrated cementitious materials, such interactions often result in the chemo-physical-mechanical (CPM) degradation, which represents a multiphysics process of high non-linearity and complexity. By further considering the inevitable uncertainties associated with both the materials and the serving conditions, solving such a process requires novel probabilistic approaches. This paper presents a stochastic chemo-physical-mechanical (SCPM) degradation analysis on the hydrated cement under acidic environment. The SCPM analysis consists of modelling the stochastic chemophysical degradation by finite element method, and assessing the mechanical deterioration through analytical micromechanics. The proposed modelling framework couples the conventional Monte Carlo Simulation with a novel support vector regression algorithm. The present method is able to not only address the detailed degradation mechanisms, but also ensure low computational costs for an accurate SCPM degradation assessment.  相似文献   
10.
Embedding endohdedral metallofullerenes (EMFs) into electron donor–acceptor systems is still a challenging task owing to their limited quantities and their still largely unexplored chemical properties. In this study, we have performed a 1,3‐dipolar cycloaddition reaction of a corrole‐based precursor with Sc3N@C80 to regioselectively form a [5,6]‐adduct ( 1 ). The successful attachment of the corrole moiety was confirmed by mass spectrometry. In the electronic ground state, absorption spectra suggest sizeable electronic communications between the electron acceptor and the electron donor. Moreover, the addition pattern occurring at a [5,6]‐bond junction is firmly proven by NMR spectroscopy and electrochemical investigations performed with 1 . In the electronically excited state, which is probed in photophysical assays with 1 , a fast electron‐transfer yields the radical ion pair state consisting of the one‐electron‐reduced Sc3N@C80 and of the one‐electron‐oxidized corrole upon its exclusive photoexcitation. As such, our results shed new light on the practical work utilizing EMFs as building blocks in photovoltaics.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号