全文获取类型
收费全文 | 24048篇 |
免费 | 1651篇 |
国内免费 | 1185篇 |
专业分类
化学 | 3519篇 |
晶体学 | 37篇 |
力学 | 2077篇 |
综合类 | 223篇 |
数学 | 17665篇 |
物理学 | 3363篇 |
出版年
2024年 | 51篇 |
2023年 | 302篇 |
2022年 | 468篇 |
2021年 | 516篇 |
2020年 | 704篇 |
2019年 | 653篇 |
2018年 | 703篇 |
2017年 | 754篇 |
2016年 | 696篇 |
2015年 | 568篇 |
2014年 | 1133篇 |
2013年 | 2307篇 |
2012年 | 1183篇 |
2011年 | 1316篇 |
2010年 | 1105篇 |
2009年 | 1597篇 |
2008年 | 1650篇 |
2007年 | 1528篇 |
2006年 | 1315篇 |
2005年 | 1098篇 |
2004年 | 905篇 |
2003年 | 871篇 |
2002年 | 747篇 |
2001年 | 543篇 |
2000年 | 582篇 |
1999年 | 541篇 |
1998年 | 477篇 |
1997年 | 439篇 |
1996年 | 361篇 |
1995年 | 274篇 |
1994年 | 202篇 |
1993年 | 171篇 |
1992年 | 164篇 |
1991年 | 129篇 |
1990年 | 95篇 |
1989年 | 61篇 |
1988年 | 57篇 |
1987年 | 56篇 |
1986年 | 57篇 |
1985年 | 96篇 |
1984年 | 99篇 |
1983年 | 47篇 |
1982年 | 51篇 |
1981年 | 51篇 |
1980年 | 34篇 |
1979年 | 37篇 |
1978年 | 26篇 |
1977年 | 22篇 |
1976年 | 15篇 |
1974年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
11.
Cavitation erosion is caused in solids exposed to strong pressure waves developing in an adjacent fluid field. The knowledge of the transient distribution of stresses in the solid is important to understand the cause of damaging by comparisons with breaking points of the material. The modeling of this problem requires the coupling of the models for the fluid and the solid. For this purpose, we use a strategy based on the solution of coupled Riemann problems that has been originally developed for the coupling of 2 fluids. This concept is exemplified for the coupling of a linear elastic structure with an ideal gas. The coupling procedure relies on the solution of a nonlinear equation. Existence and uniqueness of the solution is proven. The coupling conditions are validated by means of quasi‐1D problems for which an explicit solution can be determined. For a more realistic scenario, a 2D application is considered where in a compressible single fluid, a hot gas bubble at low pressure collapses in a cold gas at high pressure near an adjacent structure. 相似文献
12.
13.
The satisfiability (SAT) problem is a core problem in computer science. Existing studies have shown that most industrial SAT instances can be effectively solved by modern SAT solvers while random SAT instances cannot. It is believed that the structural characteristics of different SAT formula classes are the reasons behind this difference. In this paper, we study the structural properties of propositional formulas in conjunctive normal form (CNF) by the principle of structural entropy of formulas. First, we used structural entropy to measure the complex structure of a formula and found that the difficulty solving the formula is related to the structural entropy of the formula. The smaller the compressing information of a formula, the more difficult it is to solve the formula. Secondly, we proposed a -approximation strategy to approximate the structural entropy of large formulas. The experimental results showed that the proposed strategy can effectively approximate the structural entropy of the original formula and that the approximation ratio is more than 92%. Finally, we analyzed the structural properties of a formula in the solution process and found that a local search solver tends to select variables in different communities to perform the next round of searches during a search and that the structural entropy of a variable affects the probability of the variable being flipped. By using these conclusions, we also proposed an initial candidate solution generation strategy for a local search for SAT, and the experimental results showed that this strategy effectively improves the performance of the solvers CCAsat and Sparrow2011 when incorporated into these two solvers. 相似文献
14.
15.
16.
An oriented tetrahedron defined on four vertices is a set of four cyclic triples with the property that any ordered pair of vertices is contained in exactly one of the cyclic triples. A tetrahedral quadruple system of order with index , denoted by , is a pair , where is an ‐set and is a set of oriented tetrahedra (blocks) such that every cyclic triple on is contained in exactly members of . A is pure if there do not exist two blocks with the same vertex set. When , the spectrum of a pure TQS has been completely determined by Ji. In this paper, we show that there exists a pure if and only if and . A corollary is that a simple also exists if and only if and . 相似文献
17.
Synthesis of diisocyanides with phenolic groups and their polymerization to helically chiral poly(quinoxaline‐2,3‐diyl)s
下载免费PDF全文
![点击此处可从《Journal of polymer science. Part A, Polymer chemistry》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Johannes Scholz Michael Reggelin 《Journal of polymer science. Part A, Polymer chemistry》2015,53(11):1320-1329
The development of synthetic routes which lead to five new diisocyanide monomers with one or two phenolic groups is described. Their polymerization behavior is studied with Pd‐ and Ni‐based initiators, as well as under microwave irradiation. The polymerizability is mainly dominated by steric effects as is concluded from experiments using different protecting groups. Chiroptical properties of these new polymers are studied by CD‐spectroscopy. After deprotection, helically chiral poly(quinoxalin‐2,3‐diyl)s are obtained which display a Brønsted function attached to a stereolabile biaryl axis whose configuration should be influenced by the chiral polymer backbone. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1320–1329 相似文献
18.
In this paper, we propose a sufficient and necessary condition for the boundedness of all the solutions for the equation with the critical situation that on g and p, where , is periodic and is bounded. 相似文献
19.
In this paper, the deformation of the Heisenberg algebra, consistent with both the generalized uncertainty principle and doubly special relativity, has been analyzed. It has been observed that, though this algebra can give rise to fractional derivative terms in the corresponding quantum mechanical Hamiltonian, a formal meaning can be given to them by using the theory of harmonic extensions of function. Depending on this argument, the expression of the propagator of the path integral corresponding to the deformed Heisenberg algebra, has been obtained. In particular, the consistent expression of the one dimensional free particle propagator has been evaluated explicitly. With this propagator in hand, it has been shown that, even in free particle case, normal generalized uncertainty principle and doubly special relativity show very much different result. 相似文献
20.
Nonclassical light states are important for both conceptual and practical reasons: they are basic ingredients in testing and exploring quantum foundations, and are crucial resources in quantum technologies. Various useful criteria have been developed to detect nonclassicality in the literature, and several meaningful measures of nonclassicality have been introduced and measured experimentally. In this work, by use of a non-Hermitian generalization of the Wigner-Yanase-Dyson skew information and playing with operator ordering in evaluating average photon number, we develop a novel family of criteria for detecting nonclassicality of light based on Lieb's concavity, which is a deep and powerful result concerning interaction between quantum states and observables. We elucidate the information-theoretic as well as the physical meaning of the criteria, and illustrate their effectiveness in capturing and quantifying nonclassicality of various important light states. 相似文献