双功能催化剂体系作用下乙烯二聚和共聚合的研究

用乙烯为原料在双功能催化剂体系的作用下通过二聚和共聚合反应，直接合成线性低密度聚乙烯（ＬＬＤＰＥ）．所用二聚反应催化剂为钛酸正丁酯（Ｔｉ（ＯＢｕ）_４），共聚催化剂为ＴｉＣｌ_４／ＭｇＣｌ_２（ＺＭ－１催化剂）．研究了二聚反应动力学行为及影响双功能催化剂体系动力学过程的一些因素．结果表明利用这两种催化剂组成双功能催化剂体系能够很方便地制得密度范围在０．９０－０．９３，Ｅｔ／１０００Ｃ在１０－４０的ＬＬＤＰＥ．     

4-[2-(4,6-二甲氧基-2-嘧啶氧基)苄胺基]苯甲酸正丙酯的合成和晶体结构

2-甲砜基-4,6二甲氧基嘧啶和N-(4-丙氧羰基苯基)-2-羟基苄胺在四氢呋喃溶液中反应, 生成标题化合物4-[2-(4,6-二甲氧基-2-嘧啶氧基)苄胺基]苯甲酸正丙酯,并测定了其晶体结构。该化合物分子式为C23H25N3O5,晶体属单斜晶系,空间群为P2/n,晶胞参数为a = 14.8504(8),b = 9.4420(4),c = 16.3129(9) 牛 = 104.881(1)埃琕 = 2210.6(2) 3,Z = 4,Dc = 1.272 g/cm3,F(000) = 896.00,(MoK? = 0.91 cm-1,R = 0.051,wR = 0.118,获得19761衍射数据,其中独立衍射点5004个。经元素分析、IR、MS和HNMR等对化合物的结构进行了表征。在分子结构中,各有3个不同的共轭平面。嘧啶环和苯环(C(7) C(12)),及苯环(C(14) C(19))的夹角分别为99.18 , 164.15埃?个苯环之间的夹角为94.93啊;衔锍世啻焦瓜蟆?     

聚-4,7-二硫杂壬基倍半硅氧烷铑配合物的合成与催化硅氢化性能

本文叙述了一种新型有机硅聚合物负载配位催化剂——聚-4,7-二硫杂壬基倍半硅氧烷铑配合物的合成、结构及其对烯烃硅氢化反应的催化性能.标题配合物在用量为烯烃摩尔量的十万分之一时仍具有良好的催化活性,烯烃的转化数达到80,000.     

MOLECULAR WEIGHT DISTRIBUTION OF AB, A, TYPE CONDENSATION POLYMERS OBTAINED BY ADDING AB MONOMERS IN BATCHES

The molecular weight distribution (MWD) and arm length distribution of AB, Ar type condensation polymers obtained by adding AB monomers in batches have been derived by statistical and kinetic methods. Calculations show the MWD of condensation polymers obtained by this process is much narrower than that of one batch reaction and agrees with the Monte Carlo results very well.     

ZrO2对合成二甲醚双功能催化剂表面结构及催化性能的影响

采用共沉淀沉积法制备了Cu基双功能催化剂，并进行了合成气一步法制取二甲醚实验．XRD、XPS以及BET表征结果表明，催化剂中ZrO2以无定形状态存在，且随着其含量的增加，Zr^4 逐渐溶进CuO晶格，两者之间的电子交换使得Cu^2 在活化过程中很难被彻底还原为Cu^0，而是以Cu^0/Cu^ 的形式共存．活性评价结果表明，Cu^ 离子表现出优异的CO转化率和DME选择性．同时，ZrO2的存在能有效调节催化剂表面的Cu／Zn摩尔比以及促进Cu元素在表面的富集，从而改善催化剂性能．     

稀土在鼠肝中的物种分布

采用 ICP-MS、微量蛋白层析分离技术 ,研究了长时间、低剂量混合稀土及短时间、高剂量硝酸镧分别对大鼠及小鼠作用后 ,稀土在鼠肝中的代谢累积及其物种分布 .结果表明 ,鼠肝中各稀土含量随给药剂量的增加而增大 ,其累积速度大小顺序为 La>Ce>Nd>Pr;经柱层析分离未得到与稀土特异结合的鼠肝蛋白 ;稀土可与多种鼠肝蛋白 (包括多种重要的酶 )结合 ,在一定条件下 ,稀土与其结合蛋白可发生解离     

SYNTHESIS AND CATALYTIC PROPERTY OF POLYSTYRENE SUPPORTED GLUTAMIC ACID SCHIFF BASE COMPLEX OF Mn（ Ⅱ ） IN AEROBIC OXIDATION OF CYCLOHEXENE

The polystyrene supported glutamic acid Schiff base complex of Mn （ Ⅱ ） （PS-Sal-Glue-Mn） was prepared with chloromethylated styrene polymer beads, 2,4-dihydroxybenzaldehyde, L-glutamic acid and manganese （ Ⅱ ） acetate tetrahyrate. The polymeric ligand and the complex were characterized by FT-IR, small area X-ray photoelectron spectroscopy （XPS） and 1CP-AES. In the presence of the manganese complex, cyclohexene （1） was effectively oxidized by molecular oxygen without reductant. The major products of the reaction were 2-cyclohexen-l-ol （2）, 2-cyclohexen-l-one （3） and 2-cyclohexen-1- hydroperoxide （4）, which was different with typical oxidation of cyclohexene. The influence of reaction temperature and additive for oxidation had been studied. The selectivity of 2-cyclohexen-1-hydroperoxide varied with reaction time and different additives. The mechanism of cyclohexene oxidation had also been discussed.     

激光核聚变中的一种X光解谱方法

本文在SAND迭代法的基础上,采取带有周期性光滑化的限幅迭代方法,求解激光核聚变中的X光能谱取得了较好的结果。这个方法适用于根据亚千X射线谱仪、多道k边滤波谱仪和多道滤波-荧光谱仪的测量结果回推靶等离子体的X射线能谱。计算结果表明,该方法完全抑制了数值不稳定性,消除了非物理的“负能谱”现象和解谱结果中的数值结构。特别是该方法对初始试探谱有很强的适应性,解谱计算结果与初始试探谱无关。     

Ligand Exchange Between Penta-Coordinated Phosphoryl Serine and Histidine Compounds

With the assistance of HPLC-ESI-MS/MS, the self-assembly products of serine and histidine penta-coordinated phosphorus compound were separated and identified. The expectative product was seryl-histidine dipeptide, but it was found that there was almost equimolar amount of histidyl-histidine dipeptide as well as seryl-histidine dipeptide. The mechanism was speculated that there was iigand exchange between penta-coordinated phosphoryl serine and histidine in the reaction process. As a result,two types of dipeptide were produced.     

长链烷基苯异构体的气相色谱研究

长链烷基苯异构体的分离分析是石油化学中一个重要课题,曾有较多作者用气相色谱方法研究了长链烷基苯的分离及不同碳数的