Heterogeneous gold(I)-catalyzed cyclization between ynals and amidines: An efficient and practical synthesis of 2,4-disubstituted pyrimidines

A novel and highly efficient heterogeneous gold(I)-catalyzed cyclization between ynals and amidines has been developed that proceeds smoothly under mild conditions and provides a general and practical method for the synthesis of a wide variety of 2,4-disubstituted pyrimidines with high atom-economy, good to high yield, and recyclability of the gold(I) catalyst. The present method is an attractive alternative to construct substituted pyrimidines.     

杆与质点碰撞中的角动量守恒问题

关于质点与不固定的刚性杆在水平面内碰撞之类的题目,是大学力学中灵活应用角动量守恒定律、活跃学生思维的有趣而典型的例子,被许多力学教材和习题集引用.人们对该类题目的多种解法以及容易出现的问题曾进行过不少讨论[1～3],但是关于质点组对质心的角动量和对某种与质心相关的参考点的角动量的关系以及应用,并没有引起人们的注意.如果将这个关系明确化,不仅可以简化解题思路和方法,而且概念清楚,不容易出现错误.     

Ge20Sb15Se65硫系玻璃光子晶体光纤的中红外色散特性

硫系玻璃与石英玻璃相比具有高折射率(2.0~3.5)、低声子能量 (<350 cm^-1)、优良的中远红外透过性能(可至25 μm)等特性.本文制备了一种在中红外具有优良透过特性的无As环保型Ge₂₀Sb₁₅Se₆₅硫系玻璃材料,以此为基质材料设计了一种三层空气孔结构光子晶体光纤,利用多极法对光纤的中红外色散特性进行了数值模拟,系统研究了结构参量孔径d、孔间距Λ 以及d/Λ 对其色散特性的影响.分析表明:通过改变包层空气孔直径d或空气孔间距Λ,可灵活的调节光子晶体光纤的零色散波长向短波或长波方向移动.通过优化结构参量发现,当Λ=3 μm,d/Λ=0.35 附近变化时,可获得3~5 μm色散平坦,且色散值小于5 ps·nm^-1·km^-1的光子晶体光纤.     

Significant improvement of OLED efficiency and stability by doping both HTL and ETL with different dopant in heterojunction of polymer/small-molecules

This paper reports that the polymer/organic heterojunction doped light-emitting diodes using a novel poly-TPD as hole transport material and doping both hole transport layer and emitter layer with the highly fluorescent rubrene and DCJTB has been successfully fabricated. The basic structure of the heterostructure is PTPD/Alq₃. When hole transport layer and electron transport layer are doped simultaneously with different dopant, the electroluminescence quantum efficiencies are about 3 times greater than that of the undoped device. Compared with undoped device and conventional TPD/Alq₃ diode, the stability of the doping device is significantly improved. The process of emission for doped device may include carrier trapping as well as F\"{o}rster energy transfer.     

GJB151B CS115的电路仿真分析(一)--校准设备指标需求分析北大核心CSCD

GJB151B CS115给出了开展脉冲传导敏感度试验的校准平台构成和校准波形标准,但未明确校准平台各设备(脉冲源、电流注入环、校准夹具等)的具体指标需求。为解决这一问题,本文在前期脉冲电流注入电路仿真研究工作的基础上,构建了校准平台的时域电路模型,通过逐一改变模型参数的方法,仿真分析了脉冲源内部回路电感、电流注入环等效电感/电阻/电容等对校准波形前沿、半宽以及平顶降的影响,得出了平台各设备应达到的技术指标。该工作是对GJB151B CS115的有益补充,为搭建CS115试验平台,开展电子设备脉冲传导敏感度试验提供了技术支撑。     

Mucin-Inspired Single-Chain Polymer (MIP) Fibers as Potent SARS-CoV-2 Inhibitors

Mucins are the key component of the defensive mucus barrier. They are extended fibers of very high molecular weight with diverse biological functions depending strongly on their specific structural parameters. Here, we present a mucin-inspired nanostructure, produced via a synthetic methodology to prepare methacrylate-based dendronized polysulfates ( MIP-1 ) on a multi gram-scale with high molecular weight (MW=450 kDa) and thiol end-functionalized mucin-inspired polymer ( MIP ) via RAFT polymerization. Cryo-electron tomography (Cryo-ET) analysis of MIP-1 confirmed a mucin-mimetic wormlike single-chain fiber structure (length=144±59 nm) in aqueous solution. This biocompatible fiber showed promising activity against SARS-CoV-2 and its mutant strain, with a remarkable low half maximal (IC₅₀) inhibitory concentration (IC₅₀=10.0 nM). Additionally, we investigate the impact of fiber length on SARS-CoV-2 inhibition by testing other functional polymers ( MIPs ) of varying fiber lengths.     

Efficient adsorption of U(VI) using in low-level radioactive wastewater containing organic matter by amino groups modified polyacrylonitrile fibers

Journal of Radioanalytical and Nuclear Chemistry - A kind of amino groups modified polyacrylonitrile fibers (PAN-A) was prepared to extract uranium from organic-containing low-level radioactive...     

Existence and stability of periodic solution of a stage‐structured model with state‐dependent impulsive effects

A single population growth model with stage‐structured and state‐dependent impulsive control is proposed. By using the Poincar'e map and the analogue of Poincaré's criterion, we prove the existence and the stability of positive order‐1 or order‐2 periodic solution. Moreover, we show that there is no periodic solution with order greater than or equal to three. Numerical results are carried out to illustrate the feasibility of our main results and the superiority of state feedback control strategy is also discussed. Copyright © 2011 John Wiley & Sons, Ltd.     

豫南山区典型森林类型土壤水分变化规律研究

采用连续定位观测的研究方法,对豫南低山区天然落叶阔叶林土壤水分变化规律进行了研究.结果表明,10cm,20cm,30cm,50cm四个不同测定深度处的土壤水分随季节变化均发生明显的周期性变异,土壤水分含量50cm20cm30cm10cm;变异幅度随深度增加而增加,即50cm30cm20cm10cm;垂直变化差异显著.土壤水分含量与降雨量存在显著的回归关系,10cm,20cm,30cm,50cm四个测定深度土壤水分含量与降雨量的线性回归方程相关系数分别达到0.727,0.772,0.786,0.626.