离子注入诱导量子阱界面混合效应的光致荧光谱研究

采用多元芯片方法获得了一系列不同离子注入剂量的GaAsAlGaAs非对称耦合量子阱单元,通过光致荧光谱测量,研究了单纯的离子注入导致的界面混合效应.荧光光谱行为与有效质量理论计算研究表明,Al原子在异质结界面的扩散在离子注入过程中已基本完成,而热退火作用主要是去除无辐射复合中心. 关键词： 量子阱 离子注入 光致荧光谱 界面混合     

Observation of Optical Second Harmonic Generation in Wet-Spun Films of Na-DNA

The observation of optical second harmonic generation (SHG) from wetspun films of Na-DNA is reported. The SHG signal is stronger at a relative humidity of 92% (corresponding to the B conformation of Na-DNA) than at low humidity of -33% (corresponding to a disordered conformation of Na-DNA). The strength of the SHG signal is also dependent on the orientation of the incident laser beam polarization with respect to the DNA helical axes.     

A Computational Study of CIONO2H+: Structure and Vibrations

Two protonated forms of chlorine nitrate, HClONO⁺ ₂ and ClONO₂H⁺, are treated ab initio by the Hartree-Fock and the second order Møller-Plesset perturbation approach with the standard 6–31G* basis set. Both minimum energy structures are planar (C ₃ symmetry) and their structural, energy, and vibrational parameters are reported. The computations conclude that the proton attacks the chlorine nitrate at its central, not end, oxygen atom. The protonation causes a considerable elongation of the central ON bond which becomes most probable place of cleavage. The dissociation should yield the neutral HOCl and NO⁺ ₂. These quantum-chemical findings well agree with the previous experimental indications.

     

Spectroscopic Properties of Cu(L-met)2, Cu(DL-met)2, Cu(L-ala)2 and Cu(DL-ala)2˙H2O and Qualitative Explanations to the Magnetism and Relative Ordering of the One-Electron Energy Levels.

Electronic absorption spectra and photoacoustic spectra of four copper(II)-amino acid complexes of formulas Cu(L-met)˙(1). Cu(DL-met)˙(2). Cu(L-ala)x(3) and Cu(DL-ala)˙-H₂O(4)(L-met=L-methioninato;DL-met=DL-methioninato;L-ala=L-alaninato DL-ala=DL-alaninato) were recorded and the results are discussed quantitatively with respect to llgand field theory and the radical wave function of a non-free copper(II) ion. The relationship between the maximum absorption peak in PAS and magnetic properties is also discussed. Lastly, a qualitative explanation on the senquence of splitting energy in going from regular octahedral to strongly elongately and slightly tetragonally distorted octahedral around each copper(II) center is proposed.     

一种新型THz显微探测技术

由于太赫兹(THz)电磁辐射的波长较长，探测的空间分辨率受到衍射极限的限制.设计了一种 新型的THz显微探测技术，使探测晶体紧贴在薄产生晶体上，激发光采用紧聚焦的方式不但 把空间分辨率提高到光学量级，还克服了典型近场探测方法中存在的低通光量、高通滤波的 缺点.详细介绍了这一新型探测器件的基本结构和显著的探测特性. 关键词： THz 近场 聚焦     

有界随机噪声激励下软弹簧Duffing振子的安全盆分叉

研究了软弹簧Duffing振子在有界随机噪声激励下，系统安全盆的侵蚀现象，并提出了随机安全盆分叉的概念. 计算表明，由于随机扰动的影响，系统的随机安全盆分叉点发生了偏移. 关键词： Duffing振子 有界随机噪声 安全盆 分叉     

激光测距机主要参数校准测量不确定度分析

简述激光测距机主要参数校准装置的组成，通过对其主要参数(最大测程、最小测程、测距准确度、重复频率、束散角)的校准测量进行详细的不确定度分析，评价激光测距机主要参数校准装置的达标程度。     

基于正交小波包的茶叶近红外光谱特性分析

针对茶叶近红外光谱数据中存在着高度的共线性和高维数,根据小波包变换具有的去相关能力。通过引入保留能量和置零系数来定量描述茶叶近红外光谱小波包变换后的特性;分析与实验表明,正交小波包对近红外光谱具有较强的压缩能力,压缩后保留的能量为99．98％,而置零系数百分比高达95．87％;这一结果对近红外光谱图的存储、检索及快速处理都有着十分重要的意义。     

NPB表面形貌对OLED光电特性的影响

用原子力显微镜观察了沉积在不同温度基板上NPB表面形貌,发现NPB薄膜在室温下比较平坦的点状结构变为100℃时直径为0.2μm的岛状结构。为研究NPB表面形貌对OLED器件性能的影响,设计了结构为玻璃/ITO/NPB/Alq3/Al器件,比较了不同基板温度沉积的NPB薄膜对器件性能的影响。     

激光调制气溶胶红外诱饵对成像制导导弹的干扰分析

概述了气溶胶红外诱饵的工作原理、特点、现状及其发展趋势。介绍了一种新型气溶胶红外诱饵———激光调制气溶胶红外诱饵。仿真实验表明,与传统的红外诱饵相比,激光调制气溶胶红外诱饵有效地增强了保护目标和对抗红外成像制导武器的能力,是气溶胶红外诱饵发展的一个新方向。