Effects of carrier and Mn loading on supported manganese oxide catalysts for catalytic combustion of methane

Supported manganese oxide catalysts were prepared by incipient wetness impregnation method for methane catalytic combustion, and effects of the support （Al2O3, SiO2 and TiO2） and Mn loading were investigated. These catalysts were characterized with N2 adsorption, X-ray diffraction, X-ray photoelectron spectroscopy and temperature-programmed reduction techniques. Methane conversion varied in a large range depending on supports or Mn loading. Al2O3 supported 15% Mn catalyst exhibited better activity toward methane catalytic oxidation. The manganese state and oxygen species played an important role in the catalytic performance,     

Quadratic programs over the Stiefel manifold

We characterize the optimal solution of a quadratic program over the Stiefel manifold with an objective function in trace formulation. The result is applied to relaxations of HQAP and MTLS. Finally, we show that strong duality holds for the Lagrangian dual, provided some redundant constraints are added to the primal program.     

A new flavonol triglycoside derived from Anoectochilus elwesii on stimulating glucose uptake in insulin-induced human HepG2 cells

A novel flavonol triglycoside (4), isorhamnetin-3-O-β-d-glucopyranosyl (1→2)-α-l-rhamnopyranosyl (1→6)-β-d-glucopyranoside, named elwesoside A, together with six known flavonols (1–3, 5–7) was isolated from Anoectochilus elwesii (Clarke ex Hook. f.) King et Pantl. and its structure was elucidated by extensive spectroscopic methods and comparison with the literature data. All compounds were first reported in this plant and two of them (4 and 5) were the first examples of flavonol triglycosides isolated from Anoectochilus genus. The effects of 1–7 were evaluated on insulin-treated human HepG2 cells under high glucose conditions for stimulating glucose uptake activities. The novel compound (4) displayed highly potent dose-dependent effect on the stimulation of glucose uptake in insulin-resistant human HepG2 cells.     

季铵盐二聚表面活性剂C12-S2-C12·2Br复配体系在氯仿中形成反胶团的增溶水状态

采用近红外光谱技术,研究了季铵盐Gemini表面活性剂C12-S2-C12.2Br/氯仿体系中反胶团的增溶水状态,使用Peakfit解峰技术,将水的近红外光谱分为3个亚带,分别对应分散于溶剂中的水、反胶团中的类似本体水和结合水。将以上3种状态的水换算成每个表面活性剂分子对应的各种状态水分子数,即分散在溶剂中的水ns、类似本体水nf和结合水nb。向C12-S2-C12.2Br/氯仿体系中加入不同头基的离子型表面活性剂十二烷基三甲(乙)基溴化铵(DTAB、DTEB),发现随着添加剂摩尔分数αA的增大,ns和nb增大,nf减小。加入非离子表面活性剂聚乙二醇辛基苯基醚(OP-10),随着αA的增大ns减小,nb增大,nf略有增大趋势。可见加入表面活性剂头基的大小、所带电荷以及亲水性等均会对反胶团的增溶水能力和状态产生影响。     

Thermodynamic analysis of lipoic acid crystallized with additives

Differential scanning calorimetry (DSC) was used as a screening technique to study the interaction between lipoic acid and amino acids. The samples containing lipoic acid and amino acids were prepared by two different methods (milling method and cooling crystallization method). Firstly, cooling method was used to prepare the sample with amino acids as additives. DSC results indicated that only phenylalanine has some interaction with lipoic acid. Further, in order to study the interaction between lipoic acid and phenylalanine, another method (milling method) was used to prepare the sample containing phenylalanine, and the effect of sample preparation methods was studied through IR analysis and the X-ray powder diffraction. On the basis of above researches, the possible interaction mechanisms between lipoic acid and phenylalanine were proposed.     

替考拉宁和万古霉素高效液相色谱手性固定相的研究

分别使用四种不同的方法将替考拉宁和万古霉素键合在硅胶表面,制备了八种不同的高效液相色谱柱固定相,并在反相模式和极性有机相模式下考察了这八种手性柱的性能.实验表明,固定相制备方法的不同和色谱条件的改变对色谱柱拆分性能有一定的影响,不相同的键合臂,能拆分的对映异构体可能不一样,这些柱之间具有一定的互补性.八种手性固定相均有...     

对比生物体系以及合成体系中单核铜氧物种对碳氢键和氧氢键活化的理论研究展望

由于具有较好的催化性能,含过渡金属的酶一直备受研究者的关注.其中,铜作为生物体中含量仅次于铁和锌的过渡金属,在新陈代谢过程中发挥着重要作用.铜酶广泛存在于自然界中,该类生物大分子涉及电子转移、氧化还原、氧气的运输与活化等生物化学过程.多种铜酶在氧气活化方面表现出引人注目的 性质,例如:颗粒状甲烷单加氧酶(pMMO)、多...     

Tailoring the d‐Band Centers Enables Co4N Nanosheets To Be Highly Active for Hydrogen Evolution Catalysis

Endowing materials with specific functions that are not readily available is always of great importance, but extremely challenging. Co₄N, with its beneficial metallic characteristics, has been proved to be highly active for the oxidation of water, while it is notoriously poor for catalyzing the hydrogen evolution reaction (HER), because of its unfavorable d‐band energy level. Herein, we successfully endow Co₄N with prominent HER catalytic capability by tailoring the positions of the d‐band center through transition‐metal doping. The V‐doped Co₄N nanosheets display an overpotential of 37 mV at 10 mA cm^?2, which is substantially better than Co₄N and even close to the benchmark Pt/C catalysts. XANES, UPS, and DFT calculations consistently reveal the enhanced performance is attributed to the downshift of the d‐band center, which helps facilitate the H desorption. This concept could provide valuable insights into the design of other catalysts for HER and beyond.     

关于可解李三超系

给出了关于李三超系的一些基本概念和性质,包括:(1)可解李三超系的任意包络李超代数都是可解的;(2)如果一个李蔓超系有可解的包络李超代数,则它也是可解的;(3)一个李三超系T是幂零的当且仅当它的标准嵌入李超代数L(T)是幂零的;(4)L(T)的中心等于T的中心;(5)李三超系上的右不变超对称双线性型可唯一地扩张到它的标准嵌入李超代数上.     

多分量方位远探测声波测井的理论与应用

基于线性拟合的利用岩石动态模量预测静态模量方法存在经验性强且精度不准的问题,利用实验测量的岩石纵波速度、孔隙度和体密度作为输入参数,基于多基因遗传规划方法,不断进化模型得到静态模量关于三个参数的解析表达式,对储层砂岩的静态模量进行了预测。结果表明,多基因遗传规划方法得到的模量表达式更为精确,此外,由于多基因遗传规划方法中横波速度不必要作为计算过程中的输入参数,因此避免了横波速度测量不准确或缺失而带来的静态模量计算误差。