共查询到20条相似文献,搜索用时 109 毫秒
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利用原子力显微镜(AFM)和光致荧光(PL)光谱对一系列直流腐蚀和脉冲腐蚀的多孔硅的微结构及发光特性进行了对比研究.表面和侧面的AFM结果表明,多孔硅表面呈“小山”状,有许多小的、突出的硅颗粒.在相同的腐蚀条件(等效)下,脉冲腐蚀的样品表面Si颗粒更加尖锐、突出,侧面的线状结构更明显,多孔硅层更厚.对应的PL谱,脉冲腐蚀的样品发光更强.量子限制效应的理论可以比较成功地解释这个结果
关键词: 相似文献
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在制备出光致发光能量为2.7eV的发射蓝光多孔硅的基础上对它进行了较系统的研究:测量了它的光致发光时间分辨光谱,用傅里叶交换红外光谱分析了其表面吸附原子的局域振动模,研究了γ射线辐照对其发光的影响,并与发红、黄光的多孔硅作了对比,通过空气中长期存放、激光和紫外线照射的方法,研究了光致发光峰能量为2.7eV的多孔硅发光稳定性.我们及其它文献中报道的多孔硅蓝光发射的实验结果与量子限制模型矛盾,但能用量子限制/发光中心模型解释.我们认为多孔硅的2.7eV发光是多孔硅中包裹纳米硅的SiOx层中某种特征发光中心引起的.
关键词: 相似文献
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最近的研究中,采用1.06μm超短脉冲光激发,在多孔硅表面观察到了有效的红外多光子激发的荧光发射.研究表明,这是一个增强的三阶非线性光学过程.本文利用其三阶非线性特性对具有强可见光发射的多孔硅结构进行了研究,结果显示晶体硅的各向异性特征在多孔硅中几乎被保留;此外,较强的激光激发导致的红外上转换荧光信号衰减过程被归结为与多孔硅表面氢的脱附有关. 相似文献
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采用电化学腐蚀制备多孔硅,利用场致发射扫描式电子显微镜(field emission scanning electron microscope,FESEM)观测多孔硅的二维微观形貌,利用Nano Indenter XP中的纳米轮廓扫描仪组件(nano profilometry, NP)得到其三维拓扑分析图像,分析了微观结构差异的原因并讨论了多孔硅内部微观结构对其机械性能的影响;利用MTS Nano Indenter XP纳米压入测量仪器,研究了多孔硅的显微硬度和杨氏模量随压入深度的变化规律,比较了不同孔隙率多孔硅的机械性能差别.实验结果测得40mA/cm2,60mA/cm2,80mA/cm2和100mA/cm2四个不同腐蚀电流密度条件下制备多孔硅样品的孔隙率在60%—80%范围内,孔隙率随着腐蚀电流密度的增加而增大;在氢氟酸(HF)浓度为20%的条件下制备出多孔硅样品的厚度在40μm—50μm范围内;测得多孔硅的平均硬度、平均杨氏模量分别在0.478GPa—1.171GPa和10.912GPa—17.15GPa范围内,并且其数值随腐蚀电流密度的增加而减小,在纳米硬度范围内随压入深度的增加而减小,在显微硬度范围内其数值保持相对恒定,分析了样品表面、厚度、微观结构,及环境对其机械性能的影响,得到了多孔硅力学性能随其微观尺度形貌的变化规律.
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多孔硅
微观结构
硬度
杨氏模量 相似文献
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Z. H. Mkhitaryan A. A. Shatveryan V. M. Aroutiounian 《Journal of Contemporary Physics (Armenian Academy of Sciences)》2007,42(4):158-161
The current-voltage characteristics of structures with a layer of porous silicon of 73% porosity were measured at adsorption of gas (carbon monoxide) at room temperature. Estimations are performed of the height of potential heterobarrier at the interface between porous silicon and p +-type single-crystal silicon, of the perfectness factor and the resistance of a layer of porous silicon in air, in air with 0.4% CO, and in air with 2% CO. Physical causes explaining the experimental data are discussed. 相似文献
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J. Jakubowicz K. Smardz L. Smardz 《Physica E: Low-dimensional Systems and Nanostructures》2007,38(1-2):139
In this study, we have proposed the powder technology as new method for preparation of bulk porous silicon. Formation of porous silicon by high-energy ball milling followed by pressing and sintering was studied by X-ray diffraction, scanning electron microscopy and X-ray photoelectron spectroscopy (XPS). A crystalline wafer with (1 1 1) orientation was extensively ball milled up to 72 h leading to a decrease in average crystallite size up to 15 nm. The most significant reduction of crystallite size was observed after milling process for about 24 h. The nanopowders were then pressed into pellets at a pressure up to 400 MPa and sintered at 1173 K for 60 min in a high purity argon atmosphere. Results showed that after sintering the material became porous with uniform porosity in whole volume, independently of the sinter size. It is not possible to prepare such porous materials using the conventional electrochemical etching, where the porous structure depth usually does not exceed tens of micrometers. Core-level XPS studies showed very good agreement between peak positions of the sintered porous silicon and in-situ prepared polycrystalline 20 nm-Si thin film or single-crystalline Si (1 1 1) wafer. Furthermore, the valence band spectra measured for sintered samples are broader compared to those measured for the Si (1 1 1) wafer or polycrystalline Si thin film. On the other hand, the shape and broadening of the valence bands measured for the sintered samples are in very good agreement with those reported for electrochemically prepared porous silicon. 相似文献
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Charge storage characteristics of hydrogenated nanocrystalline silicon film prepared by rapid thermal annealing 下载免费PDF全文
The early stages of hydrogenated nanocrystalline silicon (nc-Si:H)
films deposited by plasma-enhanced chemical vapour deposition were
characterized by atomic force microscopy. To increase the density of
nanocrystals in the nc-Si:H films, the films were annealed by rapid
thermal annealing (RTA) at different temperatures and then analysed
by Raman spectroscopy. It was found that the recrystallization
process of the film was optimal at around 1000℃. The effects
of different RTA conditions on charge storage were characterized by
capacitance--voltage measurement. Experimental results show that
nc-Si:H films obtained by RTA have good charge storage
characteristics for nonvolatile memory. 相似文献
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GUO Hengqun 《Chinese Journal of Lasers》1994,3(6):557-563
Photoluminescence quenching of porous silicon by noble metal adsorbates¥GUOHengqun(DepartmentofAppliedPhysics,HuaqiaoUniyersi... 相似文献
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V. M. Aroutiounian Kh. S. Martirosyan A. S. Hovhannisyan P. G. Soukiassian 《Journal of Contemporary Physics (Armenian Academy of Sciences)》2008,43(2):72-76
Reflectance spectrum calculations of double- and triple-layer antireflection coatings made of porous silicon layer are performed, using the optical matrix approach method. Obtained results are compared with the reflectance spectrum of other type antireflection coatings. Lower reflectance value of both double- and triple-layer antireflection coatings made of porous silicon is obtained in comparison to that of SiO2/TiO2 antireflection coating. These results can be used in photovoltaic converters. 相似文献