| 基于离子液体的绿色催化过程 |
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| 引用本文： | 孙剑,王金泉,王蕾,张锁江.基于离子液体的绿色催化过程[J].中国科学:化学,2014(1):100-113. |
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| 作者姓名： | 孙剑 王金泉 王蕾 张锁江 |
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| 作者单位： | 中国科学院过程工程研究所,北京100190 |
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| 基金项目： | 致谢 本工作得到国家自然科学基金（21036007）、国家自然科学基金青年科学基金（21006117）,以及国家自然基金国际合作项目（121210006）资助,特此一并致谢. |
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| 摘 要： | 离子液体为构建绿色催化反应过程提供了新途径.本文简要评述了离子液体在几个代表性催化反应中的研究进展,如CO2羰基化、烷基化、酯交换、氧化、CO2加氢、共聚以及PET降解等;分析讨论了离子液体的特点和优势,如提高反应活性、降低废物排放以及简化分离等,并对离子液体催化反应的未来发展方向进行了展望.
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| 关 键 词： | 离子液体 绿色催化 反应过程 |
Ionic liquids catalyzed green processes |
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| SUN Jian,WANG JinQuan,WANG Lei,ZHANG SuoJiang.Ionic liquids catalyzed green processes[J].Scientia Sinica Chimica,2014(1):100-113. |
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| Authors: | SUN Jian WANG JinQuan WANG Lei ZHANG SuoJiang |
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| Institution: | ( Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China) |
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| Abstract: | Fundamental research on ionic liquids has promoted their wide applications including catalysis, organic synthesis and materials, which provides new method for developing green catalysis processes. This article reviews some representative ionic liquid-based catalytic reactions, such as CO2 cycloaddition, alkylation, hydroformylation, transesterification, oxidation, CO2 hydrogenation, cross-polymerization and depolymerization, with the aiming of highlighting the roles of ionic liquids on reaction efficiency, the reduction of emissions and separation. Furthermore, the prospective to the development in this field is discussed. |
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| Keywords: | ionic liquids green catalysis progress |
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