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负载型Heck反应催化剂的研究进展
引用本文:刘鸿飞,贾志刚,季生福.负载型Heck反应催化剂的研究进展[J].催化学报,2012,33(5):757-767.
作者姓名:刘鸿飞  贾志刚  季生福
作者单位:北京化工大学化工资源有效利用国家重点实验室,北京,100029
摘    要:Heck反应是一类重要的C-C偶联反应,传统的均相Heck反应催化剂存在分离和回收困难等问题;近年来负载型Heck反应催化剂的研究引起了人们的广泛关注.本文综述了钯基和非钯基负载型Heck反应催化剂的研究进展,评述了不同载体上催化活性组分对Heck反应的特点,并展望了其发展趋势.

关 键 词:负载型催化剂  Heck反应    非钯  进展

Research Progress in Supported Catalysts for Heck Reaction
LIU Hongfei , JIA Zhigang , JI Shengfu.Research Progress in Supported Catalysts for Heck Reaction[J].Chinese Journal of Catalysis,2012,33(5):757-767.
Authors:LIU Hongfei  JIA Zhigang  JI Shengfu
Institution:* State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing 100029,China
Abstract:Heck reaction is a sort of classical C-C coupling reaction.The traditional homogeneous Heck reaction catalyst has a number of disadvantages,in particular,separated and recycled after reaction.In recent years,the supported Heck reaction catalysts have attracted wide attention owing to their high catalytic activity and excellent reusable performance.The research progress of the supported palladium-based and non-palladium-based Heck reaction catalysts was reviewed.The characteristics of catalytic active component on different supports in the performance of Heck reaction were discussed.Directions in this field for future research were suggested.
Keywords:supported catalyst  Heck reaction  palladium  non-palladium  progress
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