以对二甲苯氧化为对苯二甲酸为例简要综述一级C–H键活化(英文)

The oxidation of para‐xylene to terephthalic acid has been commercialised as the AMOCO process(Co/Mn/Br) that uses a homogeneous catalyst of cobalt and manganese together with a corrosive bromide compound as a promoter. This process is conducted in acidic medium at a high tempera‐ture(175–225 °C). Concerns over environmental and safety issues have driven studies to find mild‐er oxidation reactions of para‐xylene. This review discussed past and current progress in the oxida‐tion of para‐xylene process. The discussion concentrates on the approach of green chemistry in‐cluding(1) using heterogeneous catalysts with promising high selectivity and mild reaction condi‐tion,(2) application of carbon dioxide as a co‐oxidant, and(3) application of alternative promoters. The optimisation of para‐xylene oxidation was also outlined.

A brief review of para-xylene oxidation to terephthalic acid as a model of primary C-H bond activation

The oxidation of para-xylene to terephthalic acid has been commercialised as the AMOCO process (Co/Mn/Br) that uses a homogeneous catalyst of cobalt and manganese together with a corrosive bromide compound as a promoter. This process is conducted in acidic medium at a high temperature (175-225 ℃). Concerns over environmental and safety issues have driven studies to find milder oxidation reactions of para-xylene. This review discussed past and current progress in the oxidation of para-xylene process. The discussion concentrates on the approach of green chemistry including (1) using heterogeneous catalysts with promising high selectivity and mild reaction condition, (2) application of carbon dioxide as a co-oxidant, and (3) application of alternative promoters. The optimisation of para-xylene oxidation was also outlined.