Elimination of bis(trimethylsilyl)stannylene from tris(trimethylsilyl)stannylated zirconocene and hafnocene chlorides |
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Institution: | Institute für Anorganische Chemie, Technische Universität Graz, A-8010 Graz, Austria |
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Abstract: | Reactions of (Me3Si)3SnK with Cp2MCl2 (M = Zr, Hf) give the respective stannylated metallocene chlorides. These complexes display a tendency to eliminate bis(trimethylsilyl)-stannylene under Cp2M(Cl)SiMe3 formation. |
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Keywords: | Stannylated compounds Group 4 elements Metallocenes Stannylene Tin Silicon Zirconium Hafnium |
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