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The Preparation of the Carbosilane Dendrimers with Pentafluorophenyl Groups
作者姓名:Rui  Fang  GUAN  Chuan  Jian  ZHOU  Sheng  Yu  FENG
作者单位:Rui Fang GUAN1,3,Chuan Jian ZHOU2,Sheng Yu FENG3 1 School of Materials Science and Engineering,Ji′nan University,Ji′nan 250022 2 School of Materials Science and Engineering,Shandong University,Ji′nan 250061 3 School of Chemistry and Chemical Engineering Shandong University,Ji′nan 250100
摘    要:Dendrimers as intriguing macromolecules possess potential in phase transfer catalysis, hosts-guest chemistry, controlled release drugs or might serve as recyclable extracting agents1,2,3. The fluorine-containing dendrimers can be used as low surface-energ…

关 键 词:聚硅氧烷  硅氢化作用  碳硅树枝体  五氟代苯  低粘度
收稿时间:2006-03-10

The Preparation of the Carbosilane Dendrimers with Pentafluorophenyl Groups
Rui Fang GUAN Chuan Jian ZHOU Sheng Yu FENG.The Preparation of the Carbosilane Dendrimers with Pentafluorophenyl Groups[J].Chinese Chemical Letters,2006,17(9):1159-1161.
Authors:Rui Fang GUAN  Chuan Jian ZHOU  Sheng Yu FENG
Abstract:Polysiloxane was a good solvent for hydrosilation reaction of carbosilane dendrimers with pentafluorophenyl core and HSiMe2(CH2)3C6F5. A new kind of dendrimer with both pentafluorophenyl core and terminal groups was synthesized. The studies showed that with the increase of fluorination, the viscosity values of carbosilane dendrimers decreased.
Keywords:Polysiloxane  hydrosilation  carbosilane dendrimer  pentafluorobenzene  low viscosity  
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